The 33-year-old freelancer has been working in the country for three years for a number of media outlets, most recently NBC News.
More than 3,330 people have died in four West African countries in what has become the world's worst outbreak.
President Barack Obama has pledged federal support to contain the spread in the US, after the first case there.
A Liberian man diagnosed in Texas on Tuesday remains in a serious condition.
The unnamed cameraman is the fourth American known to test positive for Ebola, all diagnosed in Liberia.
Three American aid workers were separately flown back to the US for treatment and they are all recovering.
The man was only hired by NBC News on Tuesday, the US broadcaster said, and he came down with symptoms - including fever and aches - the following day.
After seeking medical advice, he tested positive for the virus.
NBC News President Deborah Turness informed staff of the news in a statement.
"We are doing everything we can to get him the best care possible. He will be flown back to the United States for treatment at a medical center that is equipped to handle Ebola patients."
The rest of the NBC crew including the network's chief medical editor, Dr Nancy Snyderman, are being flown back to the US on a private charter flight and will be placed under quarantine for 21 days, Ms Turness added.
Meanwhile, as many as 100 people in Texas are being checked for exposure to Ebola, after Thomas Eric Duncan, a Liberian national, was diagnosed with the virus in Dallas.
He flew to the US two weeks ago to visit relatives.
A number of them have been ordered to stay home while they are watched for signs of the disease.
Dallas Mayor Mike Rawlings was called by Mr Obama on Thursday who promised to help with whatever was needed from federal resources to stop it spreading.
Mr Duncan was the first person diagnosed on US soil and on Thursday, Liberian officials said they would prosecute him for lying on an Ebola questionnaire form prior to leaving the country.
Deputy Information Minister Isaac Jackson said Mr Duncan had "lied under oath about his Ebola status".
He is alleged to have taken a sick relative to a clinic.
In West Africa. the outbreak has prompted dire warnings of economic collapse if infection rates continue.
There have been 7,178 confirmed cases in total, with Sierra Leone, Liberia and Guinea suffering the most.
Leading charity Save the Children has warned that Ebola was spreading at a "terrifying rate" in West Africa, with the number of new recorded cases doubling every few weeks.
It said that a rate of five new Ebola cases an hour in Sierra Leone meant healthcare demands were far outstripping supply.
At a conference in London co-hosted with Sierra Leone, the UK called for urgent decisive action from the international community.
Ebola virus: Busting the myths

He was found with significant injuries in Tyrconnell Street, near the city's bogside, shortly before 10:30 BST and taken to hospital, but later died.
The police said it was "possible" his injuries "were sustained as the result of a collision with a vehicle".
Donnacadh was buried in the City Cemetery in Derry after a requiem mass at St Eugene's Cathedral on Saturday.
Police are still investigating the circumstances of his death and a man who was arrested in connection with the incident has been released on bail.

Police said she was Andrea Harris from Ardrossan.
The crash, involving a Stagecoach bus and an Isuzu 4x4, took place north of Ardrossan at 14:15 on Monday.
The 48-year-old driver of the Isuzu and the 36-year-old bus driver are "serious but stable" in Glasgow's Queen Elizabeth University Hospital.
Four bus passengers, two men and two women, are also in hospital.
They were taken to Crosshouse Hospital in Kilmarnock for treatment.
A further five passengers on the bus - three men and two women - received medical treatment at the scene or were taken to Crosshouse Hospital but were released after treatment.
The Scottish Ambulance Service declared the scene of the crash, near the Rowan Tree restaurant, a major incident. Two air ambulances attended, along with specialist trauma teams.
Police Scotland have appealed for witnesses to the crash.
Sgt Kevin Blackley from the Trunk Road Policing Unit, Irvine, said: "I would urge anyone who witnessed the crash, who has not yet spoken to police, or anyone with information that may assist our investigation to contact us through the non-emergency number 101."
A cameraman working in Liberia has tested positive for Ebola and is to be flown home to the US for treatment.
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The funeral has taken place of six-year-old Donnacadh McGuire, who died in Londonderry on Tuesday.
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A 45-year-old female bus passenger killed in a crash on the A78 in North Ayrshire which left six people in hospital has been named.