Atmosphere of Venus
In 1761, Russian polymath Mikhail Lomonosov observed an arc of light surrounding the part of Venus off the Sun's disc at the beginning of the egress phase of the transit and concluded that Venus has an atmosphere. In 1940, Rupert Wildt calculated that the amount of CO in the Venusian atmosphere would raise surface temperature above the boiling point for water. This was confirmed when Mariner 2 made radiometer measurements of the temperature in 1962. In 1967, Venera 4 confirmed that the atmosphere consisted primarily of carbon dioxide.
Neptune
At high altitudes, Neptune's atmosphere is 80% hydrogen and 19% helium. A trace amount of methane is also present. Prominent absorption bands of methane exist at wavelengths above 600 nm, in the red and infrared portion of the spectrum. As with Uranus, this absorption of red light by the atmospheric methane is part of what gives Neptune its blue hue, although Neptune's vivid azure differs from Uranus's milder cyan. Because Neptune's atmospheric methane content is similar to that of Uranus, some unknown atmospheric constituent is thought to contribute to Neptune's colour.