Exercise cannot tighten your loose skin, but you can minimize the amount of loose skin you have. If you have excess skin, patience is key as you wait for your skin to adjust to your new size.
A Pepsi takes between 30 and 45 minutes to freeze solid, depending on the temperature it was at before putting it in a typical home freezer. Be aware that most (but not all) Pepsi containers will burst if you keep them frozen for more than 2 hours.
Between a half to 2 hours depending on the size of the bottle, the temperature of the water and the size of freezer and the temperature of the freezer and whether the bottle is closed or open.