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A fruit is the mature ovary of a seed plant, usually developed from a flower. Fruits have seeds so they further the reproductive cycle. A vegetable is a plant or that part of a plant which is edible, and does not necessarily have a role in the plant's reproductive cycle.
The answer is: it depends on the fruit. Before we get started, it is important to mention that although fruit skins are mostly good for you, the so-called conventionally-grown fruits (or vegetables for that matter) contain pesticides, herbicides, chemicals, contaminants, and or carcinogens.