pmid
stringlengths 5
8
| abstract
stringlengths 1
17.3k
|
|---|---|
36903204
|
Temporal average shapes of crackling noise avalanches, U(t) (U is the detected parameter proportional to the interface velocity), have self-similar behavior, and it is expected that by appropriate normalization, they can be scaled together according to a universal scaling function. There are also universal scaling relations between the avalanche parameters (amplitude, A, energy, E, size (area), S, and duration, T), which in the mean field theory (MFT) have the form E∝A3, S∝A2, S∝T2. Recently, it turned out that normalizing the theoretically predicted average U(t) function at a fixed size, U(t)=atexp-bt2 (a and b are non-universal, material-dependent constants) by A and the rising time, R, a universal function can be obtained for acoustic emission (AE) avalanches emitted during interface motions in martensitic transformations, using the relation R~A1-φ too, where φ is a mechanism-dependent constant. It was shown that φ also appears in the scaling relations E~A3-φ and S~A2-φ, in accordance with the enigma for AE, that the above exponents are close to 2 and 1, respectively (in the MFT limit, i.e., with φ= 0, they are 3 and 2, respectively). In this paper, we analyze these properties for acoustic emission measurements carried out during the jerky motion of a single twin boundary in a Ni
|
36903205
|
Time-of-flight secondary ion mass spectrometry (TOF-SIMS) is a powerful chemical characterization technique allowing for the distribution of all material components (including light and heavy elements and molecules) to be analyzed in 3D with nanoscale resolution. Furthermore, the sample's surface can be probed over a wide analytical area range (usually between 1 µm
|
36903206
|
Within the present work the homogenization of DC-cast (direct chill-cast) extrusion billets of Al-Mg-Si-Cu alloy was investigated. The alloy is characterized by higher Cu content than currently applied in 6xxx series. The aim of the work was analysis of billets homogenization conditions enabling maximum dissolution of soluble phases during heating and soaking as well as their re-precipitation during cooling in form of particles capable for rapid dissolution during subsequent processes. The material was subjected to laboratory homogenization and the microstructural effects were assessed on the basis of DSC (differential scanning calorimetry) tests, SEM/EDS (scanning electron microscopy/energy-dispersive spectroscopy) investigations and XRD (X-ray diffraction) analyses. The proposed homogenization scheme with three soaking stages enabled full dissolution of Q-Al
|
36903207
|
Silicones are commonly used as adhesives when high-quality materials are required due to harsh environmental conditions such as high temperature, humidity, etc. To ensure high resistance to environmental conditions, including high temperatures, modifications of silicone adhesives are made using fillers. The characteristics of a modified silicone-based pressure-sensitive adhesive with filler are the focus of this work. Functionalized palygorskite was prepared in this investigation by grafting 3-mercaptopropyltrimethoxysilane (MPTMS) onto palygorskite (palygorskite-MPTMS). The palygorskite was functionalized using MPTMS under dried conditions. FTIR/ATR spectroscopy, thermogravimetric analysis, and elemental analysis were all used to characterize the obtained palygorskite-MPTMS. MPTMS loading onto palygorskite was also proposed. The results demonstrated that palygorskite's initial calcination favors the grafting of functional groups on its surface. New self-adhesive tapes based on palygorskite-modified silicone resins have been obtained. This functionalized filler allows for the improvement of the compatibility of palygorskite with specific resins for application in heat-resistant silicone pressure-sensitive adhesives. The new self-adhesive materials showed increased thermal resistance while maintaining good self-adhesive properties.
|
36903208
|
The various concepts involved in the mathematical modeling of the fluid-solid interactions (FSIs) of catalytic combustion processes occurring within a porous burner are presented and discussed in this paper. The following aspects of them are addressed: (a) the relevant physical and chemical phenomena appearing at the interface between the gas and the catalytic surface; (b) a comparison of mathematical models; (c) a proposal of a hybrid two/three-field model, (d) an estimation of the interphase transfer coefficients; (e) a discussion of the proper constitutive equations and the closure relations; and (f) a generalization of the Terzaghi concept of stresses. Selected examples of application of the models are then presented and described. Finally, a numerical verification example is presented and discussed to demonstrate the application of the proposed model.
