When dealing with a headache, try boiling one cup of apple cider vinegar and one cup of water in a pot. Pour into a heat proof bowl and put on the table or other safe place that you can lean over the bowl and cover your head with a towel. Inhale the steam for a few minutes to bring some relief.
The warning on mine says not to use prior to 4 months of age. My son was in his Jolly Jumper from 3 months. The directions of use are that if they can confidently hold up their head then they are fine.
You can safely switch your child to a booster seat if she's at least 4 years old and she weighs 40 pounds or more or has grown too tall for her car seat (when her shoulders are higher than the top set of harness-strap slots in the car seat's back). Whatever you do, don't move your child to a booster seat simply because she's had her fourth birthday.