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Argon has a total of 18 electrons. There are 2, 8 and 8 electrons in the 1st, 2nd and 3rd energy levels respectively.
The electron configuration for Ca 2+ is the same as that for Argon, which has 18 electrons. Hence, we can say that both are isoelectronic. The electronic configuration of anions is assigned by adding electrons according to Aufbau's building up principle. We add electrons to fill the outermost orbital that is occupied, and then add more electrons to the next higher orbital. The neutral atom chlorine (Z=17), for instance has 17 electrons.