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Just to get it right: The password is NOT admin. The device password is the same as for the admin account on your NAS. This is when you log in through 192.168.0.32, you will need to enter a password for the System Administrator (admin) account. Use that. If you don't have one, because the factory default is <empty>, then set one.
Tap the Encrypt device button, and you'll be prompted for your password. Once you've done that, tap the Encrypt device button again, and step away from the phone. It will immediately restart and begin the process of encryption. Do NOT interrupt the process.