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Answer by Zhane lane. Confidence votes 2. Potassium was discovered in 1807 by British scientist Sir Humphry Davy, who derived it from caustic potash (KOH)where was it discovered and when His first successes came in 1807 with the separation of potassium from molten potash and of sodium from common salt.
Potassium carbonate, which was gathered from wood ash, was concentrated through boiling and then used for industrial purposes, such as soap making. The wood ash origin of the potassium carbonate lent the name potash to the compound (and eventually to the element). Potassium was first isolated by Sir Humphrey Davy in 1807. He used electrolysis with a dry potash compound to identify the element. He would later use this same process to isolate sodium, which was previously undistinguished from potassium.