|
36903209
|
Resin-based friction materials (RBFM) are widely used in the fields of automobiles, agriculture machinery and engineering machinery, and they are vital for safe and stable operation. In this paper, polymer ether ketone (PEEK) fibers were added to RBFM to enhance its tribological properties. Specimens were fabricated by wet granulation and hot-pressing. The relationship between intelligent reinforcement PEEK fibers and tribological behaviors was investigated by a JF150F-II constant-speed tester according to GB/T 5763-2008, and the worn surface morphology was observed using an EVO-18 scanning electron microscope. The results showed that PEEK fibers can efficiently enhance the tribological properties of RBFM. A specimen with 6 ωt% PEEK fibers obtained the optimal tribological performance, the fade ratio was -6.2%, which was much higher than that of the specimen without the addition of PEEK fibers, the recovery ratio was 108.59% and the wear rate was the lowest, which was 1.497 × 10
|
36903210
|
Crystals of Gd
|
36903211
|
Some considerations of slender elastic nonperiodic beams are shown in this paper. These beams have a functionally graded structure on the macro-level along the
|
36903212
|
Metal chalcogenides are attractive anode materials for lithium-ion batteries (LIBs) due to their high theoretical capacities. With the advantages of low cost and abundance reserves, ZnS is regarded as the prime candidate anode material for future generations, but its practical application is hindered by the large volume expansion during repeated cycling processes and inherent poor conductivity. Rational design of the microstructure with large pore volume and high specific surface area is of great significance to solve these problems. Here, a carbon-coated ZnS yolk-shell structure (YS-ZnS@C) has been prepared by selective partial oxidation of a core-shell structured ZnS@C precursor in air and subsequent acid etching. Studies show that the carbon wrapping and proper etching to bring cavities can not only improve the material's electrical conductivity, but can also effectively alleviate the volume expansion problem of ZnS during its cycles. As a LIB anode material, the YS-ZnS@C exhibits an obvious superiority in capacity and cycle life compared to ZnS@C. The YS-ZnS@C composite shows a discharge capacity of 910 mA h g
|
36903214
|
ZnO is one of the most widely used inorganic sunscreens, owing to its fine particle size and UV light shielding capability. However, powders at nanosizes can be toxic and cause adverse effects. The development of non-nanosized particles has been slow. The present work investigated synthesis methods of non-nanosized ZnO particles for ultraviolet protection application. By altering the starting material, KOH concentration, and input speed, the ZnO particles can be obtained in different forms, including needle type, planar type, and vertical wall type. Cosmetic samples were made by mixing different ratios of synthesized powders. The physical properties and the UV blockage efficacy of different samples were evaluated using scanning electron microscopy (SEM), X-ray diffraction (XRD), particle size analyzer (PSA), and ultraviolet/visible (UV/Vis) spectrometer. The samples with 1:1 ratio of needle-type ZnO and vertical wall-type ZnO exhibited superior light blocking effect owing to improved dispersibility and prevention of particle agglomeration. The 1:1 mixed sample also complied with the European nanomaterials regulation due to the absence of nanosized particles. With superior UV protection in the UVA and UVB regions, the 1:1 mixed powder showed potential to be used as a main ingredient in UV protection cosmetics.
|
36903213
|
The use of additively manufactured components specifically utilizing titanium alloys has seen rapid growth particularly in aerospace applications; however, the propensity for retained porosity, high(er) roughness finish, and detrimental tensile surface residual stresses are still a limiting factor curbing its expansion to other sectors such as maritime. The main aim of this investigation is to determine the effect of a duplex treatment, consisting of shot peening (SP) and a coating deposited by physical vapor deposition (PVD), to mitigate these issues and improve the surface characteristics of this material. In this study, the additive manufactured Ti-6Al-4V material was observed to have a tensile and yield strength comparable to its wrought counterpart. It also exhibited good impact performance undergoing mixed mode fracture. It was also observed that the SP and duplex treatments resulted in a 13% and 210% increase in hardness, respectively. Whilst the untreated and SP treated samples exhibited a similar tribocorrosion behavior, the duplex-treated sample exhibited the greatest resistance to corrosion-wear observed by the lack of damage on the surface and the diminished material loss rates. On the other hand, the surface treatments did not improve the corrosion performance of the Ti-6Al-4V substrate.
