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Structural Biochemistry/Carbohydrates/Polysaccharides. Polysaccharides are complex carbohydrate polymers consisting of more than 2 monosaccharides linked together covalently by glycosidic linkages in a condensation reaction. Being comparatively large macromolecules, polysaccharides are most often insoluble in water.
The hydroxyl group attached to the 3â carbon of the second nucleotide is also lost. The linkage between the nucleotides in a polynucleotide is called a phosphodiester bond, âphospho-â indicating the presence of a phos-phorus atom and âdiesterâ referring to the two ester (CâOâP) bonds in each linkage.he nucleotide monomers are linked together by joining the a phosphate group, attached to the 5â carbon of one nucleotide, to the 3â carbon of the next nucleotide in the chain. Normally a polynucleotide is built up from nucleoside triphosphate subunits, so during polymerization the b and g phosphates are cleaved off.