Atmosphere of Venus
In 1761, Russian polymath Mikhail Lomonosov observed an arc of light surrounding the part of Venus off the Sun's disc at the beginning of the egress phase of the transit and concluded that Venus has an atmosphere. In 1940, Rupert Wildt calculated that the amount of CO in the Venusian atmosphere would raise surface temperature above the boiling point for water. This was confirmed when Mariner 2 made radiometer measurements of the temperature in 1962. In 1967, Venera 4 confirmed that the atmosphere consisted primarily of carbon dioxide.
Terraforming
The renowned astronomer Carl Sagan proposed the planetary engineering of Venus in an article published in the journal "Science" in 1961. Sagan imagined seeding the atmosphere of Venus with algae, which would convert water, nitrogen and carbon dioxide into organic compounds. As this process removed carbon dioxide from the atmosphere, the greenhouse effect would be reduced until surface temperatures dropped to "comfortable" levels. The resulting carbon, Sagan supposed, would be incinerated by the high surface temperatures of Venus, and thus be sequestered in the form of "graphite or some involatile form of carbon" on the planet's surface. However, later discoveries about the conditions on Venus made this particular approach impossible. One problem is that the clouds of Venus are composed of a highly concentrated sulfuric acid solution. Even if atmospheric algae could thrive in the hostile environment of Venus's upper atmosphere, an even more insurmountable problem is that its atmosphere is simply far too thick—the high atmospheric pressure would result in an "atmosphere of nearly pure molecular oxygen" and cause the planet's surface to be thickly covered in fine graphite powder. This volatile combination could not be sustained through time. Any carbon that was fixed in organic form would be liberated as carbon dioxide again through combustion, "short-circuiting" the terraforming process.