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Al is just a more logical way to pronounce he tow words in a faster manner. Hombre=man. Not really much to that one. So all together, al hombre is the equivalent of saying to the man..
The name al-Salaam is a Name of Allaah, may He be exalted, so the meaning of the greeting of salaam which is required among Muslims is, May the blessing of His Name descend upon you.. The usage of the preposition 'ala in 'alaykum (upon you) indicates that the greeting is inclusive.