Figure S8. CV for HTM02 acquired at varying scan rates. The voltage axis is normalized such that the onset of oxidation of ferrocene (Fc) is equal to zero. An estimation of the HOMO and LUMO energy levels were obtained by comparing the onsets of oxidation and reduction, respectively, of HTM02 (from the scan acquired at 100 mV/s with = 0.26 eV and = Eox Ered eV) to the normal hydrogen electrode (NHE), assuming the ionization energy of Fc to be −1.90 4.80 eV below the vacuum level.12 CV plots for HTM03 acquired at varying scan rates. The voltage axis is normalized Figure S9. such that the onset of oxidation of ferrocene (Fc) is equal to zero. An estimation of the HOMO and LUMO energy levels were obtained by comparing the onsets of oxidation and reduction, respectively, of HTM03 (from the scan acquired at 100 mV/s with = 0.26 eV and = Eox Ered eV) to the normal hydrogen electrode (NHE), assuming the ionization energy of Fc to be −1.44 4.80 eV below the vacuum level.12 Figure S10. CV plots for HTM04 acquired at varying scan rates. The voltage axis is normalized such that the onset of oxidation of ferrocene (Fc) is equal to zero. An estimation of the HOMO and LUMO energy levels were obtained by comparing the onsets of oxidation and reduction, respectively, of HTM04 (from the scan acquired at 100 mV/s with = 0.23 eV and = Eox Ered eV) to the normal hydrogen electrode (NHE), assuming the ionization energy of Fc to be −1.43 4.80 eV below the vacuum level.12 11. References
Figure S8. CV for HTM02 acquired at varying scan rates. The voltage axis is normalized such that the onset of oxidation of ferrocene (Fc) is equal to zero. An estimation of the HOMO and LUMO energy levels were obtained by comparing the onsets of oxidation and reduction, respectively, of HTM02 (from the scan acquired at 100 mV/s with Eox = 0.26 eV and Ered = −1.90 eV) to the normal hydrogen electrode (NHE), assuming the ionization energy of Fc to be 4.80 eV below the vacuum level.12 Figure S9. CV plots for HTM03 acquired at varying scan rates. The voltage axis is normalized such that the onset of oxidation of ferrocene (Fc) is equal to zero. An estimation of the HOMO and LUMO energy levels were obtained by comparing the onsets of oxidation and reduction, respectively, of HTM03 (from the scan acquired at 100 mV/s with Eox = 0.26 eV and Ered = −1.44 eV) to the normal hydrogen electrode (NHE), assuming the ionization energy of Fc to be 4.80 eV below the vacuum level.12 Figure S10. CV plots for HTM04 acquired at varying scan rates. The voltage axis is normalized such that the onset of oxidation of ferrocene (Fc) is equal to zero. An estimation of the HOMO and LUMO energy levels were obtained by comparing the onsets of oxidation and reduction, respectively, of HTM04 (from the scan acquired at 100 mV/s with Eox = 0.23 eV and Ered = −1.43 eV) to the normal hydrogen electrode (NHE), assuming the ionization energy of Fc to be 4.80 eV below the vacuum level.12 11. References
cjc-2015-0427-supplement-1.docx