Table S3. List of reported performances over PtSn/Al2O3 catalysts for n-butane dehydrogenation. Loading Initial GHSV amount of Initial Particle C4= Pt and Sn Temp. (ºC) (mL conversion size (nm)/ parameter h-1) metals (%) TOF (s-1) (%) (%)a (wt%) 30.0 (Time on stream: 14.0 (after 0.5: 0.5 530 5400 94 .0 - [1] after 10 120 min) min) 38.0 (Pulse 58.0 (after 0.5: 0.5 530 5400 method: first 83.0 - [2] 20 pulses) pulse) 29 (Time on 4 (after 0.3: 0.3 530 5400 stream: 96.0 - [3] 120 min) 10 min) 41.9 (Time on stream: 21.0 (after 0.5: 0.5 550 18000 83.7 9.3/10.2 [4] after 30 300 min) min) 31.5 (Time on stream: 61.9 (after 0.49: 0.49 530 5400 84.0 - [5] after 10 120 min) min) 39.4 (Time on stream: 28.9 (after 0.5: 0.5 550 18000 89.0 9.7/11.1 [6] after 30 300 min) min) a initial conversion (X0)−final conversion (Xf). ΔX/X0: ΔX: References A.D. Ballarini, P. Zgolicz, I.M.J. Vilella, S.R. de Miguel, A.A. Castro, O.A. Scelza, Appl. Catal. A: Gen. 381 (2010) 83-91. S.R. de Miguel, S.A. Bocanegra, I.M.J. Vilella, A. Guerrero-Ruiz, O.A. Scelza, Catal. Lett. 119 (2007) 5-15. S. Bocanegra, A. Ballarini, P. Zgolicz, O. Scelza, S. de Miguel, Catal. Today 143 (2009) 334-340.
Table S3. List of reported performances over PtSn/Al2O3 catalysts for n-butane dehydrogenation. Loading amount of Pt and Sn metals (wt%) Temp. (ºC) GHSV (mL h-1) Initial conversion (%) Initial C4= (%) parameter (%)a Particle size (nm)/ TOF (s-1) 0.5: 0.5 530 5400 30.0 (Time on stream: after 10 min) 94 .0 14.0 (after 120 min) - [1] 0.5: 0.5 530 5400 38.0 (Pulse method: first pulse) 83.0 58.0 (after 20 pulses) - [2] 0.3: 0.3 530 5400 29 (Time on stream: 10 min) 96.0 4 (after 120 min) - [3] 0.5: 0.5 550 18000 41.9 (Time on stream: after 30 min) 83.7 21.0 (after 300 min) 9.3/10.2 [4] 0.49: 0.49 530 5400 31.5 (Time on stream: after 10 min) 84.0 61.9 (after 120 min) - [5] 0.5: 0.5 550 18000 39.4 (Time on stream: after 30 min) 89.0 28.9 (after 300 min) 9.7/11.1 [6] a ΔX/X0: ΔX: initial conversion (X0)−final conversion (Xf). References A.D. Ballarini, P. Zgolicz, I.M.J. Vilella, S.R. de Miguel, A.A. Castro, O.A. Scelza, Appl. Catal. A: Gen. 381 (2010) 83-91. S.R. de Miguel, S.A. Bocanegra, I.M.J. Vilella, A. Guerrero-Ruiz, O.A. Scelza, Catal. Lett. 119 (2007) 5-15. S. Bocanegra, A. Ballarini, P. Zgolicz, O. Scelza, S. de Miguel, Catal. Today 143 (2009) 334-340.
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