Atmosphere of Venus
In 1761, Russian polymath Mikhail Lomonosov observed an arc of light surrounding the part of Venus off the Sun's disc at the beginning of the egress phase of the transit and concluded that Venus has an atmosphere. In 1940, Rupert Wildt calculated that the amount of CO in the Venusian atmosphere would raise surface temperature above the boiling point for water. This was confirmed when Mariner 2 made radiometer measurements of the temperature in 1962. In 1967, Venera 4 confirmed that the atmosphere consisted primarily of carbon dioxide.
Terraforming of Venus
Venus could also be cooled by placing reflectors in the atmosphere. Reflective balloons floating in the upper atmosphere could create shade. The number and/or size of the balloons would necessarily be great. Geoffrey A. Landis has suggested that if enough floating cities were built, they could form a solar shield around the planet, and could simultaneously be used to process the atmosphere into a more desirable form, thus combining the solar shield theory and the atmospheric processing theory with a scalable technology that would immediately provide living space in the Venusian atmosphere. If made from carbon nanotubes or graphene (a sheet-like carbon allotrope), then the major structural materials can be produced using carbon dioxide gathered "in situ" from the atmosphere. The recently synthesised amorphous carbonia might prove a useful structural material if it can be quenched to Standard Temperature and Pressure (STP) conditions, perhaps in a mixture with regular silica glass. According to Birch's analysis, such colonies and materials would provide an immediate economic return from colonizing Venus, funding further terraforming efforts.