Redox Reaction of Multivalent Ions in Glass Melts
Kim, Kidong (Department of Materials Science and Engineering, Kunsan National University)
https://doi.org/10.4191/kcers.2015.52.2.83
The redox reaction $M^{(x+n)+}+\frac{n}{2}O^{-2}{\rightleftarrows}M^{x+}+\frac{n}{4}O_2$ of multivalent ions in glass melts influences the melting process and final properties of the glass including the fining (removal of bubbles), infrared absorption and homogenization of melts, reaction between metal electrodes and melts or refractory and melts, and transmission and color of glass. In this review paper, the redox behaviors that occur frequently in the glass production process are introduced and the square wave voltammetry (SWV) is described in detail as an in situ method of examining the redox behavior of multivalent ions in the melt state. Finally, some voltammetry results for LCD glass melts are reviewed from the practical viewpoint of SWV.
Redox reaction;Multivalent element;Glass melt;Voltammetry
Supported by : National Research Foundation of Korea (NRF)
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