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Instant Fire. Potassium chlorate, KClO 3, is a white, crystalline or powdery solid which is a very good oxidizing agent; it is used in explosives, fireworks, matches, etc. When it decomposes under heating (especially in the presence of a manganese catalyst), it releases molecular oxygen, O 2 : 2KClO 3 (s) â.
What's happening is the sodium hypochlorite in the bleach is disproportionating to form sodium chloride and sodium chlorate. Adding the potassium chloride exchanges the ions and precipitates out potassium chlorate. The boiling is required for this reaction to work; you can't simply let the bleach evaporate.otassium chloride is sold as a sodium-free salt substitute. Now, once the bleach is cooled, measure out an equal volume of potassium chloride solution and pour into the boiled bleach solution, but do not mix in the crystals.