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Acetyl coenzyme A or acetyl-CoA is an important molecule in metabolism, used in many biochemical reactions.Its main function is to convey the carbon atoms within the acetyl group to the citric acid cycle (Krebs cycle) to be oxidized for energy production.he oxidative conversion of pyruvate into acetyl-CoA is referred to as the pyruvate dehydrogenase reaction. It is catalyzed by the pyruvate dehydrogenase complex. Other conversions between pyruvate and acetyl-CoA are possible.
Hydrolysis of the thioester bond is highly exergonic (-31.5 kJ). Acetyl-CoA is produced during breakdown of carbohydrates through glycolysis as well as fatty acid oxidation and enters the citric acid cycle. Acetyl-CoA is also an important component in the biogenic synthesis of the neurotransmitter acetylcholine.