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Flaky dry skin due to face eczema. If your face looks dry and inflamed and moisturizers do not work at all then the problem can be face eczema. Dry flaky skin on face due to face eczema should be treated by products that contain hydrocortisone. Start with mild ones if it does not work, see a dermatologist.
Dandruff, or sebhorreic dermatitis, can cause your scalp to itch and shed flakes of dry skin. Dandruff has a variety of causes, from shampooing your hair too often or not often enough, to sensitivity to washing and styling products. Medical problems like eczema and psoriasis also can result in an itchy flaky scalp.