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Alcohol does not freeze. Fiction: Actually, alcohol does freeze; its freezing point is simply far below that of water. For instance, water freezes at 32 degrees Fahrenheit, while ethanol (or pure grain alcohol such as Everclear) freezes at -173.2 degrees Fahrenheit.
The freezing point depends on the spirit's proof, or alcoholic concentration, which is is double its alcohol percentage. Vodka is usually about 80 proof, or 40 percent alcohol. Wine is usually around 28 proof, and grain alcohol is 190 proof -- pretty darn close to pure alcohol [source: Real Simple ]. The higher the proof of a given alcohol, the lower the freezing point -- in other words, higher alcoholic concentration makes a spirit harder to freeze.