cheletropic reactions are a subclass of cycloadditions. what sets cheletropic reactions apart is that on one of the reagents, both new bonds are being made to the same atom. a few examples are shown to the right in figure 1. in the first case, the single atom is the carbon atom in the carbonyl group. that carbon atom ends up in carbon monoxide. the end result is making two new bonds to one atom. the first two examples are known as "cheletropic extrusions" because a small stable molecule is given off in the reaction. the driving force for these reactions is often the entropic benefit of releasing a gas (e.g. co or n2).