Table S2 Operational characteristics of the electrospray ionization Ion Trap-Mass Spectrometer (ESI-IT-MSn). – Mode Tune Source Trap MS/MS Automatic Mass Precursor Ions Std/Normal Trap Drive 46.8 Scan Begin 50 m/z 4 AutoMS(2) Mode Ion Octopole RF 266.7 Precursor Ions Positive Scan End 300 m/z 1 Polarity Amplitude Vpp AutoMS(>2) Ion 4 5 Source ESI Lens 2 -58.0 V Averages MS(n) Averages Spectra Spectra Type Capillary Accumulation Depth 108.3 V 200000 s 3 Exit Time AutoMS(>2) (Smart) ICC Dry Temp. 350 °C 40000 Auto MS/MS On Target 30.00 Nebulizer ICC On Group Length 5 psi 12.00 abs. Threshold Dry Gas 10000 L/min Auto MS(2) rel. Threshold HV Capillary 4080 V 5.0% Auto MS(2) HV End abs. Threshold 500 V 1000 Plate Offset Auto MS(>2) rel. Threshold Skimmer 33.4 V 5.0% Auto MS(>2) octopole one 10.71 V octopole two 2.24 V
Table S2 – Operational characteristics of the electrospray ionization Ion Trap-Mass Spectrometer (ESI-IT-MSn). Mode Tune Source Trap MS/MS Automatic Mass Mode Std/Normal Trap Drive 46.8 Scan Begin 50 m/z Precursor Ions AutoMS(2) 4 Ion Polarity Positive Octopole RF Amplitude 266.7 Vpp Scan End 300 m/z Precursor Ions AutoMS(>2) 1 Ion Source Type ESI Lens 2 -58.0 V Averages 4 Spectra MS(n) Averages 5 Spectra Capillary Exit 108.3 V Accumulation Time 200000 s Depth AutoMS(>2) 3 Dry Temp. 350 °C (Smart) ICC Target 40000 Auto MS/MS On Nebulizer 30.00 psi ICC On Group Length 5 Dry Gas 12.00 L/min abs. Threshold Auto MS(2) 10000 HV Capillary 4080 V rel. Threshold Auto MS(2) 5.0% HV End Plate Offset 500 V abs. Threshold Auto MS(>2) 1000 Skimmer 33.4 V rel. Threshold Auto MS(>2) 5.0% octopole one 10.71 V octopole two 2.24 V
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