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As nouns the difference between oligomerization and polymerization is that oligomerization is (chemistry) the formation of an oligomer from a monomer while polymerization is (chemistry) the chemical process, normally with the aid of a catalyst, to form a polymer by bonding together multiple identical units (monomers).
The difference between the two is that macromolecules are polymers, built from monomers carbohydrates include sugars and the polymers of sugars the differences between the complex in polymer chemistry, polymerization is a process of reacting molecule, or macromolecule, composed of many repeated subunits.