Louis I, Grand Duke of Hesse
In 1776, he became engaged to Sophie Dorothea of Württemberg, eldest daughter of Frederick II Eugene, Duke of Württemberg. The engagement was broken off so that Sophia Dorothea could marry Louis's recently widowed brother-in-law Tsarevich Paul Petrovich, son and heir of Catherine II "the Great", Empress of Russia. He received a monetary compensation when the engagement was broken.
Paul I of Russia
Paul I (; "Pavel Petrovich") ( – ) reigned as Emperor of Russia between 1796 and 1801. Officially, he was the only son of Peter III and Catherine the Great, though Catherine hinted that he was fathered by her lover Sergei Saltykov, who also had Romanov blood, being a descendant of the first Romanov tsar's sister, Tatiana Feodorovna Romanova.