Moses Billings
With the development of the daguerreotype in the 1840s, the role of the portrait painter declined in general, because it was now much easier and much cheaper to have one's likeness presented in a visual format. While many portrait painters lost business in competition with the daguerreotype, Billings instead began to produce daguerreotype prints himself. It is not known exactly which prints were made by Moses Billings, as daguerreotypes were usually signed, when signed at all, along the side of the plate. Due to the traditional storing methods of daguerreotype plates, even this signature usually quickly became illegible. However, it has been generally noted, or at least hypothesized, that his daguerreotype prints showed a level of talent and artistry above that of amateur daguerreotypists. Though it is not known exactly which prints were his, it is known that he had largely abandoned the process by the 1850s. Even after he stopped making daguerreotypes, he did continue to paint people's portraits on canvas.
Louis Daguerre
After the death of Niépce in 1833, Daguerre concentrated his attention on the light-sensitive properties of silver salts, which had previously been demonstrated by Johann Heinrich Schultz and others. For the process which was eventually named the daguerreotype, he exposed a thin silver-plated copper sheet to the vapour given off by iodine crystals, producing a coating of light-sensitive silver iodide on the surface. The plate was then exposed in the camera. Initially, this process, too, required a very long exposure to produce a distinct image, but Daguerre made the crucial discovery that an invisibly faint "latent" image created by a much shorter exposure could be chemically "developed" into a visible image. Upon seeing the image, the contents of which are unknown, Daguerre said, "I have seized the light – I have arrested its flight!"