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For Eukaryotes the electron transport chain occurs in the Inner Membrane of a mitochondria. (mitochondria has 2 membranes both outer and inner). For Prokaryotes, it occurs in the plasma membrane as prokaryotes do not have mitochondria.
The electron transport chain is a series of electron carriers in the membrane of the mitochondria in eukaryotic cells. Through a series of reactions, the high energy electrons are passed to oxygen. In the process, a gradient is formed, and ultimately ATP is produced by oxidative phosphorylation.