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In Massachusetts, the legal limit for alcohol is .08 Blood Alcohol Content (BAC) for those over 21, and .02 for those under 21 (aka zero tolerance). You are generally better off not taking the breathalyzer if asked to do so by the police. The fact that you refuse the breath test/breathalyzer test cannot be noted or used against you in court.
So therefore, he will want further evidence to bolster his DUI case and request a blood or breath test. In most cases, a breathalyzer is requested in order to determine a driver's blood alcohol content or BAC. However in some jurisdictions, a blood test is the preferred means to measure the driver's BAC. If a chemical test indicates you have an illegal BAC, you will be arrested and charge under Tennessee DUI laws.