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In Italy really good balsamic is also drunk as a palette cleanser, aperitif or digestif, especially on special occasions such as weddings. The name balsamic connotes the vinegar's original use as a tonic, or balm..
Dr. Atkins points out in DANDR that we should avoid balsamic vinegar. Other vinegars are fine, though. my balsamic is thick and sweet...definitley a no-no ...sigh... I used balsamic this summer with my tomato mozzarealla and a few times in my salads.