Alkali
In chemistry, an alkali (; from Arabic: "al-qaly" "ashes of the saltwort") is a basic, ionic salt of an alkali metal or alkaline earth metal chemical element. An alkali also can be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The adjective alkaline is commonly, and alkalescent less often, used in English as a synonym for basic, especially for bases soluble in water. This broad use of the term is likely to have come about because alkalis were the first bases known to obey the Arrhenius definition of a base, and they are still among the most common bases.
Alkali metal
Other "pseudo-alkali metals" include the alkylammonium cations, in which some of the hydrogen atoms in the ammonium cation are replaced by alkyl or aryl groups. In particular, the quaternary ammonium cations () are very useful since they are permanently charged, and they are often used as an alternative to the expensive Cs to stabilise very large and very easily polarisable anions such as . Tetraalkylammonium hydroxides, like alkali metal hydroxides, are very strong bases that react with atmospheric carbon dioxide to form carbonates. Furthermore, the nitrogen atom may be replaced by a phosphorus, arsenic, or antimony atom (the heavier nonmetallic pnictogens), creating a phosphonium () or arsonium () cation that can itself be substituted similarly; while stibonium () itself is not known, some of its organic derivatives are characterised.