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An element is a substance consisting of atoms which all have the same number of protons-i.e. the same atomic number. Elements are chemically the simplest substances and hence cannot be broken down using chemical methods. Elements can only be changed into other elements using nuclear methods. Although an element's atoms must all have the same number of protons, they can have different numbers of neutrons and hence different masses.
How many elements are there? An element is a substance that is made entirely from one type of atom. If you had very, very good eyes and could look at the atoms in a sample of hydrogen, you would notice that most of the hydrogen atoms would have no neutrons, some of them would have one neutron and a few of them would have two neutrons.