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The two states that have the highest concentration of Mexican  Americans is California and Texas. The two states have 61 percent  of Mexican American population.
Hispanic Americans: Who they are and where they live. 1  Among Latino subgroups, Mexican Americans make up the largest subgroup at 63 percent and, at 38 percent, have the largest proportion of people under the age of 18. In 2010 the states with the largest Latino populations were California (14 million), Texas (9.5 million), Florida (4.2 million), New York (3.4 million), and Illinois (1.2 million).