|
36903215
|
The hydration reaction seriously affects the quality and performance of MgO-based products. The final analysis showed that the problem is the surface hydration of MgO. By studying the adsorption and reaction of water molecules on the surface of MgO, we can understand the nature of the problem from the root cause. In this paper, first-principles calculations are performed on the crystal plane of MgO (100) to study the influence of the different orientation, sites and coverage of water molecules on the surface adsorption. The results show that the adsorption sites and orientations of monomolecular water has no effect on the adsorption energy and adsorption configuration. The adsorption of monomolecular water is unstable, with almost no charge transfer, belonging to the physical adsorption, which implies that the adsorption of monomolecular water on MgO (100) plane will not lead to the dissociation of water molecule. When the coverage of water molecules exceeds 1, water molecules will dissociate, and the population value between Mg and O
|
36903217
|
The rolling process of rebar steel production is one of the well established manufacturing processes; however, it should be subjected to revision and redesign for productivity enhancement and power reduction throughout the slit rolling process. In this work, slitting passes are extensively reviewed and modified for the attainment of better rolling stability and reduction in power consumption. The study has been applied for grade B400B-R Egyptian rebar steel, which is equivalent to steel grade ASTM A615M, Grade 40. Traditionally, the rolled strip in the rolling pass is edged before implementing a slitting pass using grooved rolls; this produces a single barreled strip. This single barrel form causes instability in the next slitting stand on the pressing by the slitting roll knife. Multiple industrial trials are attempted to achieve the deformation of the edging stand using a grooveless roll. As a result, a double barreled slab is produced. In parallel, finite element simulations of the edging pass are performed using grooved and grooveless rolls, and similar slab geometry with single and double barreled form are produced. In addition, further finite element simulations of the slitting stand are execute using idealized single barreled strips. The power calculated by the FE simulations of the single barreled strip is (245 kW), which is in acceptable agreement with the experimental observations in the industrial process (216 kW). This result validates the FE modeling parameters such as material model and boundary conditions. The FE modeling is extended to the slit rolling stand of a double barreled strip, which was previously produced by the grooveless edging rolls. It is found that the power consumption is (165 kW) 12% lower than the power consumed (185 kW) for slitting the single barreled strip.
|
36903216
|
With the goal of improving the mechanical properties of porous hierarchical carbon, cellulosic fiber fabric was incorporated into the resorcinol/formaldehyde (RF) precursor resins. The composites were carbonized in an inert atmosphere, and the carbonization process was monitored by TGA/MS. The mechanical properties, evaluated by nanoindentation, show an increase in the elastic modulus due to the reinforcing effect of the carbonized fiber fabric. It was found that the adsorption of the RF resin precursor onto the fabric stabilizes its porosity (micro and mesopores) during drying while incorporating macropores. The textural properties are evaluated by N
|
36903218
|
Membrane technologies and materials development appear crucial for the hydrogen/natural gas separation in the impending transition to the hydrogen economy. Transporting hydrogen through the existing natural gas network could result less expensive than a brand-new pipe system. Currently, many studies are focused on the development of novel structured materials for gas separation applications, including the combination of various kind of additives in polymeric matrix. Numerous gas pairs have been investigated and the gas transport mechanism in those membranes has been elucidated. However, the selective separation of high purity hydrogen from hydrogen/methane mixtures is still a big challenge and nowadays needs a great improvement to promote the transition towards more sustainable energy source. In this context, because of their remarkable properties, fluoro-based polymers, such as PVDF-HFP and Nafion
|
36903219
|
Rotary swaging is a promising technique for the fabrication of clad Cu/Al composites. Residual stresses appearing during the processing of a special arrangement of Al filaments within the Cu matrix and the influence of the bar reversal between the passes were studied by (i) neutron diffraction using a novel evaluation procedure for pseudo-strain correction and (ii) a finite element method simulation. The initial study of the stress differences in the Cu phase allowed us to infer that the stresses around the central Al filament are hydrostatic when the sample is reversed during the passes. This fact enabled the calculation of the stress-free reference and, consequently, the analysis of the hydrostatic and deviatoric components. Finally, the stresses with the von Mises relation were calculated. Hydrostatic stresses (far from the filaments) and axial deviatoric stresses are zero or compressive for both reversed and non-reversed samples. The reversal of the bar direction slightly changes the overall state within the region of high density of Al filaments, where hydrostatic stresses tend to be tensile, but it seems to be advantageous for avoiding plastification in the regions without Al wires. The finite element analysis revealed the presence of shear stresses; nevertheless, stresses calculated with the von Mises relation show similar trends in the simulation and in the neutron measurements. Microstresses are suggested as a possible reason for the large width of the neutron diffraction peak in the measurement of the radial direction.
