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In quantum mechanics, an atomic orbital is a mathematical function that describes the wave-like behavior of either one electron or a pair of electrons in an atom. This function can be used to calculate the probability of finding any electron of an atom in any specific region around the atom's nucleus.
1 An orbital is a wave function for an electron defined by the three quantum numbers, n, â and m l. 2  Orbitals define regions in space where you are likely to find electrons. 3  s orbitals (â = 0) are spherical shaped. 4  p orbitals (â = 1) are dumb-bell shaped.