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Lower the high pH in pool water. Adding an acid to the pool water reduces the pH. The most common chemicals used to reduce high pool water pH are: muriatic acid - typically 30% - 35% liquid hydrochloric acid; sodium bisulfate - granule or powder pH reducer, dry acid.
Increasing the pH of the water without affecting the alkalinity is very easy, but there is a trick. With the pump motor on and water circulating, add the sodium bicarb. in the deep end of the pool and work your way around the perimeter. This will raise the pH with minimal effect on the alkalinity.