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When you are a liquid and want to become a gas, you need to find a lot of energy. Once you can direct that energy into your molecules, they will start to vibrate. If they vibrate enough, they can escape the limitations of the liquid environment and become a gas. When you reach your boiling point, the molecules in your system have enough energy to become a gas. The reverse is true if you are a gas.
1 Condensation: the substance changes from a gas to a liquid. 2  Vaporization: the substance changes from a liquid to a gas. 3  Sublimation: the substance changes directly from a solid to a gas without going through the liquid phase.