The closest spread to peanut butter I've found in terms of flavor and texture is sunflower seed butter. It's also relatively easy to find; I've seen it in large chain grocery stores right next to the peanut butter.
A curmudgeon with years of practice. The bubbles in boiling water are steam or vaporized water. The bubbles initially do not reach the surface of the billing fluid as the colder water away from the hot bottom cools the steam turning it back to liquid. WHen all the water is at 100oC the bubbles reach the top.
Boiling occurs only when the liquid is heated to the boiling point, and vapor bubbles come from the bulk of the liquid. In evaporation, vaporization occurs only at the surface of the liquid, not throughout the liquid, and this occurs at lower temperatures.