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In quantum mechanics, an atomic orbital is a mathematical function that describes the wave-like behavior of either one electron or a pair of electrons in an atom. This function can be used to calculate the probability of finding any electron of an atom in any specific region around the atom's nucleus.
The electrons creating the orbital that is located the furthest away from the nucleus have the most energy. Orbitals closer to the nucleus have gradually and slightly less energy (See diagram below). At the atomic level, the electrons are orbiting the nucleus at the speed of light. But electrons can for various reasons also jump between orbitals, which requires energy to do so. If an electron jumps from an inner orbital to an outer higher energy orbital, the electron uses energy.