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Monroe, Ohio. Not to be confused with Monroe County, Ohio. Monroe is a city located in east central Butler and west central Warren counties in the southwestern part of the U.S. state of Ohio. As of the 2010 Census, the city population was 12,442, up from 4,008 in 1990. Contents.
According to the United States Census Bureau, Monroe township had a total area of 42.232 square miles (109.382 km 2), including 41.974 square miles (108.713 km 2) of land and 0.258 square miles (0.668 km 2) of water (0.61%). At 42 square miles, it is the largest municipality in Middlesex County in terms of total area.