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Caffeine withdrawal symptoms typically appear 12 to 24 hours after abstaining from coffee, and peak within 24 to 48 hours. They include: headache; lethargy and drowsiness; depressed mood; anxiety; nausea; vomiting; muscle pain and stiffness; and inability to concentrate.
Caffeine is a diuretic, which means that it helps your body get rid of fluids. This can lead to increased frequency of urination, especially when for individuals who get their caffeine fix through a drink like coffee, soda or tea. The diuretic effects of caffeine may lead to nausea in some people as well. In some cases, people may even vomit after having too much caffeine, although people are more than likely to just feel nauseous, and actually vomiting is a very rare side effect.