Louis I, Grand Duke of Hesse
In 1776, he became engaged to Sophie Dorothea of Württemberg, eldest daughter of Frederick II Eugene, Duke of Württemberg. The engagement was broken off so that Sophia Dorothea could marry Louis's recently widowed brother-in-law Tsarevich Paul Petrovich, son and heir of Catherine II "the Great", Empress of Russia. He received a monetary compensation when the engagement was broken.
Princess Charlotte of Saxe-Hildburghausen
On 28 September 1805, she married Prince Paul of Wurttemberg in an extravagant wedding, but it was not a happy marriage. They had numerous arguments, and Paul was said to have many mistresses, with whom he had several affairs. However, during their marriage, they had five children:The couple separated soon after the birth of their fifth child. The idea of divorce was rejected by the King of Württemberg. Charlotte lived in a house called Sovereignty in Hildburghausen. Her eldest daughter, Princess Charlotte, visited her there quite often. Her brother, Frederick, was also a frequent visitor.