7 29aug-3sept Chemistry of xenon Alkanes and cycloalkanes Relationship between compounds. critical constant and Isomerism in alkanes, vander waals sources, methods of constants, the law of formation (with special corresponding states reference to Wurtz reduced equation of reaction, Kolbe reaction, state. Corey-House reaction and decarboxylation of carboxylic acids) 8 5sept-10sept Structure and bonding Physical properties and Molecular velocities: in Xenon compounds chemical reaction of Maxwell’s distribution Comparative study alkanes. Mechanism of of molecular free radical halogenations velocities, collision of alkanes :orientation, number , diameter, reactivity and sensitivity Diagonal Mean free path , 9 12sept-17sept relationships, salient nomenclature, methods of liquefaction of gases. features of hydrides formation, chemical reactions 10 19sept-24sept Solvation and Baeyer’s strain theory and Chemical Kinetics: complexation its limitations. Ring strain Introduction, factors tendencies including in small rings affecting rate of their function in (cyclopropane and reaction, molecularity biosystems cyclobutane), theory of and order of reaction, strainless rings. The case of cyclopropane ring : banana bonds 11 26sept-29sept Revision and test Revision and test Mathematical characteristics of simple chemical reactions: zero order, first order 12 18oct-22oct percentage ionic Stereochemistry: concept Mathematical character from dipole of isomerism, optical characteristics of moment and isomerism: element of simple chemical electronegativity symmetry, molecular reactions: second difference chirality, enantiomers, order and pseudo stereogenic centre, optical order, activity, properties of enantiomers.
7 29aug-3sept Chemistry of xenon compounds. Alkanes and cycloalkanes Isomerism in alkanes, sources, methods of formation (with special reference to Wurtz reaction, Kolbe reaction, Corey-House reaction and decarboxylation of carboxylic acids) Relationship between critical constant and vander waals constants, the law of corresponding states reduced equation of state. 8 5sept-10sept Structure and bonding in Xenon compounds Comparative study Physical properties and chemical reaction of alkanes. Mechanism of free radical halogenations of alkanes :orientation, reactivity and sensitivity Molecular velocities: Maxwell’s distribution of molecular velocities, collision number , diameter, 9 12sept-17sept Diagonal relationships, salient features of hydrides methods of formation, chemical reactions Mean free path , liquefaction of gases. 10 19sept-24sept Solvation and complexation tendencies including their function in biosystems Baeyer’s strain theory and its limitations. Ring strain in small rings (cyclopropane and cyclobutane), theory of strainless rings. The case of cyclopropane ring : banana bonds Chemical Kinetics: Introduction, factors affecting rate of reaction, molecularity and order of reaction, 11 26sept-29sept Revision and test Revision and test Mathematical characteristics of simple chemical reactions: zero order, first order 12 18oct-22oct percentage ionic character from dipole moment and electronegativity difference Stereochemistry: concept of isomerism, optical isomerism: element of symmetry, molecular chirality, enantiomers, stereogenic centre, optical activity, properties of enantiomers. Mathematical characteristics of simple chemical reactions: second order and pseudo order, nomenclature,
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