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As nouns the difference between oligomerization and polymerization is that oligomerization is (chemistry) the formation of an oligomer from a monomer while polymerization is (chemistry) the chemical process, normally with the aid of a catalyst, to form a polymer by bonding together multiple identical units (monomers).
Definition of polymerization. 1  1 : a chemical reaction in which two or more molecules combine to form larger molecules that contain repeating structural units â compare association 5. 2  2 : reduplication of parts in an organism.