Lithium (Li) Calcium carbide (CaC2) Organic acid halides and hydrides of low Alkali Metal Amides: molecular weight. Alkali Metal Hydrides: Silver amides (Ag2NH) Cuprous nitride (Cu3N) Cadmium amide (Cd(NH2)2) Lithium aluminum hydrides (LAH) Sodium amide (NaNH2) Sodium borohydride (NaBH4) Potassium amide (KNH2) (NOTE: the latter two Sodium hydride (NaH) chemicals under certain conditions). Potassium hydride (KH) Calcium hydride (CaH) Halides of Non-Metals: Metal Alkyls: Boron trichloride (BCI3) Alkylithiums trifluroide (BF3) Aryllithiums Phosphorus trichloride (PCI3) Trialkylaluminums Silicon tetrachloride (SiCl4) Sulfur monochloride (S2Cl2) Anhydrous Metal Halide: Phosphorus oxychloride (OPCl3) Aluminum chloride Titanium tetrachloride (TiCl4) Others: Zirconium tetrachloride (ZrCl4) Stannic chloride (SnCl4) Phosphorus pentaoxide (P2O5) EXAMPLES OF PYROHORIC CHEMICALS: Grignard Reagents: Metal Hydrides: (RMgX) Sodium hudride (HaH) Alkyls and Aryls: Non-Metal hydrides: (RLi) (RNa) Diborane (B2H6) (R3AL) Phosphine (PH3) (R2Zn) Arsine (AsH3) boranes Carbonyls: Non-Metal Alklys: Nickel tetracarbinyl (Ni(CO)4) Iron pentacarbonyl (Fe(CO)5) (R3B) Cobalt carbonyl (Co3(CO)8) (R3P) (R3As) Alkali Metals: Potassium (K) Sodium (Na) White phosphorus Powders (especially when finely divided):
Lithium (Li) Alkali Metal Amides: Silver amides (Ag2NH) Cuprous nitride (Cu3N) Cadmium amide (Cd(NH2)2) Sodium amide (NaNH2) Potassium amide (KNH2) (NOTE: the latter two chemicals under certain conditions). Halides of Non-Metals: Boron trichloride (BCI3) trifluroide (BF3) Phosphorus trichloride (PCI3) Silicon tetrachloride (SiCl4) Sulfur monochloride (S2Cl2) Phosphorus oxychloride (OPCl3) Others: Phosphorus pentaoxide (P2O5) Calcium carbide (CaC2) Organic acid halides and hydrides of low molecular weight. Alkali Metal Hydrides: Lithium aluminum hydrides (LAH) Sodium borohydride (NaBH4) Sodium hydride (NaH) Potassium hydride (KH) Calcium hydride (CaH) Metal Alkyls: Alkylithiums Aryllithiums Trialkylaluminums Anhydrous Metal Halide: Aluminum chloride Titanium tetrachloride (TiCl4) Zirconium tetrachloride (ZrCl4) Stannic chloride (SnCl4) EXAMPLES OF PYROHORIC CHEMICALS: Grignard Reagents: (RMgX) Alkyls and Aryls: (RLi) (RNa) (R3AL) (R2Zn) Carbonyls: Nickel tetracarbinyl (Ni(CO)4) Iron pentacarbonyl (Fe(CO)5) Cobalt carbonyl (Co3(CO)8) Alkali Metals: Metal Hydrides: Sodium hudride (HaH) Non-Metal hydrides: Diborane (B2H6) Phosphine (PH3) Arsine (AsH3) boranes Non-Metal Alklys: (R3B) (R3P) (R3As) Potassium (K) Sodium (Na) White phosphorus Powders (especially when finely divided):
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