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Rust is an iron oxide, usually red oxide formed by the redox reaction of iron and oxygen in the presence of water or air moisture.Several forms of rust are distinguishable both visually and by spectroscopy, and form under different circumstances.he rusting of iron is an electrochemical process that begins with the transfer of electrons from iron to oxygen. The iron is the reducing agent (gives up electrons) while the oxygen is the oxidising agent (gains electrons).