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Just to get it right: The password is NOT admin. The device password is the same as for the admin account on your NAS. This is when you log in through 192.168.0.32, you will need to enter a password for the System Administrator (admin) account. Use that. If you don't have one, because the factory default is <empty>, then set one.
Wi-Fi password (Network Security Key) serves to protect your wireless network and prevents from the unauthorized access to your PCs, laptops, tablets, phones, etc. In different operating systems it also can be called Wireless Security Key, Wireless Password and Network Security Key. It is a typical situation when you forget the security key for your Wi-Fi because everything has been working well for a long time. And suddenly you need to enter your Wi-Fi password again.