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Al is just a more logical way to pronounce he tow words in a faster manner. Hombre=man. Not really much to that one. So all together, al hombre is the equivalent of saying to the man..
4. hombre. Literally meaning 'man' (originally denoting Spanish descent). Commonly used as slang for 'dude' as a variant of 'homeboy' or 'homie'. A term of endearment used to address an acquaintance from one's town or neighbourhood, or a member of one's peer group or gang. Hey... hey, hombre.