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As nouns the difference between oligomerization and polymerization is that oligomerization is (chemistry) the formation of an oligomer from a monomer while polymerization is (chemistry) the chemical process, normally with the aid of a catalyst, to form a polymer by bonding together multiple identical units (monomers).
Polymerization. the process of producing macromolecular substances in which polymer molecules (macromolecules) are formed by the successive addition of low-molecular-weight substances (monomers) to the reactive site at the end of the growing chain. polymerisation. the act or process of forming a polymer or copolymer, esp a chemical reaction in which a polymer is formed.