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1 The skin condition known as rosacea can also cause hot face and ears. Other symptoms include broken veins and redness.  The condition can also be a sign of carcinoid syndrome. Hormone releasing tumors in the appendix, bronchial tubes, colon or small intestine cause this syndrome.
Heat can also trigger inflammation and itching. Besides directly causing eczema, hot temperatures cause the skin to dry out and also trigger sweating. Dry skin and sweating are two known triggers of eczema. When the skin gets dry, it cracks and wrinkles.