v6 1477 1477 0.25 1477 1477 -0.18 v7 1492 1492 0.35 1492 1300 -0.28 v8 1507 1507 0.18 1507 1507 -0.14 v9 1513 1513 0.245 1513 1513 -0.15 (cm-1) 300 300 Γ (cm-1) 450 450 Θ 12400 13700 Ε00(cm1) 2.38 1.75 Μ1(Å) HMW-CF-1 HMW-CF-2 v1 1327 1327 0.06 1327 1327 0.05 1335 1335 0.165 1335 1335 -0.20 v2 v3 1371 1371 0.255 1371 1371 -0.18 v4 1391 1391 0.23 1391 1391 -0.10 v5 1414 1414 0.27 1414 1414 -0.11 v6 1477 1477 0.25 1477 1477 -0.15 v7 1492 1300 0.42 1492 1300 -0.50 v8 1507 1507 0.07 1507 1507 0.10 v9 1513 1513 0.35 1513 1513 -0.37 (cm-1) 350 350 Γ (cm-1) 350 350 Θ 12300 13600 Ε00(cm1) 2.79 1.70 Μ1(Å) aground state frequency bexcited state frequency cnon-dimensional displacement between the ground and excited potential Figure S7.3 Experimental (solid black line) and calculated (dashed red line) absorption cross sections of C3 LMW and HMW polymers in 1,2-dichlorobenzene (upper plots) and chloroform (lower plots) when one dipole-allowed transition is included in the model. Experimental (points) and calculated (solid line) Raman excitation profiles for Figure S7.4 the 1492 cm-1 mode of LMW and HMW C3 polymer in 1,2-dichlorobenzene (upper plots) and chloroform (lower plots) using a single dipole-allowed transition in the RRIA.
v6 1477 1477 0.25 1477 1477 -0.18 v7 1492 1492 0.35 1492 1300 -0.28 v8 1507 1507 0.18 1507 1507 -0.14 v9 1513 1513 0.245 1513 1513 -0.15 Γ (cm-1) 300 300 Θ (cm-1) 450 450 Ε00(cm1) 12400 13700 Μ1(Å) 2.38 1.75 HMW-CF-1 HMW-CF-2 v1 1327 1327 0.06 1327 1327 0.05 v2 1335 1335 0.165 1335 1335 -0.20 v3 1371 1371 0.255 1371 1371 -0.18 v4 1391 1391 0.23 1391 1391 -0.10 v5 1414 1414 0.27 1414 1414 -0.11 v6 1477 1477 0.25 1477 1477 -0.15 v7 1492 1300 0.42 1492 1300 -0.50 v8 1507 1507 0.07 1507 1507 0.10 v9 1513 1513 0.35 1513 1513 -0.37 Γ (cm-1) 350 350 Θ (cm-1) 350 350 Ε00(cm1) 12300 13600 Μ1(Å) 2.79 1.70 aground state frequency bexcited state frequency cnon-dimensional displacement between the ground and excited potential Figure S7.3 Experimental (solid black line) and calculated (dashed red line) absorption cross sections of C3 LMW and HMW polymers in 1,2-dichlorobenzene (upper plots) and chloroform (lower plots) when one dipole-allowed transition is included in the model. Figure S7.4 Experimental (points) and calculated (solid line) Raman excitation profiles for the 1492 cm-1 mode of LMW and HMW C3 polymer in 1,2-dichlorobenzene (upper plots) and chloroform (lower plots) using a single dipole-allowed transition in the RRIA.
20160331_SuppInfo_postReview3.docx