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The two states that have the highest concentration of Mexican  Americans is California and Texas. The two states have 61 percent  of Mexican American population.
1 In New Mexico, Hispanics make up 46.7% of the stateâs population, the highest Hispanic population share among the 50 states and District of Columbia. 2  Maine, West Virginia, and Vermont were among those with the lowest Hispanic population shares, at 1% each.