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Quick Answer. There are 70 milligrams of caffeine in a tall Starbucks Chai tea latte. The caffeine content increases to 95 milligrams in the grande size.
10g of coffee produces about 18-30 ml of espresso (probably about 18-20ml if ristretto) Hence I would say that a single ristretto shot (around 20ml) could estimably have around 33mg of caffeine, while a double shot (40ml) would have about 66mg.