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Article Information. Abstract. Ethyl Hexanediol is an aliphatic alcohol used as a solvent in a small number of cosmetic formulations applied to the skin and hair. Animal data indicate that Ethyl Hexanediol is absorbed through the skin and is metabolized and eliminated in the urine. Reported oral LD50 values in rats are generally above 5 g/kg.
1,6-Hexanediol is prepared industrially by the hydrogenation of adipic acid. Laboratory synthesis can be done by reduction of adipic acid with lithium aluminium hydride, however, since it is cheaply and commercially available, it is usually not synthesized in the laboratory.