Ancient Roman architecture
Although concrete had been used on a minor scale in Mesopotamia, Roman architects perfected Roman concrete and used it in buildings where it could stand on its own and support a great deal of weight. The first use of concrete by the Romans was in the town of Cosa sometime after 273 BC. Ancient Roman concrete was a mixture of lime mortar, aggregate, pozzolana, water, and stones, and was stronger than previously-used concretes. The ancient builders placed these ingredients in wooden frames where they hardened and bonded to a facing of stones or (more frequently) bricks. The aggregates used were often much larger than in modern concrete, amounting to rubble.
Roman engineering
Cement was made of hydrated lime (calcium oxide) mixed with sand and water. The Romans discovered that substituting or supplementing the sand with a pozzolanic additive, such as volcanic ash, would produce a very hard cement, known as hydraulic mortar or hydraulic cement. They used it widely in structures such as buildings, public baths and aqueducts, ensuring their survival into the modern era.