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Best Answer: ethanol because of the OH polar head is more soluble in water because it forms hydrogen bonds with H20 than the CH3 in dimethyl ether.Also alcohol is more soluble then ethers because of that OH polar head.In addition, 1-5 carbons chain are generally soluble but more preference is given to the one with less carbon chain and OH polar head.Source(s): took organic chem 1 and 2.ating Newest Oldest. Best Answer: ethanol because of the OH polar head is more soluble in water because it forms hydrogen bonds with H20 than the CH3 in dimethyl ether. Also alcohol is more soluble then ethers because of that OH polar head.
Alkanes are more soluble because they are more like benzene when looking at intermolecular forces. Alcohol on the other hand have OH groups so small carbon chain alcohols are pretty soluble in polar solvents, like water, because they have simliar intermolecular forces.nswers: In the world of solubility the axiom is like dissolves like. In the solvents shown the organic solvents, benzene, chloroform, and dimethyl ether (a gas at room temperature), have relatively polarity constants.