During photosynthesis, light energy is used to produce ATP molecules which are then used to construct sugar molecules from carbon dioxide and hydrogen obtained from water. Chloroplasts have two outer membranes and several stacks of small disc-shaped membranes called thylakoids (also spelled thylacoids) inside.
Scheduling a week off will give your body time to do this and will also help you return to your workout stronger and ready to challenge your body once again. Many endurance athletes end their season with a week off and many weightlifters will take a week off from their program every four to eight weeks.
You can opt for a sixth workout in your seven day week, but I do recommend you give yourself 1-2 days rest for recovery. A workout #6 option would be to take a day off prior and do the full test in the order that you will be taking it.