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1 The Ideal Gas Law is a convenient approximation of most gas-phase reactions, but does not always sufficiently describe real gases near the condensation point, near the critical point, or at high pressures.  Two common models for real gases are the van der Waals model and the Redlich-Kwong model.
The formula for the Ideal Gas Law is PV=nRT. Therefore, V=nRT/P. If T and P are constant and only the moles change V is entirely dependent on n. Since n is in the numerator of the equation, that means as the number of moles increase, the volume will increase too. This means V is directly proportional to n.