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In quantum mechanics, an atomic orbital is a mathematical function that describes the wave-like behavior of either one electron or a pair of electrons in an atom. This function can be used to calculate the probability of finding any electron of an atom in any specific region around the atom's nucleus.
Share. By Anne Marie Helmenstine, Ph.D. Orbital Definition: Electron cloud having an energy state described by given values of the n, â, and m â quantum numbers. An orbital can contain two electrons with paired spins and is often associated with a specific region of an atom.xamples: The electrons in the 2p x orbital of an atom are generally found within a dumbbell-shaped cloud about the x-axis. Return to the Chemistry Glossary Index.