6 Temperature of ECD 7 Self manufactured glass column Table S3.3 Analytical techniques applied in round 3 Lab Analytical R1 Column Temperatures (°C) Gas Calibration& technique Type Oven program3 Quantification method5 Flow MS rate4 (µL) (mL/min) 001 Magnetic 1 90 (1.2min), 20/min to 140 1 Internal, Tomy et al. [2] HP-1MS Sector 245, 50/min to 300 004 GC-ECNI-LRMS 2 90 (1min), 120/min to 150 1.5 NA 1000 Rtx-200 140, 15/min to 320 (10min) 008 GC-ECNI-LRMS 1 105 (1min), 34/min to 200 0.9 Internal, Castells et al. [3] 1000 190 (1min), 8/min to 250, 40/min to 290 (8min) 009 GC-ECNI-LRMS 1 100 (10min), 10/min to 230 NA, Internal, linear 1000 Rtx-1614 260 (30min) Helium GC-ECNI-LRMS 4 x 1 90 (2min), 15/min to 200 1 External, linear 1000 DB-5MS 325 (10min) 017 Magnetic 2 110, 10/min to 310 120 NA, Argon Internal, Tomy et al. [2] Rxi-5MS Sector
6 Temperature of ECD 7 Self manufactured glass column Table S3.3 Analytical techniques applied in round 3 Lab Analytical technique R1 Column Type (µL) Temperatures (°C) Oven program3 MS Gas Flow rate4 (mL/min) Calibration& Quantification method5 001 Magnetic Sector HP-1MS 1 90 (1.2min), 20/min to 245, 50/min to 300 140 1 Internal, Tomy et al. [2] 004 GC-ECNI-LRMS 1000 Rtx-200 2 90 (1min), 120/min to 140, 15/min to 320 (10min) 150 1.5 NA 008 GC-ECNI-LRMS 1000 1 105 (1min), 34/min to 190 (1min), 8/min to 250, 40/min to 290 (8min) 200 0.9 Internal, Castells et al. [3] 009 GC-ECNI-LRMS 1000 Rtx-1614 1 100 (10min), 10/min to 260 (30min) 230 NA, Helium Internal, linear GC-ECNI-LRMS 1000 DB-5MS 4 x 1 90 (2min), 15/min to 325 (10min) 200 1 External, linear 017 Magnetic Sector Rxi-5MS 2 110, 10/min to 310 120 NA, Argon Internal, Tomy et al. [2]
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