When halogens combine or react with metals, they form ionic bonds. As a result of these reactions, these elements become anions, or negatively charged ions. Owing to their high reactivity, these are never found in a pure form in the nature.They must be extracted from their sources, using proper methods and techniques.hen halogens react with hydrogen, they form binary compounds known as hydrogen halides. These compounds (hydrogen halides) are extremely strong acids, which make them a unique brand of elemental family. When these compounds are converted to an aqueous state, they are known as hydrohalic acids.
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