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The remarkable triple state of matter where solid, liquid and vapor are in equilibrium may be characterized by a temperature called the triple point. The triple state is represented by a line parallel to the Pv plane with a characteristic pressure for the substance but variable volume. The triple point temperature of water is assigned the value 273.16 K and the triple state of water is used as the reference for establishing the Kelvin temperature scale.
Actually it is -273.15 C, and the triple point of water is at a temperature of 273.16 K or 0.01 C. At standard atmospheric pressure water boils at 100 C and freezes at 0 C, which decides the size of the degree.