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It is false that in an energy diagram for a chemical reaction, energy is plotted along the x-axis (the horizontal axis) and reaction progress is plotted along the y-axis (the vertical axis). The energy is actually plotted along the y-axis and the reaction along the x-axis.
Although the step I 2 â products has the smallest individual activation energy Ea3, the energy of X3 with respect to the reactants determines the activation energy of the overall reaction, denoted by the leftmost vertical arrow . Thus the rate-determining step is I2 â products.