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Instant Fire. Potassium chlorate, KClO 3, is a white, crystalline or powdery solid which is a very good oxidizing agent; it is used in explosives, fireworks, matches, etc. When it decomposes under heating (especially in the presence of a manganese catalyst), it releases molecular oxygen, O 2 : 2KClO 3 (s) â.
This is also the first step of the Liebig process for the manufacture of potassium chlorate. In theory, electrolysis of hot calcium chloride solution will give chlorate, analogous to the process used for the manufacture of sodium chlorate. In practice, electrolysis is complicated by calcium hydroxide depositing on the cathode, preventing the flow of current.