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Like halite, it forms clear, transparent crystals that are much softer than glass and exhibit good cubic cleavage. The only easy way to distinguish the two is by their taste. Halite is salty, while sylvite is quite bitter.
In the language of close-packing, the larger chloride ions are arranged in a cubic array whereas the smaller sodium ions fill all the cubic gaps (octahedral voids) between them. This same basic structure is found in many other compounds and is commonly known as the halite or rock-salt crystal structure.