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1 The skin condition known as rosacea can also cause hot face and ears. Other symptoms include broken veins and redness.  The condition can also be a sign of carcinoid syndrome. Hormone releasing tumors in the appendix, bronchial tubes, colon or small intestine cause this syndrome.
A hot shower usually leads to excessive drying of the skin. This is one of the major causes of itchy skin after a hot shower. Hard water can leave a fine layer of soap film on your skin which can then trigger the itching sensation. Hard water contains calcium which can make your skin dry and itchy.