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The theme song to Psych, I Know, You Know, is performed by series creator Steve Franks and his band, the Friendly Indians. WIKI. You can download the MP3 from the link I am providing. These lyrics were all I could find off of someone's blog.
Nobody spelled out the sexiness of the James Bond films better than Carly Simon. The song was written by Marvin Hamlisch and Carole Bayer Sager and holds the distinction of being the first Bond theme that did not carry the same name as the accompanying film. In this case, the film was The Spy Who Loved Me.