Moses Billings
With the development of the daguerreotype in the 1840s, the role of the portrait painter declined in general, because it was now much easier and much cheaper to have one's likeness presented in a visual format. While many portrait painters lost business in competition with the daguerreotype, Billings instead began to produce daguerreotype prints himself. It is not known exactly which prints were made by Moses Billings, as daguerreotypes were usually signed, when signed at all, along the side of the plate. Due to the traditional storing methods of daguerreotype plates, even this signature usually quickly became illegible. However, it has been generally noted, or at least hypothesized, that his daguerreotype prints showed a level of talent and artistry above that of amateur daguerreotypists. Though it is not known exactly which prints were his, it is known that he had largely abandoned the process by the 1850s. Even after he stopped making daguerreotypes, he did continue to paint people's portraits on canvas.
Daguerreotype
The discovery and commercial availability of the halides: iodine, bromine and chlorine a few years earlier (iodine was discovered by Courtois in 1811, bromine by Löwig in 1825 and Balard in 1826 independently, and chlorine by Scheele in 1774) meant that silver photographic processes that rely on the reduction of silver iodide, silver bromide and silver chloride to metallic silver became feasible. The daguerreotype is one of these processes, but was not the first, as Niépce had experimented with paper silver chloride negatives while Wedgwood's experiments were with silver nitrate as were Schultze's stencils of letters. Hippolyte Bayard had been persuaded by Arago to wait before making his paper process public.