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Ammonium carbonate, (NH4)2CO3 dissolves in water releasing the ammonium ion, NH4+, and carbonate ion, CO32- into solution. Both of these ions hydrolyze (react with water). The chemical equations describing the hydrolysis reactions are given. By adding these reactions one can write the overall balanced net ionic equation for the reaction that occurs when ammonium carbonate dissolves in water.
The process for conversion of FGD gypsum to ammonium sulfate and calcium carbonate by the reaction with ammonium carbonate is by a unique combination of countercurrent flows with internal recycle of liquids to maximize the purity of reaction products while minimizing the reaction time.