Atmosphere of Venus
In 1761, Russian polymath Mikhail Lomonosov observed an arc of light surrounding the part of Venus off the Sun's disc at the beginning of the egress phase of the transit and concluded that Venus has an atmosphere. In 1940, Rupert Wildt calculated that the amount of CO in the Venusian atmosphere would raise surface temperature above the boiling point for water. This was confirmed when Mariner 2 made radiometer measurements of the temperature in 1962. In 1967, Venera 4 confirmed that the atmosphere consisted primarily of carbon dioxide.
Venera 4
In 1967 it was the first successful probe to perform in-place analysis of the environment of another planet. It may also have been the first probe to land on another planet, with the fate of its predecessor Venera 3 being unclear. Venera 4 provided the first chemical analysis of the Venusian atmosphere, showing it to be primarily carbon dioxide with a few percent of nitrogen and below one percent of oxygen and water vapors. The station detected a weak magnetic field and no radiation field. The outer atmospheric layer contained very little hydrogen and no atomic oxygen. The probe sent the first direct measurements proving that Venus was extremely hot, that its atmosphere was far denser than expected, and that it had lost most of its water long ago.