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Polar molecules are hydrophylic. Because the inner portion of the phospholipid bilayer (plasma membrane) consists of hydrophobic interactions, generally polar molecules cannotâ¦ pass directly though. These molecules require protein channels to actively or passively move between the cytosol and the plasma membrane.
Because of the chemistry and fluidity of phospholipid bilayers, certain types of molecules can pass through freely, while other types have no chance without help from the cell. The former types of molecules use a mixture of size, chemistry, and the forces of diffusion to squeeze through what seems to be an impenetrable barrier.