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Iron and steel rust when they come into contact with water and oxygen: this is a form of corrosion. Both water and oxygen are needed for rusting to occur. Rusting is an oxidation reaction. The iron reacts with water and oxygen to form hydrated iron(III) oxide, which we see as rust.Here is the word equation for the reaction: iron + water + oxygen â hydrated iron(III) oxide. In the experiment below, the nail does not rust when air-containing oxygen-or water is not present:ron and steel rust when they come into contact with water and oxygen: this is a form of corrosion. Both water and oxygen are needed for rusting to occur. Rusting is an oxidation reaction. The iron reacts with water and oxygen to form hydrated iron(III) oxide, which we see as rust.