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Structural Biochemistry/Carbohydrates/Polysaccharides. Polysaccharides are complex carbohydrate polymers consisting of more than 2 monosaccharides linked together covalently by glycosidic linkages in a condensation reaction. Being comparatively large macromolecules, polysaccharides are most often insoluble in water.
The covalent bond that links nucleotides in the sugar-phosphate backbone is a phosphodiester bond. Nucleotides are linked together by the formation of a phosphodiester bond which is formed between the 3' -OH group of one sugar molecule, and the 5' phosphate group on the adjacent sugar molecule. This results in a loss of a molecule of water, making this a condensation reaction, also called a dehydration synthesis. Source: