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Really, this article explains well what the best times to water plants are. The ideal time to water them is in the morning before 10 am. 6 am would be good; 3 am is a bit early but also okay. The worst time to water is between 10 am and 2 pm, when the sun is hottest.
When first planting you should water every day or two for a couple of weeks, making sure not to let the root ball dry out, then gradually back off the watering frequency so that after 6 weeks you are watering every two-three days or so in the summer and every week to two weeks in the winter.