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Silicone caulk generally cures within 24 hours. If it has been over 24 hours, check the silicone caulk Use By date on the package. If the product is older than the Use by date printed on the product, safely dispose of the product.It is too old and will not cure.ilicone caulk generally cures within 24 hours. If it has been over 24 hours, check the silicone caulk Use By date on the package. If the product is older than the Use by date printed on the product, safely dispose of the product.
Silicone caulk, such as GE Silicone II* Concrete & Masonry, develops strength and adhesion quickly so it can be exposed to water in as little as three hours.aulk has to have enough time to build adhesion to the surface and cure or dry adequately so it won't wash away when exposed to water. That means if rain is in the forecast, homeowners and pros typically will have to delay or cancel a project when using most caulks.