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For Eukaryotes the electron transport chain occurs in the Inner Membrane of a mitochondria. (mitochondria has 2 membranes both outer and inner). For Prokaryotes, it occurs in the plasma membrane as prokaryotes do not have mitochondria.
In Eukaryotes energy production is carried out in the mitochondria as a separate function from the rest of the cell. 1  The Citric Acid Cycle is the second stage of cellular respiration.  Citric Acid Cycle takes place in the cytosol of prokaryotes.