|
36903220
|
This study examines the possibilities of applying numerical and physical modeling to the elaboration of technology and design of tools used in the hot forging of needle rails for railroad turnouts. First, a numerical model of a three-stage process for forging a needle from lead was built in order to develop a proper geometry of the tools' working impressions for physical modeling. Based on preliminary results of the force parameters, a decision was made to verify the numerical modeling at 1:4 scale due to forging force values as well as agreement of the numerical and physical modeling results, which was confirmed by the similar courses of forging forces and a comparison of the 3D scan image of the forged lead rail with the CAD model obtained from FEM. The final stage of our research was modeling an industrial forging process in order to determine the preliminary assumptions of this newly developed method of precision forging using a hydraulic press as well as preparing tools to reforge a needle rail from the target material, i.e., 350HT steel with a 60E1A6 profile to the 60E1 profile used in railroad turnouts.
|
36903221
|
Heterogeneous catalysis, although known for over a century, is constantly improved and plays a key role in solving the present problems in chemical technology. Thanks to the development of modern materials engineering, solid supports for catalytic phases having a highly developed surface are available. Recently, continuous-flow synthesis started to be a key technology in the synthesis of high added value chemicals. These processes are more efficient, sustainable, safer and cheaper to operate. The most promising is the use of heterogeneous catalyst with column-type fixed-bed reactors. The advantages of the use of heterogeneous catalyst in continuous flow reactors are the physical separation of product and catalyst, as well as the reduction in inactivation and loss of the catalyst. However, the state-of-the-art use of heterogeneous catalysts in flow systems compared to homogenous ones remains still open. The lifetime of heterogeneous catalysts remains a significant hurdle to realise sustainable flow synthesis. The goal of this review article was to present a state of knowledge concerning the application of Supported Ionic Liquid Phase (SILP) catalysts dedicated for continuous flow synthesis.
|
36903222
|
This study aimed to fabricate a glass ionomer cement/diopside (GIC/DIO) nanocomposite to improve its mechanical properties for biomaterials applications. For this purpose, diopside was synthesized using a sol-gel method. Then, for preparing the nanocomposite, 2, 4, and 6 wt% diopside were added to a glass ionomer cement (GIC). Subsequently, X-ray diffraction (XRD), differential thermal analysis (DTA), scanning electron microscopy (SEM), and Fourier transform infrared spectrophotometry (FTIR) analyses were used to characterize the synthesized diopside. Furthermore, the compressive strength, microhardness, and fracture toughness of the fabricated nanocomposite were evaluated, and a fluoride-releasing test in artificial saliva was also applied. The highest concurrent enhancements of compressive strength (1155.7 MPa), microhardness (148 HV), and fracture toughness (5.189 MPa·m
|
36903223
|
The reaction-diffusion equation approach, which solves differential equations of the development of density distributions of mobile and immobile dislocations under mutual interactions, is a method widely used to model the dislocation structure formation. A challenge in the approach is the difficulty in the determination of appropriate parameters in the governing equations because deductive (bottom-up) determination for such a phenomenological model is problematic. To circumvent this problem, we propose an inductive approach utilizing the machine-learning method to search a parameter set that produces simulation results consistent with experiments. Using a thin film model, we performed numerical simulations based on the reaction-diffusion equations for various sets of input parameters to obtain dislocation patterns. The resulting patterns are represented by the following two parameters; the number of dislocation walls (p2), and the average width of the walls (p3). Then, we constructed an artificial neural network (ANN) model to map between the input parameters and the output dislocation patterns. The constructed ANN model was found to be able to predict dislocation patterns; i.e., average errors in p2 and p3 for test data having 10% deviation from the training data were within 7% of the average magnitude of p2 and p3. The proposed scheme enables us to find appropriate constitutive laws that lead to reasonable simulation results, once realistic observations of the phenomenon in question are provided. This approach provides a new scheme to bridge models for different length scales in the hierarchical multiscale simulation framework.
