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Weather in Punta Cana in October. The average maximum daytime temperature in Punta Cana in October is a hot 31Â°C (88Â°F) with very high heat & humidity. There are usually 8 hours of bright sunshine each day, which represents 66% of the 12 hours of daylight. The average sea temperature in and around Punta Cana in October is 29Â°C (84Â°F).
Share: Facebook Tweet Google+. The best time to visit Punta Cana is from March to May, when the peak season rush trickles out of the city. Luckily, the weather is warm year-round, with average highs around 80 degrees Fahrenheit. But keep in mind: The Dominican Republic experiences some of the effects of the Atlantic hurricane season, which lasts from June to November.