Supporting information of Liquid Organic Hydrogen Carriers Teng Hea,*, Qijun Peia,b, Ping Chena,c,* a. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China b. University of the of the Chinese Academy of Sciences, Beijing 100049, China c. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457, Zhongshan Road, Dalian 116023, Liaoning, China * Corresponding author: Tel: +86 411 84379583; Fax: +86 411 84379905 E-mail: (T. He); (P. Chen); Data in Figure 5 Number Organic hydrogen carriers Hydrogen capacity mol-1 ΔH(kJ (wt%) H2) 1 1.3 71.4 2,3-dihydro-1H-phosphindol-1-ol 2 1.5 68.9 2,3-dihydro-1H-benzo[b]silole 3 7.4 54.6 Tetracosahydrocoronene 4 5.7 105.5 cyclopentane 5 7.1 68.6 Cyclohexane 6 6.1 68.3 Methylcyclohexane 7 7.2 63.4 Decalin 66.4 cis (63.9) trans 8 7.2 67.2 Bicyclohexyl 9 5.6 55.4 pyrrolidine 10 7.1 63.8 piperidine 11 4 40.7 12 6.3 26.9 octahydro-1H-purine 13 6.6 32.3 14 5.6 39.9 Imidazolidine 15 7 60.1 Hexahydropyrimidine 16 6.7 51.2 Dodecahydrocarbazole
Supporting information of Liquid Organic Hydrogen Carriers Teng Hea,*, Qijun Peia,b, Ping Chena,c,* a. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China b. University of the of the Chinese Academy of Sciences, Beijing 100049, China c. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457, Zhongshan Road, Dalian 116023, Liaoning, China * Corresponding author: Tel: +86 411 84379583; Fax: +86 411 84379905 E-mail: (T. He); (P. Chen); Data in Figure 5 Number Organic hydrogen carriers Hydrogen capacity (wt%) ΔH(kJ mol-1 H2) 1 2,3-dihydro-1H-phosphindol-1-ol 1.3 71.4 2 2,3-dihydro-1H-benzo[b]silole 1.5 68.9 3 Tetracosahydrocoronene 7.4 54.6 4 cyclopentane 5.7 105.5 5 Cyclohexane 7.1 68.6 6 Methylcyclohexane 6.1 68.3 7 Decalin cis trans 7.2 63.4 66.4 (63.9) 8 Bicyclohexyl 7.2 67.2 9 pyrrolidine 5.6 55.4 10 piperidine 7.1 63.8 11 4 40.7 12 octahydro-1H-purine 6.3 26.9 13 6.6 32.3 14 Imidazolidine 5.6 39.9 15 Hexahydropyrimidine 7 60.1 16 Dodecahydrocarbazole 6.7 51.2
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