|
36903224
|
This paper presents the results of research on laser lap welding technology of heterogeneous materials and a laser post-heat treatment method to enhance welding performance. The purpose of this study is to reveal the welding principle of austenitic/martensitic dissimilar stainless-steel materials (3030Cu/440C-Nb) and to further obtain welded joints with good mechanical and sealing properties. A natural-gas injector valve is taken as the study case where its valve pipe (303Cu) and valve seat (440C-Nb) are welded. Experiments and numerical simulations were conducted where the welded joints' temperature and stress fields, microstructure, element distribution, and microhardness were studied. The results showed that the residual equivalent stresses and uneven fusion zone tend to concentrate at the joint of two materials within the welded joint. The hardness of the 303Cu side (181.8 HV) is less than the 440C-Nb side (266 HV) in the center of the welded joint. The laser post-heat treatment can reduce the residual equivalent stress in the welded joint and improve the mechanical and sealing properties. The results of the press-off force test and the helium leakage test showed that the press-off force increased from 9640 N to 10,046 N and the helium leakage rate decreased from 3.34 × 10
|
36903226
|
The building and construction industry is a key sector behind the ecological transition in that it is one of the main responsible factors in the consumption of natural resources. Thus, in line with circular economy, the use of waste aggregates in mortars is a possible solution to increase the sustainability of cement materials. In the present paper, polyethylene terephthalate (PET) from bottle scraps (without chemical pretreatment) was used as aggregate in cement mortars to replace conventional sand aggregate (20%, 50% and 80% by weight). The fresh and hardened properties of the innovative mixtures proposed were evaluated through a multiscale physical-mechanical investigation. The main results of this study show the feasibility of the reuse of PET waste aggregates as substitutes for natural aggregates in mortars. The mixtures with bare PET resulted in less fluid than the specimens with sand; this was ascribed to the higher volume of the recycled aggregates with respect to sand. Moreover, PET mortars showed a high tensile strength and energy absorption capacity (with Rf = 1.9 ÷ 3.3 MPa, Rc = 6 ÷ 13 MPa); instead, sand samples were characterized by a brittle rupture. The lightweight specimens showed a thermal insulation increase ranging 65-84% with respect to the reference; the best results were obtained with 800 g of PET aggregate, characterized by a decrease in conductivity of approximately 86% concerning the control. The properties of these environmentally sustainable composite materials may be suitable for non-structural insulating artifacts.
|
36903228
|
The appearance of all-dielectric micro-nano photonic devices constructed from high refractive index dielectric materials offers a low-loss platform for the manipulation of electromagnetic waves. The manipulation of electromagnetic waves by all-dielectric metasurfaces reveals unprecedented potential, such as focusing electromagnetic waves and generating structured light. Recent advances in dielectric metasurfaces are associated with bound states in the continuum, which can be described as non-radiative eigen modes above the light cone supported by metasurfaces. Here, we propose an all-dielectric metasurface composed of elliptic cross pillars arranged periodically and verify that the displacement distance of a single elliptic pillar can control the strength of the light-matter interaction. Specifically, when the elliptic cross pillar is C
|
36903227
|
In this paper, micron-sized TiB
|
36903225
|
In metal halide perovskites, charge transport in the bulk of the films is influenced by trapping and release and nonradiative recombination at ionic and crystal defects. Thus, mitigating the formation of defects during the synthesis process of perovskites from precursors is required for better device performance. An in-depth understanding of the nucleation and growth mechanisms of perovskite layers is crucial for the successful solution processing of organic-inorganic perovskite thin films for optoelectronic applications. In particular, heterogeneous nucleation, which occurs at the interface, must be understood in detail, as it has an effect on the bulk properties of perovskites. This review presents a detailed discussion on the controlled nucleation and growth kinetics of interfacial perovskite crystal growth. Heterogeneous nucleation kinetics can be controlled by modifying the perovskite solution and the interfacial properties of perovskites adjacent to the underlaying layer and to the air interface. As factors influencing the nucleation kinetics, the effects of surface energy, interfacial engineering, polymer additives, solution concentration, antisolvents, and temperature are discussed. The importance of the nucleation and crystal growth of single-crystal, nanocrystal, and quasi-two-dimensional perovskites is also discussed with respect to the crystallographic orientation.
