Refer to the Supplemental Guidance document associated with this SAP template for more information. Table 4 Monitoring Parameter Suite, Sample Handling, Analysis & Preservation – Required Holding Preferred Alternate Parameter Reporting Time Bottle Preservative Method Method Limit ug/L Days Water Sample - Common Ions, Physical Parameters, Miscellaneous Total Suspended A2540 D 4000 7 Solids (TSS) Total Dissolved Solids A2540 C 4000 7 (TDS) Volatile Suspended A2540 E 4000 7 Solids (VSS) 1000 ml Alkalinity (Bicarb., HDPE/ 500 ≤6oC A2320 B EPA 310.2 1000 14 Carb.) ml HDPE Sulfate EPA 300.0 A4110 B 50 28 Chloride EPA 300.0 A4110 B 50 28 Bromide EPA 300.0 A4110 B 50 28 A4110 Fluoride EPA 300.0 50 28 B/A4500-F-B 1 MPN/100 100 ml E. Coli A9223 B EPA 160.4 6 hrs ≤10oC ml HDPE Biochemical Oxygen 1000 ml B 2000 2 ≤6oC Demand (BOD) HDPE Carbonaceous 1000 ml Biochemical Oxygen A5210 B EPA 405.1 2 ≤6oC HDPE Demand (CBOD) Dissolved Organic 125ml Filt. 0.45 um, B 500 28 Carbon (DOC) Glass H2SO4, ≤6oC Total Organic Carbon 125ml A5310 C 500 28 H2SO4, ≤6oC (TOC) Glass Zinc Acetate + 250 ml Sulfide A4500-S2 D 1000 7 NaOH to pH >9, HDPE ≤6oC Sample - Nutrients Total Persulfate (28d HT), ≤6oC A4500-N C A4500-N B 40 28 HDPE Nitrogen (TPN) Freeze (45d HT) Dissolved 250ml Filt. 0.45 um, EPA 365.1 A4500-P F 1 2 Orthophosphate as P HDPE ≤6oC Total Phosphorus as EPA 365.1 A4500-P F 3 P 250 ml H2SO4 , or ≤6oC Nitrate-Nitrite as N EPA 353.2 A4500-NO3 F 10 28 HDPE Freeze A4500-NH3 Total Ammonia as N EPA 350.1 50 B,C,D,E,or G
Refer to the Supplemental Guidance document associated with this SAP template for more information. Table 4 – Monitoring Parameter Suite, Sample Handling, Analysis & Preservation Parameter Preferred Method Alternate Method Required Reporting Limit ug/L Holding Time Days Bottle Preservative Water Sample - Common Ions, Physical Parameters, Miscellaneous Total Suspended Solids (TSS) A2540 D 4000 7 1000 ml HDPE/ 500 ml HDPE ≤6oC Total Dissolved Solids (TDS) A2540 C 4000 7 Volatile Suspended Solids (VSS) A2540 E 4000 7 Alkalinity (Bicarb., Carb.) A2320 B EPA 310.2 1000 14 Sulfate EPA 300.0 A4110 B 50 28 Chloride EPA 300.0 A4110 B 50 28 Bromide EPA 300.0 A4110 B 50 28 Fluoride EPA 300.0 A4110 B/A4500-F-B 50 28 E. Coli A9223 B EPA 160.4 1 MPN/100 ml 6 hrs 100 ml HDPE ≤10oC Biochemical Oxygen Demand (BOD) B 2000 2 1000 ml HDPE ≤6oC Carbonaceous Biochemical Oxygen Demand (CBOD) A5210 B EPA 405.1 2 1000 ml HDPE ≤6oC Dissolved Organic Carbon (DOC) B 500 28 125ml Glass Filt. 0.45 um, H2SO4, ≤6oC Total Organic Carbon (TOC) A5310 C 500 28 125ml Glass H2SO4, ≤6oC Sulfide A4500-S2 D 1000 7 250 ml HDPE Zinc Acetate + NaOH to pH >9, ≤6oC Sample - Nutrients Total Persulfate Nitrogen (TPN) A4500-N C A4500-N B 40 28 HDPE ≤6oC (28d HT), Freeze (45d HT) Dissolved Orthophosphate as P EPA 365.1 A4500-P F 1 2 250ml HDPE Filt. 0.45 um, ≤6oC Total Phosphorus as P EPA 365.1 A4500-P F 3 28 250 ml HDPE H2SO4 , ≤6oC or Freeze Nitrate-Nitrite as N EPA 353.2 A4500-NO3 F 10 Total Ammonia as N EPA 350.1 A4500-NH3 B,C,D,E,or G 50