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The Free Dictionary describes a complexation reaction as a chemical reaction between a ligand and a metal ion. A ligand is an ionic entity with at least one atom that contains an unshared pair of electrons. Keep Learning.
Enzymes lower the activation energy of a reaction by forming an intermediary complex with the substrate. This complex is called an enzyme-substrate complex. For example, sucrase, 400 times the size of its substrate sucrose, splits the sucrose into its constituent sugars, which are glucose and fructose.