|
36903229
|
The conductor aluminum alloys of Al-0.25wt.%Zr alloyed additionally with X = Er, Si, Hf and Nb were the objects of our investigations. The fine-grained microstructure in the alloys was formed via equal channel angular pressing and rotary swaging. The thermal stability of the microstructure, specific electrical resistivity and microhardness of the novel conductor aluminum alloys were investigated. The mechanisms of nucleation of the Al
|
36903230
|
The optimal mode for ultrasonic welding (USW) of the "PEEK-ED (PEEK)-prepreg (PEI impregnated CF fabric)-ED (PEEK)-PEEK" lap joint was determined by artificial neural network (ANN) simulation, based on the sample of the experimental data expanded with the expert data set. The experimental verification of the simulation results showed that mode 10 (t = 900 ms, P = 1.7 atm, τ = 2000 ms) ensured the high strength properties and preservation of the structural integrity of the carbon fiber fabric (CFF). Additionally, it showed that the "PEEK-CFF prepreg-PEEK" USW lap joint could be fabricated by the "multi-spot" USW method with the optimal mode 10, which can resist the load per cycle of 50 MPa (the bottom HCF level). The USW mode, determined by ANN simulation for the neat PEEK adherends, did not provide joining both particulate and laminated composite adherends with the CFF prepreg reinforcement. The USW lap joints could be formed when the USW durations (
|
36903232
|
Herein, we present the synthesis and electrochemical performance of a comb-like polycaprolactone-based gel electrolyte from acrylate terminated polycaprolactone oligomers and liquid electrolyte for high-voltage lithium metal batteries. The ionic conductivity of this gel electrolyte at room temperature was measured to be 8.8 × 10
|
36903231
|
High-quality, uniaxially oriented, and flexible PbZr
|
36903233
|
Two biopolyol-based foams derived from banana leaves (BL) or stems (BS) were produced, and their compression mechanical behavior and 3D microstructure were characterized. Traditional compression and in situ tests were performed during 3D image acquisition using X-ray microtomography. A methodology of image acquisition, processing, and analysis was developed to discriminate the foam cells and measure their numbers, volumes, and shapes along with the compression steps. The two foams had similar compression behaviors, but the average cell volume was five times larger for the BS foam than the BL foam. It was also shown that the number of cells increased with increasing compression while the average cell volume decreased. Cell shapes were elongated and did not change with compression. A possible explanation for these characteristics was proposed based on the possibility of cell collapse. The developed methodology will facilitate a broader study of biopolyol-based foams intending to verify the possibility of using these foams as green alternatives to the typical petrol-based foams.
|
36903235
|
Modern technological development has made the designing and characterization of materials sophisticated [...].
