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Wine vinegars do still contain some level of alcohol. The vinegar taste is actually due to acetic acid, but the chemical transformation is never fully complete just sitting around a kitchen. Vinegar would be much too gross to drink in the quantity it would take to intoxicate anyone.
Go With Vinegar. Mirin has a small amount of alcohol. If you're looking for a nonalcoholic substitute, vinegar is a suitable replacement. Rice wine vinegar offers a similar taste to mirin, but any white wine or distilled white vinegar will work.