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Just to get it right: The password is NOT admin. The device password is the same as for the admin account on your NAS. This is when you log in through 192.168.0.32, you will need to enter a password for the System Administrator (admin) account. Use that. If you don't have one, because the factory default is <empty>, then set one.
Enterprise-Ready Identity Solutions in Windows 10. Device Guard is one of our top security features in Windows 10 but investments are also required to address the challenges organizations and consumer face when it comes to identity. Windows Hello* and Microsoft Passport, announced at WinHEC last month, are two of the key features that we are delivering in the space.