|
36903234
|
C/C-SiC-(Zr
|
36903237
|
Contact lens materials include polymers that are ionized in the ocular pH condition and are susceptible to protein deposition due to their surface characteristics. Herein, we investigated the effect of the electrostatic state of the contact lens material and protein on protein deposition level using hen egg white lysozyme (HEWL) and bovine serum albumin (BSA) as model proteins and etafilcon A and hilafilcon B as model contact lens materials. Only HEWL deposition on etafilcon A showed a statistically significant pH-dependency (
|
36903236
|
The increasing amount of waste from the vulcanization industry has become a serious environmental challenge. Even the partial reuse of the steel contained in tires as dispersed reinforcement in the production of new building materials may contribute to reducing the environmental impact of this industry while supporting the principle of sustainable development. In this study, the concrete samples were made of Portland cement, tap water, lightweight perlite aggregates, and steel cord fibers. Two different addition of steel cord fibers (1.3% and 2.6% wt. of concrete, respectively) were used. The samples of lightweight concrete based on perlite aggregate with steel cord fiber addition showed a significant increase in compressive (18-48%), tensile (25-52%), and flexural strength (26-41%). Moreover, higher thermal conductivity and thermal diffusivity were reported after incorporating steel cord fibers into the concrete matrix; however, the specific heat values decreased after these modifications. The highest values of thermal conductivity and thermal diffusivity were obtained for samples modified with a 2.6% addition of steel cord fibers and were equal to 0.912 ± 0.002 W/mK and 0.562 ± 0.002 µm
|
36903238
|
Polycaprolactone (PCL) micro- and nanoparticles produced using the electrospraying technique present high drug encapsulation capacity, a controllable surface area, and a good cost-benefit ratio. PCL is also considered a non-toxic polymeric material with excellent biocompatibility and biodegradability. All these characteristics make PCL micro- and nanoparticles a promising material for tissue engineering regeneration, drug delivery, and surface modification in dentistry. In this study, PCL electrosprayed specimens were produced and analyzed to determine their morphology and size. Three PCL concentrations (2, 4, and 6 wt%) and three solvent types (chloroform (CF), dimethylformamide (DMF), and acetic acid (AA)) with various solvent mixtures ratios (1:1 CF/DMF, 3:1 CF/DMF, 100% CF, 1:1 AA/CF, 3:1 AA/CF, and 100% AA) were used while keeping the remaining electrospray parameters constant. SEM images followed by ImageJ analysis showed a change in the morphology and size of the particles among various tested groups. A two-way ANOVA demonstrated a statistically significant interaction (
|
36903239
|
The influence of n-alkanol (C2-C10) water solutions on bubble motion was studied in a wide range of concentrations. Initial bubble acceleration, as well as local, maximal and terminal velocities during motion were studied as a function of motion time. Generally, two types of velocity profiles were observed. For low surface-active alkanols (C2-C4), bubble acceleration and terminal velocities diminished with the increase in solution concentration and adsorption coverage. No maximum velocities were distinguished. The situation is much more complicated for higher surface-active alkanols (C5-C10). In low and medium solution concentrations, bubbles detached from the capillary with acceleration comparable to gravitational acceleration, and profiles of the local velocities showed maxima. The terminal velocity of bubbles decreased with increasing adsorption coverage. The heights and widths of the maximum diminished with increasing solution concentration. Much lower initial acceleration values and no maxima presence were observed in the case of the highest n-alkanol concentrations (C5-C10). Nevertheless, in these solutions, the observed terminal velocities were significantly higher than in the case of bubbles moving in solutions of lower concentration (C2-C4). The observed differences were explained by different states of the adsorption layer in the studied solutions, leading to varying degrees of immobilization of the bubble interface, which generates other hydrodynamic conditions of bubble motion.
|
36903240
|
The transport of liquid sweat in clothing worn close to human skin is very important from the point of view of the thermo-physiological comfort of clothing users. It ensures the drainage of sweat secreted by the human body and condensed on the human skin. In the presented work, knitted fabrics made of cotton and cotton blends with other fibers (elastane, viscose, polyester) were measured in the range of liquid moisture transport using the Moisture Management Tester MMT M290. The fabrics were measured in unstretched form and stretched to 15%. Stretching of the fabrics was performed using the MMT Stretch Fabric Fixture. Obtained results confirmed that stretching significantly changed the values of parameters characterizing the liquid moisture transport in the fabrics. Before stretching, the best liquid sweat transport performance was stated for the KF5 knitted fabric made of 54% cotton and 46% polyester. For this, the greatest value (10 mm) of maximum wetted radius for the bottom surface was obtained. The Overall Moisture Management Capacity (OMMC) of the KF5 fabric was 0.76. This was the highest value among all values obtained for the unstretched fabrics. The lowest value of the OMMC parameter (0.18) was stated for the KF3 knitted fabric. After stretching, the KF4 fabric variant was assessed as the best one. Its OMMC improved from 0.71 before stretching to 0.80 after stretching. The value of the OMMC for the KF5 fabric remained after stretching at the same level (0.77) than before stretching. The most significant improvement was observed for the KF2 fabric. Before stretching, the value of the OMMC parameter for the KF2 fabric was 0.27. After stretching, the OMMC value increased to 0.72. It was also stated that the changes in the liquid moisture transport performance of the investigated knitted fabrics were different for the particular fabrics being investigated. Generally, in all cases, the ability of the investigated knitted fabrics to transfer liquid sweat was improved after stretching.
