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Decaffeination is the act of removing caffeine from coffee beans, mate, cocoa, tea leaves and other caffeine containing materials. (While caffeine-free soft drinks are occasionally referred to as decaffeinated, some are better termed uncaffeinated: prepared via simply omitting caffeine from production.)
In a word, no. Caffeine is an integral part of the tea leave's chemistry. Due to matcha's powder form you cannot separate it as you would with regular tea leaves. Decaf green tea is achievable by either harsh chemical processes which are damaging to the teas quality.