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Best Answer: ethanol because of the OH polar head is more soluble in water because it forms hydrogen bonds with H20 than the CH3 in dimethyl ether.Also alcohol is more soluble then ethers because of that OH polar head.In addition, 1-5 carbons chain are generally soluble but more preference is given to the one with less carbon chain and OH polar head.Source(s): took organic chem 1 and 2.ating Newest Oldest. Best Answer: ethanol because of the OH polar head is more soluble in water because it forms hydrogen bonds with H20 than the CH3 in dimethyl ether. Also alcohol is more soluble then ethers because of that OH polar head.
Nov 19, 2015. As we know LIKE DISSOLVES LIKE. Water is a polar solvent and has hydrogen bonding , so for any other compund to dissolve in water , it must posses Polarity or H-Bond. Ethyl alcohol shows presence of hydrogen bonding as well as it is polar due to high EN of oxygen , due to this it is soluble in water. Was this helpful? Let the contributor know!