Table S1. Analytical method validation data Recovery (%RSD) at Spiking Retention Collision Collision LOQ level (mg kg-1) Quantifier Qualifier No. Name time Energy Energy (mg transition transition (Min) (V) (V) kg-1) 0.01 0.05 0.10 Dichlorvos 0.008 1 6.15 185.00>93.00 14 14 79.2 (6) 73.3 (13) 83.4 (7) 2 Novaluron 0.009 6.57 335.00>168.00 16 25 97.8 (6) 119.6 (9) – 4-bromo 115.3 3 0.008 6.64 207.90>63.00 25 22 (13) 93.6 (13) 96.9 (10) Disulfoton 108.4 4 0.009 sulfoxide 6.77 125.00>96.95 7 26 (20) 96.5(18) 102.4(14) 5 Dichlobenil 0.010 7.23 170.90>100.00 24 14 71.5 (5) 78.1 (8) 81.8 (6) 98.9 6 Diflubenzuron 0.009 7.25 157.05>141.05 9 25 (10) 77.8 (6) 93.4 (16) 93.0 7 Butylate 0.009 7.97 174.10>146.10 6 8 (18) 71.8 (4) 80.3 (9) 8 Mevinphos 0.010 8.04 192.00>127.00 12 4 85.9 (8) 87.1 (7) 96.8 (9) 9 Chlormephos 0.008 8.16 233.90>121.00 12 6 85.2 (7) 84.3 (9) 91.7 (8)
Table S1. Analytical method validation data No. Name Retention time (Min) Quantifier transition Collision Energy (V) Qualifier transition Collision Energy (V) LOQ (mg kg-1) Recovery (%RSD) at Spiking level (mg kg-1) 0.01 0.05 0.10 1 Dichlorvos 6.15 185.00>93.00 14 14 0.008 79.2 (6) 73.3 (13) 83.4 (7) 2 Novaluron 6.57 335.00>168.00 16 25 0.009 – 97.8 (6) 119.6 (9) 3 4-bromo 6.64 207.90>63.00 25 22 0.008 115.3 (13) 93.6 (13) 96.9 (10) 4 Disulfoton sulfoxide 6.77 125.00>96.95 7 26 0.009 108.4 (20) 96.5(18) 102.4(14) 5 Dichlobenil 7.23 170.90>100.00 24 14 0.010 71.5 (5) 78.1 (8) 81.8 (6) 6 Diflubenzuron 7.25 157.05>141.05 9 25 0.009 98.9 (10) 77.8 (6) 93.4 (16) 7 Butylate 7.97 174.10>146.10 6 8 0.009 93.0 (18) 71.8 (4) 80.3 (9) 8 Mevinphos 8.04 192.00>127.00 12 4 0.010 85.9 (8) 87.1 (7) 96.8 (9) 9 Chlormephos 8.16 233.90>121.00 12 6 0.008 85.2 (7) 84.3 (9) 91.7 (8)
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