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For Eukaryotes the electron transport chain occurs in the Inner Membrane of a mitochondria. (mitochondria has 2 membranes both outer and inner). For Prokaryotes, it occurs in the plasma membrane as prokaryotes do not have mitochondria.
Answer by Jeyradan. Confidence votes 175. Electron transport occurs in the mitochondria of eukaryotic cells. Specifically, the four protein complexes of the electron transport chain (ETC) exist as transmembrane complexes in the inner membrane of the mitochondria.