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Wine vinegars do still contain some level of alcohol. The vinegar taste is actually due to acetic acid, but the chemical transformation is never fully complete just sitting around a kitchen. Vinegar would be much too gross to drink in the quantity it would take to intoxicate anyone.
The name comes from the Old French vin aigre, which translates into sour wine.. Vinegar is made from the oxidation of ethanol in an alcohol-containing liquid, such as wine, fermented fruit juice, or beer. There are two processes of fermentation that differ by speed of production.