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This is caused by the dilation of blood vessels in the face and neck, which allows blood to rush to the head. This, in turn, causes the skin to feel warm and turn red. Generally, people with fair skin and younger people are most susceptible to hot face and ears caused by blushing.
The face will feel tight and will burn after washing. Facial burning sensation can also be caused by eczema, an itchy skin condition. Due to eczema, excessive itching of the face can cause the skin to split and tear, resulting in a burning sensation.