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Smackover, Arkansas. Smackover is a small city in Union County, Arkansas, United States. According to Citydata.com, the 2014 population was at 1,790.
Former Smackover residents of note are Sidney Albert Umsted, who discovered the Smackover oil field, and Clyde âSmackoverâ Scott, who was an All-American in football and track and field at the University of Arkansas, as well as an Olympic silver medallist.