Atmosphere of Venus
In 1761, Russian polymath Mikhail Lomonosov observed an arc of light surrounding the part of Venus off the Sun's disc at the beginning of the egress phase of the transit and concluded that Venus has an atmosphere. In 1940, Rupert Wildt calculated that the amount of CO in the Venusian atmosphere would raise surface temperature above the boiling point for water. This was confirmed when Mariner 2 made radiometer measurements of the temperature in 1962. In 1967, Venera 4 confirmed that the atmosphere consisted primarily of carbon dioxide.
Geology of Venus
Chemical and mechanical erosion of the old lava flows is caused by reactions of the surface with the atmosphere in the presence of carbon dioxide and sulfur dioxide (see carbonate-silicate cycle for details). These two gases are the planet's first and third most abundant gases, respectively; the second most abundant gas is inert nitrogen. The reactions probably include the deterioration of silicates by carbon dioxide to produce carbonates and quartz, as well as the deterioration of silicates by sulfur dioxide to produce anhydrate calcium sulfate and carbon dioxide.