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Simmer pearled barley for 20 to 25 minutes, until tender and chewy, and hulled barley for 40 minutes or longer. Drain any excess moisture, in the case of hulled barley, then let the grain rest for 10 minutes to absorb the remaining surface moisture and become slightly firmer.
Oven Toasting. Oven toasting is another easy method for toasting grain. Barley, for example, can be lightly toasted in the oven before it is added to soups and other dishes. To toast barley, simply spread the barley grains evenly on a baking sheet and toast for about 10 minutes in a 350ÂºF oven.