Daguerreotype
It is said that Daguerre has found the means to collect, on a plate prepared by him, the image produced by the camera obscura, in such a way that a portrait, a landscape, or any view, projected upon this plate by the ordinary camera obscura, leaves an imprint in light and shade there, and thus presents the most perfect of all drawings ... a preparation put over this image preserves it for an indefinite time ... the physical sciences have perhaps never presented a marvel comparable to this one.
A further clue to fixing the date of invention of the process is that when the Paris correspondent of the London periodical "The Athenaeum" reported the public announcement of the daguerreotype in 1839, he mentioned that the daguerreotypes now being produced were of considerably better quality than the ones he had seen "four years earlier".
John C. Moss
The weakness in the process came from the fact that the finished photograph had to be framed behind sealed glass to prevent oxidation of the silver, which would cause the photograph to deteriorate. Each image was unique and no copy could be made. This was largely why the daguerreotype became obsolete within 20 years of its invention.