HMBC (500 MHz) spectrum of in Supplementary Figure 19. 6 3. Supplementary References 1 Tsunematsu, Y. Distinct mechanisms for spiro-carbon formation reveal et al. biosynthetic pathway crosstalk. 9, 818–825 (2013). Nat. Chem. Biol. 2 Sato, M. Involvement of lipocalin-like CghA in decalin-forming stereoselective et al. intramolecular [4+2] cycloaddition. 16, 2294–2298 (2015). ChemBioChem, 3 Lee, J. C., Lobkivsky, N, P., N. B., Strobel, G. & Clardy, J. Subglutinols A and B: Immunosuppressive compounds from the endophytic fungus Fusarium subglutinans. 60, 7076–7077 (1995). J. Org. Chem.
Supplementary Figure 19. HMBC (500 MHz) spectrum of 6 in 3. Supplementary References 1 Tsunematsu, Y. et al. Distinct mechanisms for spiro-carbon formation reveal biosynthetic pathway crosstalk. Nat. Chem. Biol. 9, 818–825 (2013). 2 Sato, M. et al. Involvement of lipocalin-like CghA in decalin-forming stereoselective intramolecular [4+2] cycloaddition. ChemBioChem, 16, 2294–2298 (2015). 3 Lee, J. C., Lobkivsky, N, P., N. B., Strobel, G. & Clardy, J. Subglutinols A and B: Immunosuppressive compounds from the endophytic fungus Fusarium subglutinans. J. Org. Chem. 60, 7076–7077 (1995).
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