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Carbon monoxide is a simple diatomic molecule that illustrates how two different atoms interact to form molecular orbitals (MO). The oxygen atom and the carbon atom have an s and three p orbitals each. For clarity, we draw the atomic orbitals of oxygen in red, and those on carbon in black (see below).
Carbon monoxide is polar because oxygen is more electronegative than carbon giving oxygen a partila negative charge and carbon a partial positive charge. There is a net dipole moment.n the free carbon monoxide, a net negative charge Î´- remains at the carbon end and the molecule has a small dipole moment of 0.122 D The molecule is therefore asymmetric: oxygen has more electron density than carbon, and is also slightly positively charged compared to carbon being negative.