Astronaut
The first civilian in space was Valentina Tereshkova aboard Vostok 6 (she also became the first woman in space on that mission).
Tereshkova was only honorarily inducted into the USSR's Air Force, which did not accept female pilots at that time. A month later, Joseph Albert Walker became the first American civilian in space when his X-15 Flight 90 crossed the line, qualifying him by the international definition of spaceflight. Walker had joined the US Army Air Force but was not a member during his flight. 
The first people in space who had never been a member of any country's armed forces were both Konstantin Feoktistov and Boris Yegorov aboard Voskhod 1.
Anousheh Ansari
Anousheh Ansari (; née Raissyan; born September 12, 1966) is an Iranian-American engineer and co-founder and chairwoman of Prodea Systems. Her previous business accomplishments include serving as co-founder and CEO of Telecom Technologies, Inc. (TTI). The Ansari family is also the title sponsor of the Ansari X Prize. On September 18, 2006, a few days after her 40th birthday, she became the first Iranian in space. Ansari was the fourth overall self-funded space tourist, and the first self-funded woman to fly to the International Space Station. Her memoir, "My Dream of Stars", co-written with Homer Hickam, was published by Palgrave Macmillan in 2010.