Louis I, Grand Duke of Hesse
In 1776, he became engaged to Sophie Dorothea of Württemberg, eldest daughter of Frederick II Eugene, Duke of Württemberg. The engagement was broken off so that Sophia Dorothea could marry Louis's recently widowed brother-in-law Tsarevich Paul Petrovich, son and heir of Catherine II "the Great", Empress of Russia. He received a monetary compensation when the engagement was broken.
Peter I, Grand Duke of Oldenburg
On 6 June 1781, he married Duchess Frederica of Württemberg, the second daughter of Frederick II Eugene, Duke of Württemberg and his wife, Friederike Dorothea of Brandenburg-Schwedt. Frederica's sister, Sophie, was the wife of Crown Prince Paul of Russia (the future Tsar Paul I. Peter and Frederica became the parents of two sons: August (born in 1783) and George (born in 1784).