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When correctly reared, llamas spitting at a human is a rare thing. Llamas are very social herd animals, however, and do sometimes spit at each other as a way of disciplining lower-ranked llamas in the herd. A llama's social rank in a herd is never static.
Being that llamas are ruminates it seems to me that they clearly chew their cud. But I have not found any definitive information on whether or not the have fully split hooves. Furthermore, they are not in the list of animals with one sign in Vayikra 11:4-7.