It is the same XV that faced Fiji in their opening game of the tournament.
Bernard Foley returns at fly-half over Quade Cooper, with Michael Hooper alongside David Pocock in the back row and Matt Giteau at inside-centre.
Australia trail Wales in Pool A after two victories, while an England defeat would see the hosts all but eliminated.
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England have recalled centre Jonathan Joseph in place of Sam Burgess, while number eight Ben Morgan and lock Joe Launchbury also start.
Morgan believes the Wallabies' forwards will have "doubts", with the 26-17 defeat by England at Twickenham last November, fresh in their memories.
But Australia coach Michael Cheika responded by saying his side would not be "looking backwards" at previous matches between the sides.
"I know they think we are weak in the forwards, they are saying it out loud. They have stuck it to us the last couple of times we have played," he said.
"The only place we can show the difference is on the field on Saturday night, that is where we will show our colours. Talk is cheap."
Australia's eight-man replacements' bench will also be confirmed later.
Wales, who beat England 28-25 on Saturday and are second in the pool, beat Fiji 23-13 at the Millennium Stadium on Thursday to head the group.
The Wallabies squad has been hit with injuries, with lock Will Skelton and number eight Wycliff Palu ruled out of the tournament after being hurt against Uruguay.
Sam Carter and James Hanson have replaced them.
"This selection has been really clear on where we must improve and the level we must be at to compete with England," added Cheika.
"We know that it's going to be a very tough challenge."
Australia: Israel Folau; Adam Ashley-Cooper, Tevita Kuridrani, Matt Giteau, Rob Horne; Bernard Foley, Will Genia; Scott Sio, Stephen Moore, Sekope Kepu; Kane Douglas, Rob Simmons; Scott Fardy, Michael Hooper, David Pocock.
Replacements: Tatafu Polota-Nau, James Slipper, Greg Holmes, Dean Mumm, Ben McCalman, Nick Phipps, Matt Toomua, Kurtley Beale.

Iselle made landfall early on Friday morning on the chain's Big Island, shortly after it was downgraded from hurricane to tropical storm.
But Hurricane Julio, a Category 3 storm with winds of more than 120mph, is about 1,000 miles (1,609km) away.
Hawaiian officials have urged residents to stock up on emergency supplies.
The last cyclone to hit Hawaii, Hurricane Iniki in 1992, killed six and caused $2.4bn (Â£1.4bn) in damage.
Five to eight inches of rain are forecast, along with heavy winds and potential flash flooding in some parts of the state.
The storm was weakening as it hit the terrain of the eastern-most island of Hawaii, also known as the Big Island, according to Chris Brenchley, a National Weather Service meteorologist in Honolulu.
"As wind blows into the terrain, the terrain kind of redirects the wind," he said.
The state's department of emergency management has asked residents to prepare a seven-day emergency kit, including non-perishable food and water.
Hawaii's remoteness from the mainland makes it hard to get emergency supplies to the state. Stores have had to quickly restock bottled water and other supplies.
The storm has already knocked out power for more than 18,000 people on the Big Island, according to the Honolulu Star-Advertiser. Another 2,700 were without power on the island of Maui.
At least 50 flights from major airlines were canceled on Thursday and an inter-island airline cancelled all of its flights on Friday.
Rudy Cruz and Ashley Dochnahl from California told the Associated Press they had attempted to fly back early but failed to secure a flight.
"We were trying to beat it, but we now will have to ride it out," Mr Cruz said.
Big Island resident Andrew Fujimura said the waves were topping 20ft (6m) along the coast.
"I can't say I'm too worried," he said. "Worst-case scenario, the power may go out a day or two. But we're prepared for that kind of stuff out here."
Australia have made 14 changes to the team that beat Uruguay for Saturday's crucial World Cup match against England at Twickenham.
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A rare tropical storm battering Hawaii has already caused power blackouts and blocked roads on one island, but no deaths have been reported.