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The theme song to Psych, I Know, You Know, is performed by series creator Steve Franks and his band, the Friendly Indians. WIKI. You can download the MP3 from the link I am providing. These lyrics were all I could find off of someone's blog.
Leslie Uggams and Big Bird sing  Love Will Keep Us Together  for the closing number in episode 318 of The Muppet Show. The song was originally recorded by one of its writers, Neil Sedaka, but not released as a single. In 1975 it was covered by Captain and Tenille who had their first number one hit with it.