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Best Answer: ethanol because of the OH polar head is more soluble in water because it forms hydrogen bonds with H20 than the CH3 in dimethyl ether.Also alcohol is more soluble then ethers because of that OH polar head.In addition, 1-5 carbons chain are generally soluble but more preference is given to the one with less carbon chain and OH polar head.Source(s): took organic chem 1 and 2.ating Newest Oldest. Best Answer: ethanol because of the OH polar head is more soluble in water because it forms hydrogen bonds with H20 than the CH3 in dimethyl ether. Also alcohol is more soluble then ethers because of that OH polar head.
â¢ Ethers do not hydrogen bond to one another. As a result they have lower boiling point than alcohols. â¢ The ether oxygen can form hydrogen bonds with water, causing low molecular weight ethers to be water soluble. Ethers with large organic groups are water insoluble. â¢ Simple ethers are highly flammable solvents.