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Silicone caulk generally cures within 24 hours. If it has been over 24 hours, check the silicone caulk Use By date on the package. If the product is older than the Use by date printed on the product, safely dispose of the product.It is too old and will not cure.ilicone caulk generally cures within 24 hours. If it has been over 24 hours, check the silicone caulk Use By date on the package. If the product is older than the Use by date printed on the product, safely dispose of the product.
After you've smoothed the bead go back and wipe any excess from the wall and trim surfaces before it can dry. When you've finished, be careful not to disturb the caulk until it has time to set and cure. Acrylic latex caulk will set (become firm) in about an hour and cure (become hard) in about 24 hours. For the best finish, wait for the caulk to cure before cutting-in around the corners with a paint brush.