Open-pit mining
After mining finishes, the mine area may undergo land rehabilitation. Waste dumps are contoured to flatten them out, to further stabilise them. If the ore contains sulfides it is usually covered with a layer of clay to prevent access of rain and oxygen from the air, which can oxidise the sulfides to produce sulfuric acid, a phenomenon known as acid mine drainage. This is then generally covered with soil, and vegetation is planted to help consolidate the material. Eventually this layer will erode, but it is generally hoped that the rate of leaching or acid will be slowed by the cover such that the environment can handle the load of acid and associated heavy metals. There are no long term studies on the success of these covers due to the relatively short time in which large scale open pit mining has existed. It may take hundreds to thousands of years for some waste dumps to become "acid neutral" and stop leaching to the environment. The dumps are usually fenced off to prevent livestock denuding them of vegetation. The open pit is then surrounded with a fence, to prevent access, and it generally eventually fills up with ground water. In arid areas it may not fill due to deep groundwater levels. Instead of returning the land to its former natural state, it may also be reused, converting it into recreational parks or even residential/mixed communities.
Sand casting
The choice of sand has a lot to do with the temperature at which the metal is poured. At the temperatures that copper and iron are poured, the clay gets inactivated by the heat, in that the montmorillonite is converted to illite, which is a non-expanding clay. Most foundries do not have the very expensive equipment to remove the burned out clay and substitute new clay, so instead, those that pour iron typically work with silica sand that is inexpensive compared to the other sands. As the clay is burned out, newly mixed sand is added and some of the old sand is discarded or recycled into other uses. Silica is the least desirable of the sands, since metamorphic grains of silica sand have a tendency to explode to form sub-micron sized particles when thermally shocked during pouring of the molds. These particles enter the air of the work area and can lead to silicosis in the workers. Iron foundries spend a considerable effort on aggressive dust collection to capture this fine silica. The sand also has the dimensional instability associated with the conversion of quartz from alpha quartz to beta quartz at 680 °C (1250 °F). Often, combustible additives such as wood flour are added to create spaces for the grains to expand without deforming the mold. Olivine, chromite, etc. are therefore used because they do not have a phase transition that causes rapid expansion of the grains, as well as offering greater density, which cools the metal faster, producing finer grain structures in the metal. Since they are not metamorphic minerals, they do not have the polycrystals found in silica, and subsequently do not form hazardous sub-micron sized particles.