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Contrary to popular opinion, cacao is a poor source of caffeine. A typical sample of cacao nibs or cacao beans will yield anywhere from zero caffeine to 1,000 parts per million of caffeine (less than 1/20th of the caffeine present in coffee).
Caffeine: 22.4mg. Health Benefits of Cocoa Nibs. 1  Fiber and protein found in cocoa nibs will support your weight management goals by slowing digestion and leaving you feeling fuller for longer. 2  They are packed full of antioxidants and phytonutrients, which will help you fight damage caused by free radicals.n addition to being great for cooking, cocoa nibs are also nutrient-dense sources of some vitamins and minerals. Try adding cocoa nibs to coffee, dessert toppings, savory dishes like cacao and coffee roasted chicken, or baked into your favorite cookies. The Nutritional Value of Cocoa Nibs. 1oz of Cocoa Nibs/ Cacao.