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law of mass action - (chemistry) the law that states the following principle: the rate of a chemical reaction is directly proportional to the molecular concentrations of the reacting substances. 1  law of nature, law - a generalization that describes recurring facts or events in nature; the laws of thermodynamics.
For systems that are not at equilibrium yet, the ratio calculated from the mass action law is called a reaction quotient Q. The Q values of a closed system have a tendency to reach a limiting value called equilibrium constant K over time.A system has a tendency to reach an equilibrium state.kills to develop. 1  Identify a system, an open system, a closed system and the environment of the system. 2  Define a state of equilibrium. 3  Describe the mass action law. 4  Apply the mass action law to write expressions for equilibrium constant. 5  Write the equilibrium constant expression for any reaction equation.