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Structural plasticity will mostly refer to the remodeling of synaptic elements, e.g. spine strengthening or weakening. Functional plasticity does not preclude structural plasticity, but it means general recovery of function, for example after stroke. You lose many neurons there, but existing neurons can rearrange (using structural plasticity) their connections so as to restore function to the degree possible.
Functionalism is the doctrine that what makes something a thought, desire, pain (or any other type of mental state) depends not on its internal constitution, but solely on its function, or the role it plays, in the cognitive system of which it is a part.f so, then functionalism can stand as a materialistic alternative to the Psycho-Physical Identity Thesis (introduced in Place 1956, Feigl 1958, and Smart 1959, and defended more recently in Hill 1991, and Polger 2011), which holds that each type of mental state is identical with a particular type of neural state.