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The pH of vinegar depends upon how much acid is present in it. The most commercial distilled white vinegars contain 5% acetic acid, and hence, has a pH value that ranges between 2.40 - 3.40. More Information on Vinegar and its pH Levels. Though vinegar is available in different varieties, apple cider vinegar is the most commonly used example, which is prepared from apple cider.
Acetic acid isn't the only compound in vinegar, but it's the one that makes vinegar acidic. In fact, with a pH of 2.4, distilled white vinegar is a pretty strong acid, more acidic than coffee or orange juice, but still less acidic than your stomach juices or, say, the liquid inside batteries (luckily).