I would say 5-7 days in Buenos Aires (including a day trip to Colonia). Then pick a side trip such as Iguazu Falls or Mendoza. You can find my recent trip report by clicking on my name.A was one of my least favourite cities so I would give it 3 days but a lot of people love it so 4-5 days seems reasonable. If you like cities then I guess you could go to Santiago but I would suggest going to El Calafate and see some glaciers or go up north to Iguassu to see the falls.
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