Supporting Information for Preparation and reactions of iodobutoxy pinacolborate. Synthesis of substituted alkyl and arylpinacolboronates via iodobutoxy pinacolborate utilizing tetrahydrofuran as the leaving group Chris L. Murphy, Aaron Hall, Emily J. Roberts, Matthew D. Ryan, Jacob W. Clary, and Bakthan Singaram* Department of Chemistry and Biochemistry, University of California, Santa Cruz, 1156 High Street, Santa Cruz, California, 95064 Table of Contents Page 2-(4-Iodobutoxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1) S3 1H, 13C, and 11B-NMR spectrum of Boronates (Table 1) 2-Octyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1a) S6 2-(3-Chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1b) S9 2-(4-Chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1c) S12 2-(3,4-Dichlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1d) S15 2-(3,5-Dichlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1e) S18 2-(4-Ethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1f) S21 4,4,5,5-tetramethyl-2-o-tolyl-1,3,2-dioxaborolane (1g) S24 4,4,5,5-tetramethyl-2-m-tolyl-1,3,2-dioxaborolane (1h) S27
Supporting Information for Preparation and reactions of iodobutoxy pinacolborate. Synthesis of substituted alkyl and arylpinacolboronates via iodobutoxy pinacolborate utilizing tetrahydrofuran as the leaving group Chris L. Murphy, Aaron Hall, Emily J. Roberts, Matthew D. Ryan, Jacob W. Clary, and Bakthan Singaram* Department of Chemistry and Biochemistry, University of California, Santa Cruz, 1156 High Street, Santa Cruz, California, 95064 Table of Contents 2-(4-Iodobutoxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1) 1H, 13C, and 11B-NMR spectrum of Boronates (Table 1) 2-Octyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1a) 2-(3-Chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1b) 2-(4-Chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1c) 2-(3,4-Dichlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1d) 2-(3,5-Dichlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1e) 2-(4-Ethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1f) 4,4,5,5-tetramethyl-2-o-tolyl-1,3,2-dioxaborolane (1g) 4,4,5,5-tetramethyl-2-m-tolyl-1,3,2-dioxaborolane (1h) Page S3 S6 S9 S12 S15 S18 S21 S24 S27
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