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Decaffeination is the act of removing caffeine from coffee beans, mate, cocoa, tea leaves and other caffeine containing materials. (While caffeine-free soft drinks are occasionally referred to as decaffeinated, some are better termed uncaffeinated: prepared via simply omitting caffeine from production.)
Do-It-Yourself Decaf. Caffeine is the first substance released into the water during steeping (this occurs within the first 25 seconds). To decaffeinate your favorite tea, steep the leaves or bag for 30 seconds, dump the water, then refill your cup with hot water and steep again. Most of the caffeine will be removed.