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I think I often type â silicon baking matsâ but thatâs wrong â silicone is the material in the bakeware. Silicon is right on the periodic table, a natural element that is in sand and makes up 28% of the earthâs crust. However, I donât eat on the earthâs crust. Many silicone baking mats are actually made of fiberglass covered on both sides with silicone, so unless you want to risk fiberglass in your food, donât cut on the mats! 2  Itâs reasonably new, so long-term studies havenât been performed on cookware that has been exposed to high temperatures over very long periods.
Heat is your friend. If you have bits of muffin or casserole that ended up a crispy mess on your bakeware, the key to getting them off is actually more heat. Put the silicone pan in the oven at 350Â°F for about 10 minutes, and then soak it in really hot water.