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Silicone caulk generally cures within 24 hours. If it has been over 24 hours, check the silicone caulk Use By date on the package. If the product is older than the Use by date printed on the product, safely dispose of the product.It is too old and will not cure.ilicone caulk generally cures within 24 hours. If it has been over 24 hours, check the silicone caulk Use By date on the package. If the product is older than the Use by date printed on the product, safely dispose of the product.
Freshly applied silicone caulk has to seal before you use the shower, and moisture in the air speeds the curing time. Even if the silicone no longer feels tacky, it may not be fully cured. If the air is dry, it may take as long three days before the caulk is cured, according to remodeling expert Tim Carter.amp surfaces or moisture seepage can prevent the caulk from adhering. After applying fresh silicone caulk in a climate with moderate humidity, the silicone can cure overnight and you can take a shower the next day.