In the second reaction neutral iodine combines with starch to form a blue-black compound. I. 2. + starch = blue-black compound. In the third reaction the neutral iodine gains an electron from a sulfur atom in the compound called sodium. thiosulfate and goes back to colorless iodine with a negative charge.
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A cholagogue, on the other hand, clears away a great quantity of bile, and the skin of patients so treated at once becomes clear. On the Natural Faculties Galen. On the skin its action is that of a diaphoretic, and being also excreted by the bile it acts slightly as a cholagogue. Encyclopaedia Britannica, 11th Edition, Volume 2, Slice 2 Various. It might therefore be supposed that Colchicum too acted as a cholagogue.