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Caffeine withdrawal symptoms typically appear 12 to 24 hours after abstaining from coffee, and peak within 24 to 48 hours. They include: headache; lethargy and drowsiness; depressed mood; anxiety; nausea; vomiting; muscle pain and stiffness; and inability to concentrate.
When you deprive your body of the caffeine it has grown accustomed to, it struggles to cope with this sudden change. In the coping process, you end up with a pounding headache. Headaches, irritability, lethargy, nervousness, and mild depression are all fairly common withdrawal symptoms associated with caffeine intake.