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Wine vinegars do still contain some level of alcohol. The vinegar taste is actually due to acetic acid, but the chemical transformation is never fully complete just sitting around a kitchen. Vinegar would be much too gross to drink in the quantity it would take to intoxicate anyone.
Although it is considered a wine vinegar, it is not a wine vinegar at all. It is not made from , but from grape pressings that have never been permitted to ferment into wine. Sweet white Trebbiano grape pressings are boiled down to a dark syrup and then aged under rigid restrictions.