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Peachskin is a blouseweight fabric with a soft hand. It has almost a suede-like face, but still soft and does not have a nap like suede. It drapes nicely on the body and is perfect for tops, dresses and skirts.
Polyester fabric is, by definition, synthetic: a fabric made by chemical synthesis rather than from natural materials (such as wool, cotton, linen, silk) or quasi-synthetic cellulose-based materials (rayon, acetate).