Question: I work at an electronics store and the other day a customer came in who was rebuilding a circuit board. I sold him some resistors, but later he came back in wanting to return some of them because they were only 1% tolerance, and he needed 5%. I'm not an engineer but I have a hobbyist's understanding of electronics, and I was under the impression that there are situations that would call for a more exact value, but never a *less* exact one. Am I mistaken?

Answer: 
There might be a hidden specification in wanting 5% - the circuit might be relying on carbon film (typically 5%, "beige bones") vs metal film (typically 1%, "blue bones") resistors. Carbon film has different behaviour under temporary overloads (in a bad design, a metal film resistor might fail) and looks (which might be relevant if someone is restoring vintage equipment and wants their resistors as beige as they were).
Customers don't know everything, I once returned a suitable product as unsuitable just because I don't know any better.

However customers are always right (tm)

With beer 5% is better than 1%, perhaps your customer was thinking along those lines.