How did the first peoples know which foods were safe to eat? Excellent question! Food historians make educated guesses based on ancient records and modern practices.
When water freezes its entropy decreases. This does not violate the second law of thermodynamics. The second law does not say that entropy can never decrease anywhere. It just says that the total entropy of the universe can never decrease.he entropy increases whenever heat flows from a hot object to a cold object. It increases when ice melts, water is heated, water boils, water evaporates. The entropy increases when a gas flows from a container under high pressure into a region of lower pressure.
(This pattern is what you see if you look at ice crystals.) So, when water freezes, the molecules take up more space, and the ice ends up being even /bigger/ than the water was. If you were to put that water in a closed container in the freezer, then it would still get bigger. What happens to the container depends on what sort of a container it is. For example, if the container were made of thin plastic, it would probably stretch a bit as the water freezes.