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Sulfur belongs to the chalcogen family. Other members of the family are oxygen, selenium, tellurium, and polonium. These elements make up Group 16 (VIA) of the periodic table. The periodic table is a chart that shows how chemical elements are related to each other.
Sulfur is in 3rd period and in group 16 (Chalcogens), its Atomic Number is 16, which means that it will definitely has 16 electrons and 16 protons. The number of neutrons depends upon that which isotope of sulfur we are talking about.