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1 The skin condition known as rosacea can also cause hot face and ears. Other symptoms include broken veins and redness.  The condition can also be a sign of carcinoid syndrome. Hormone releasing tumors in the appendix, bronchial tubes, colon or small intestine cause this syndrome.
It's difficult to be sure of the cause of your hot ears. It's possible this symptom is related to changing hormone levels. Hot flushes can affect the whole body but can be mainly felt on the face and neck. From your description it's not clear if you're having any other symptoms that might be related to the menopause.