|
36903241
|
The electromagnetic technique based on magnetic Barkhausen noise (MBN) can be used to control the quality of ball screw shafts non-destructively, although identifying any slight grinding burns independently of induction-hardened depth remains a challenge. The capacity to detect slight grinding burns was studied using a set of ball screw shafts manufactured by means of different induction hardening treatments and different grinding conditions (some of them under abnormal conditions for the purpose of generating grinding burns), and MBN measurements were taken in the whole group of ball screw shafts. Additionally, some of them were tested using two different MBN systems in order to better understand the effect of the slight grinding burns, while Vickers microhardness and nanohardness measurements were taken in selected samples. To detect the grinding burns (both slight anddata intense) with varying depths of the hardened layer, a multiparametric analysis of the MBN signal is proposed using the main parameters of the MBN two-peak envelope. At first, the samples are classified into groups depending on their hardened layer depth, estimated using the intensity of the magnetic field measured on the first peak (H1) parameter, and the threshold functions of two parameters (the minimum amplitude between the peaks of the MBN envelope (MIN) and the amplitude of the second peak (P2)) are then determined to detect the slight grinding burns for the different groups.
|
36903243
|
Airborne and impact sound insulation of composite panels arranged in different configurations were investigated in this study. The use of Fiber Reinforced Polymers (FRPs) in the building industry is growing; however, poor acoustic performance is a critical issue for their general employment in residential buildings. The study aimed to investigate possible methods of improvement. The principal research question involved the development of a composite floor satisfying acoustic expectations in dwellings. The study was based on the results of laboratory measurements. The airborne sound insulation of single panels was too low to meet any requirements. The double structure improved the sound insulation radically at middle and high frequencies but the single number values were still not satisfactory. Finally, the panel equipped with the suspended ceiling and floating screed achieved adequate level of performance. Regarding impact sound insulation, the lightweight floor coverings were ineffective and they even enhanced sound transmission in the middle frequency range. Heavy floating screeds behaved much better but the improvement was too small to satisfy acoustic requirements in residential buildings. The composite floor with a dry floating screed and a suspended ceiling appeared satisfactory with respect to airborne and impact sound insulation; the single number values were R
|
36903242
|
The present work aimed to study the properties of medium-carbon steel during tempering treatment and to present the strength increase of medium-carbon spring steels by strain-assisted tempering (SAT). The effect of double-step tempering and double-step tempering with rotary swaging, also known as SAT, on the mechanical properties and microstructure was investigated. The main goal was to achieve a further enhancement of the strength of medium-carbon steels using SAT treatment. The microstructure consists of tempered martensite with transition carbides in both cases. The yield strength of the DT sample is 1656 MPa, while that of the SAT sample is about 400 MPa higher. On the contrary, plastic properties such as the elongation and reduction in area have lower values after SAT processing, about 3% and 7%, respectively, compared to the DT treatment. Grain boundary strengthening from low-angle grain boundaries can be attributed to the increase in strength. Based on X-ray diffraction analysis, a lower dislocation strengthening contribution was determined for the SAT sample compared to the double-step tempered sample.
|
36903244
|
This paper reports two piezoelectric materials of lead zirconium titanate (PZT) and aluminum nitride (AlN) used to simulate microelectromechanical system (MEMS) speakers, which inevitably suffered deflections as induced via the stress gradient during the fabrication processes. The main issue is the vibrated deflection from the diaphragm that influences the sound pressure level (SPL) of MEMS speakers. To comprehend the correlation between the geometry of the diaphragm and vibration deflection in cantilevers with the same condition of activated voltage and frequency, we compared four types of geometries of cantilevers including square, hexagon, octagon, and decagon in triangular membranes with unimorphic and bimorphic composition by utilizing finite element method (FEM) for physical and structural analyses. The size of different geometric speakers did not exceed 10.39 mm
|