Emperor
The first Austrian Emperor was the last Holy Roman Emperor Francis II. In the face of aggressions by Napoleon, Francis feared for the future of the Holy Roman Empire. He wished to maintain his and his family's Imperial status in the event that the Holy Roman Empire should be dissolved, as it indeed was in 1806 when an Austrian-led army suffered a humiliating defeat at the Battle of Austerlitz. After which, the victorious Napoleon proceeded to dismantle the old "Reich" by severing a good portion from the empire and turning it into a separate Confederation of the Rhine. With the size of his imperial realm significantly reduced, Francis II, "Holy Roman Emperor" became Francis I, "Emperor of Austria". The new imperial title may have sounded less prestigious than the old one, but Francis' dynasty continued to rule from Austria and a Habsburg monarch was still an emperor ("Kaiser"), and not just merely a king ("König"), in name.
Frederick II, Holy Roman Emperor
Unlike most Holy Roman emperors, Frederick spent few years in Germany. In 1218, he helped King Philip II of France and Odo III, Duke of Burgundy, to bring an end to the War of Succession in Champagne (France) by invading Lorraine, capturing and burning Nancy, capturing Theobald I, Duke of Lorraine and forcing him to withdraw his support from Erard of Brienne-Ramerupt. After his coronation in 1220, Frederick remained either in the Kingdom of Sicily or on Crusade until 1236, when he made his last journey to Germany. He returned to Italy in 1237 and stayed there for the remaining thirteen years of his life, represented in Germany by his son Conrad.