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Answer by Zhane lane. Confidence votes 2. Potassium was discovered in 1807 by British scientist Sir Humphry Davy, who derived it from caustic potash (KOH)where was it discovered and when His first successes came in 1807 with the separation of potassium from molten potash and of sodium from common salt.
The alkali metal was discovered by Sir Humphry Davy in 1807 in England. The discovery of the element happened when he used electrolysis to process caustic potash. According to records, it is the first alkali metal to be discovered using electrolysis. At first, there are no distinctions between potassium and sodium.