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Structural plasticity will mostly refer to the remodeling of synaptic elements, e.g. spine strengthening or weakening. Functional plasticity does not preclude structural plasticity, but it means general recovery of function, for example after stroke. You lose many neurons there, but existing neurons can rearrange (using structural plasticity) their connections so as to restore function to the degree possible.
Someone explained it to me that way: there are two ways to disable a synapse: either remove it or make it non responsive (set its weight to 0). The first solution is structural plasticity, the second one is functional plasticity (the synapse is still there, but just functionally disabled). Of course plasticity isn't just about disabling a synapse, but this is what the topic of discussion was at the moment with the guy I talked with, and I thought it was a quite simple enough explanation to remember it easily.