and C-C inter-ring stretch TT and DPP N-CH3 stretch in DPP, and C-C stretch 1335 1376 1373 between TT and DPP on both sides C-N stretch and C=C s 1371 1405 stretch between rings in 1408 DPP C=C stretch in TT and 1391 1426 stretch and CH3 1426 umbrella mode in DPP C=C as stretch (one C=C stretch in TT ring) and C-H bend 1414 1463 (between rings) and CH3 1456 in TT and DPP CH3 umbrella mode in DPP umbrella mode TT C=C s stretch TT C=C stretch (one 1477 1523 1524 (opposite sides C=C on each side of DPP) opposite rings) TT C=C s stretch (one 1492 1534 1532 CH2 in CH3 DPP δ C=C on each side of T) TT C=C s stretch 1507 1534 (opposite sides opposite rings) DPP C=C s stretch 1513 1560 (opposite sides opposite 1561 rings) as: symmetric, bend δ: Table S7.2Absolute resonance Raman Cross Sections (σR) for the vibrational modes of included in RRIA analysis. σR(737 σR(637 Transition σR(683 σR(737 σR(683 σR(637 nm) nm) (cm-1) nm) nm) nm) nm) (x10-9 Å2) (x10-9 Å2)
and C-C inter-ring stretch TT and DPP 1335 1376 N-CH3 stretch in DPP, and C-C stretch between TT and DPP on both sides 1373 1371 1405 C-N stretch and C=C s stretch between rings in DPP 1408 1391 1426 C=C stretch in TT and stretch and CH3 umbrella mode in DPP 1426 1414 1463 C=C stretch in TT (between rings) and CH3 umbrella mode in DPP 1456 C=C as stretch (one ring) and C-H bend in TT and DPP CH3 umbrella mode 1477 1523 TT C=C stretch (one C=C on each side of DPP) 1524 TT C=C s stretch (opposite sides opposite rings) 1492 1534 TT C=C s stretch (one C=C on each side of T) 1532 CH2 δ in CH3 DPP 1507 1534 TT C=C s stretch (opposite sides opposite rings) 1513 1560 DPP C=C s stretch (opposite sides opposite rings) 1561 as: symmetric, δ: bend Table S7.2Absolute resonance Raman Cross Sections (σR) for the vibrational modes of included in RRIA analysis. Transition (cm-1) σR(737 nm) (x10-9 Å2) σR(683 nm) σR(637 nm) (x10-9 Å2) σR(737 nm) σR(683 nm) σR(637 nm)
20160331_SuppInfo_postReview3.docx