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Monroe, Ohio. Not to be confused with Monroe County, Ohio. Monroe is a city located in east central Butler and west central Warren counties in the southwestern part of the U.S. state of Ohio. As of the 2010 Census, the city population was 12,442, up from 4,008 in 1990. Contents.
With the charm of a small rural community yet close access to larger population centers, the community of Monroe has about 600 residents and is the smallest incorporated city in the Tri-County region. Having settlers as early as the 1850âs, Monroe was born as a homesteading center, timber town, and a minor river port.