Alkali
The word "alkali" is derived from Arabic "al qalīy" (or "alkali"), meaning "the calcined ashes" (see calcination), referring to the original source of alkaline substances. A water-extract of burned plant ashes, called potash and composed mostly of potassium carbonate, was mildly basic. After heating this substance with calcium hydroxide ("slaked lime"), a far more strongly basic substance known as "caustic potash" (potassium hydroxide) was produced. Caustic potash was traditionally used in conjunction with animal fats to produce soft soaps, one of the caustic processes that rendered soaps from fats in the process of saponification, one known since antiquity. Plant potash lent the name to the element potassium, which was first derived from caustic potash, and also gave potassium its chemical symbol K (from the German name Kalium), which ultimately derived from alkali.
Leblanc process
Soda ash (sodium carbonate) and potash (potassium carbonate), collectively termed "alkali", are vital chemicals in the glass, textile, soap, and paper industries. The traditional source of alkali in western Europe had been potash obtained from wood ashes. However, by the 13th century, deforestation had rendered this means of production uneconomical, and alkali had to be imported. Potash was imported from North America, Scandinavia, and Russia, where large forests still stood. Soda ash was imported from Spain and the Canary Islands, where it was produced from the ashes of glasswort plants (called barilla ashes in Spain), or imported from Syria. The soda ash from glasswort plant ashes was mainly a mixture of sodium carbonate and potassium carbonate. In addition in Egypt, naturally occurring sodium carbonate, the mineral natron, was mined from dry lakebeds. In Britain, the only local source of alkali was from kelp, which washed ashore in Scotland and Ireland.