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Disaccharides are formed when two monosaccharides join together by the dehydration synthesis reaction resulting in a glycosidic bond between the two monosaccharide molecules.
In simple terms, polysaccharides are complex sugar molecules made up of many blocks of simple sugar. The sugars are held together by the glycosidic bonds. A glycosidic bond is a covalent bond that joins a carbohydrate molecule to another group that may or may not be a carbohydrate.