DMSO at 25.0 0.1oC. Figure S9. Plot of [amine] (A) and vs [amine] (B) for the reaction of kobsdvs. kobsd/[amine] 1-(4-chlorophenoxy)-2,4-dinitrobenzene (1f) with piperidinein 80mol% H2O / 20mol% DMSO at 25.0 0.1oC igure S10. Plot of [amine] (A) and vs [amine] (B) for the reaction of kobsdvs. kobsd/[amine] 1-phenoxy-2,4-dinitrobenzene (1g) with piperidinein 80mol% H2O / 20mol% DMSO at 25.0 0.1oC. Plot of [amine] (A) and vs [amine] (B) for the reaction Figure S11. kobsdvs. kobsd/[amine] of 1-(4-methylphenoxy)-2,4-dinitrobenzene (1h) with piperidinein 80mol% H2O / 20mol% DMSO at 25.0 0.1oC. Hammett plots correlated with (A) and (B) for the uncatalyzed Figure S12. σY− σYo reactions of 1-(Y-substituted-phenoxy)-2,4-dinitrobenzenes (1a-1h) with piperidinein 80 mol% H2O / 20 mol% DMSO at 25.0 ± 0.1 °C.
DMSO at 25.0 0.1oC. Figure S9. Plot of kobsdvs. [amine] (A) and kobsd/[amine] vs [amine] (B) for the reaction of 1-(4-chlorophenoxy)-2,4-dinitrobenzene (1f) with piperidinein 80mol% H2O / 20mol% DMSO at 25.0 0.1oC igure S10. Plot of kobsdvs. [amine] (A) and kobsd/[amine] vs [amine] (B) for the reaction of 1-phenoxy-2,4-dinitrobenzene (1g) with piperidinein 80mol% H2O / 20mol% DMSO at 25.0 0.1oC. Figure S11. Plot of kobsdvs. [amine] (A) and kobsd/[amine] vs [amine] (B) for the reaction of 1-(4-methylphenoxy)-2,4-dinitrobenzene (1h) with piperidinein 80mol% H2O / 20mol% DMSO at 25.0 0.1oC. Figure S12. Hammett plots correlated with σY− (A) and σYo (B) for the uncatalyzed reactions of 1-(Y-substituted-phenoxy)-2,4-dinitrobenzenes (1a-1h) with piperidinein 80 mol% H2O / 20 mol% DMSO at 25.0 ± 0.1 °C.
cjc-2017-0454%20suppla.docx