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Sulfur belongs to the chalcogen family. Other members of the family are oxygen, selenium, tellurium, and polonium. These elements make up Group 16 (VIA) of the periodic table. The periodic table is a chart that shows how chemical elements are related to each other.
An element's main group number indicates how many valence electrons each atom of that element will have, and because sulfur is part of group six on the periodic table, this indicates that this element has six electrons in its outermost electron shell..