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Monroe, Ohio. Not to be confused with Monroe County, Ohio. Monroe is a city located in east central Butler and west central Warren counties in the southwestern part of the U.S. state of Ohio. As of the 2010 Census, the city population was 12,442, up from 4,008 in 1990. Contents.
According to the U.S. Census Bureau, the county has a total area of 680 square miles (1,800 km2), of which 549 square miles (1,420 km2) is land and 131 square miles (340 km2) (19%) is water. Monroe is Michiganâs only county on Lake Erie. The River Raisin and Sandy Creek flow through the county.