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Lower the high pH in pool water. Adding an acid to the pool water reduces the pH. The most common chemicals used to reduce high pool water pH are: muriatic acid - typically 30% - 35% liquid hydrochloric acid; sodium bisulfate - granule or powder pH reducer, dry acid.
There is NO way to lower TA without lowering pH. Slugging acid in a pool with the pump off will have EXACTLY the same effect as walking the acid around the pool AND can cause damage to pool surfaces. When you add acid you convert bicarbonate (TA) into carbonic acid. This action lowers both pH and TA.