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Best Answer: ethanol because of the OH polar head is more soluble in water because it forms hydrogen bonds with H20 than the CH3 in dimethyl ether.Also alcohol is more soluble then ethers because of that OH polar head.In addition, 1-5 carbons chain are generally soluble but more preference is given to the one with less carbon chain and OH polar head.Source(s): took organic chem 1 and 2.ating Newest Oldest. Best Answer: ethanol because of the OH polar head is more soluble in water because it forms hydrogen bonds with H20 than the CH3 in dimethyl ether. Also alcohol is more soluble then ethers because of that OH polar head.
If a liquid is insoluble in water, adding it to water will turn the solution cloudy, or turbid. When two liquids are soluble in each other they mix together perfectly and are said to be miscible. Based on all this, you can expect ethanol and isopropanol to be more soluble in water than 1-butanol, which in turn will be more soluble than cyclohexanol. (Both ethanol and isopropanol are miscible with water). Experiment 18C: The Lucas Test. The Lucas test tells whether an alcohol is primary, secondary or tertiary.