Louis I, Grand Duke of Hesse
In 1776, he became engaged to Sophie Dorothea of Württemberg, eldest daughter of Frederick II Eugene, Duke of Württemberg. The engagement was broken off so that Sophia Dorothea could marry Louis's recently widowed brother-in-law Tsarevich Paul Petrovich, son and heir of Catherine II "the Great", Empress of Russia. He received a monetary compensation when the engagement was broken.
Maria Luisa of Savoy
Maria Luisa was wed by proxy to Philip V on 12 September 1701 at the age of thirteen and was escorted to Nice, arriving there on 18 September. While in Nice, she was greeted by Pope Clement XI who gave her the Golden Rose on 20 September as a ritualistic gift for the young princess. Within a week, she sailed from Nice for Antibes and was taken to Barcelona. The official wedding took place on 2 November 1701.