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1 The skin condition known as rosacea can also cause hot face and ears. Other symptoms include broken veins and redness.  The condition can also be a sign of carcinoid syndrome. Hormone releasing tumors in the appendix, bronchial tubes, colon or small intestine cause this syndrome.
The face will feel tight and will burn after washing. Facial burning sensation can also be caused by eczema, an itchy skin condition. Due to eczema, excessive itching of the face can cause the skin to split and tear, resulting in a burning sensation.