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Disaccharides are formed when two monosaccharides join together by the dehydration synthesis reaction resulting in a glycosidic bond between the two monosaccharide molecules.
Polysaccharides are complex carbohydrate polymers consisting of more than 2 monosaccharides linked together covalently by glycosidic linkages in a condensation reaction. Being comparatively large macromolecules, polysaccharides are most often insoluble in water.nbranched polysaccharides contain only alpha 1,4 linkages. However, there exists branched polysaccharides which are branched by virtue of certain molecules being linked to a molecule via alpha 1,4 and another via alpha 1,6 glycosidic bonds.