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Process pickled peppers in pints or half pints 10 minutes below 1000 feet. Process 15 minutes if you are between 1000 - 6000 feet. Process 20 minutes if you are above 6000 feet. For more information on why your altitude is important see this altitude adjustments page.
Cayenne peppers will be ready to harvest in about 70-80 days. When ready, cayenne pepper will be 4-6 inches long and easily pull from the stem, although it is really better to snip from the plant so you do not cause any damage.