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As nouns the difference between oligomerization and polymerization is that oligomerization is (chemistry) the formation of an oligomer from a monomer while polymerization is (chemistry) the chemical process, normally with the aid of a catalyst, to form a polymer by bonding together multiple identical units (monomers).
Polymerization is defined as the addition of two or more small molecules [known as monomers] to form a larger molecule [known as the polymer] with or without the elimination o â¦ f simple compounds such as water or methanol.  There are two types of polymerization 1.olymerization is a chemical process that combines several monomers to form a polymer or polymeric compound.