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Lower the high pH in pool water. Adding an acid to the pool water reduces the pH. The most common chemicals used to reduce high pool water pH are: muriatic acid - typically 30% - 35% liquid hydrochloric acid; sodium bisulfate - granule or powder pH reducer, dry acid.
Alum is one of the most effective coagulants, but in low-alkalinity ponds can reduce pH to levels harmful to fish. In this situation, hydrated lime must be added with the alum to offset the reduction in pH. Gypsum is an effective coagulant in most ponds and does not cause a loss in alkalinity.