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Quick Answer. There are 70 milligrams of caffeine in a tall Starbucks Chai tea latte. The caffeine content increases to 95 milligrams in the grande size.
As always, these new Starbucks additions come with a generous kick of caffeine; a shot of solo espresso contains 75 mg of caffeine, so when you combine that with a regular Frappuccino, the caffeine count can stack up: An Affogato-Style Mocha Frappuccino contains 130 mg of caffeine, for example.