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Just to get it right: The password is NOT admin. The device password is the same as for the admin account on your NAS. This is when you log in through 192.168.0.32, you will need to enter a password for the System Administrator (admin) account. Use that. If you don't have one, because the factory default is <empty>, then set one.
The device IP address is a unique IP address that is assigned to devices that are connected on a network. While the steps below were tried on a Android 6.0 (Marshmallow) device, they are generally the same on all versions of Android devices. 1) Open your Settings menu and tap on About. 2) Tap on Status.