Atmosphere of Venus
In 1761, Russian polymath Mikhail Lomonosov observed an arc of light surrounding the part of Venus off the Sun's disc at the beginning of the egress phase of the transit and concluded that Venus has an atmosphere. In 1940, Rupert Wildt calculated that the amount of CO in the Venusian atmosphere would raise surface temperature above the boiling point for water. This was confirmed when Mariner 2 made radiometer measurements of the temperature in 1962. In 1967, Venera 4 confirmed that the atmosphere consisted primarily of carbon dioxide.
Atmosphere of Venus
The atmosphere contains a range of compounds in small quantities, including some based on hydrogen, such as hydrogen chloride (HCl) and hydrogen fluoride (HF). There is carbon monoxide, water vapour and atomic oxygen as well. Hydrogen is in relatively short supply in the Venusian atmosphere. A large amount of the planet's hydrogen is theorised to have been lost to space, with the remainder being mostly bound up in sulfuric acid (HSO) and hydrogen sulfide (HS). The loss of significant amounts of hydrogen is proven by a very high D–H ratio measured in the Venusian atmosphere. The ratio is about 0.015–0.025, which is 100–150 times higher than the terrestrial value of 1.6. According to some measurements, in the upper atmosphere of Venus D/H ratio is 1.5 higher than in the bulk atmosphere.