0 2 Ketones, aldehydes: bonding mode 2 -1 2 CH3, CH2R bonding mode 1 -1 2 CH3, CH2R (1 to each M) assuming no agostic M-H interactions -1 2 Aryl: C6H5 terminal 1 -1 2 Alkenyl (vinyl), alkynyl: CH=CH2, CCH 1 terminal -1 4 Alkenyl (vinyl): CH=CH2 terminal 2 -1 4 Alkenyl (vinyl), alkynyl: CH=CH2, CCH (2 to ,2 terminal each M) +1 2 Cyclopropenyl: C3H3 terminal 3 -1 4 -1 4 Allyl: C3H5 3 terminal -1 2 Allyl: C3H5 1 terminal Pentadienyl: C5H7 -1 6 5 terminal Pentadienyl: C5H7 -1 4 3 terminal Pentadienyl: C5H7 -1 2 terminal 1 Cyclopentadienyl: C5H5 -1 6 5
Ketones, aldehydes: 2 bonding mode 0 2 CH3, CH2R 1 bonding mode -1 2 CH3, CH2R -1 2 (1 to each M) assuming no agostic M-H interactions Aryl: C6H5 1 terminal -1 2 Alkenyl (vinyl), alkynyl: CH=CH2, CCH 1 terminal -1 2 Alkenyl (vinyl): CH=CH2 2 terminal -1 4 Alkenyl (vinyl), alkynyl: CH=CH2, CCH ,2 terminal -1 4 (2 to each M) Cyclopropenyl: C3H3 3 terminal +1 -1 2 4 Allyl: C3H5 3 terminal -1 4 Allyl: C3H5 1 terminal -1 2 Pentadienyl: C5H7 5 terminal -1 6 Pentadienyl: C5H7 3 terminal -1 4 Pentadienyl: C5H7 1 terminal -1 2 Cyclopentadienyl: C5H5 5 -1 6
chap01-Intro_0.docx