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Silicone caulk generally cures within 24 hours. If it has been over 24 hours, check the silicone caulk Use By date on the package. If the product is older than the Use by date printed on the product, safely dispose of the product.It is too old and will not cure.ilicone caulk generally cures within 24 hours. If it has been over 24 hours, check the silicone caulk Use By date on the package. If the product is older than the Use by date printed on the product, safely dispose of the product.
Your time estimates are over the top. The polyester putty I use dries completely solid in 10 minutes. I can sand and carve it around 10 minutes from mixing it depending on the ratio of hardener to putty I use. Milliput, which I've used for years, again takes no way near 24-48 hours to cure.