Lithium hydride
Before the Castle Bravo nuclear weapons test in 1954, it was thought that only the less common isotope lithium-6 would breed tritium when struck with fast neutrons. The Castle Bravo test showed (accidentally) that the more plentiful lithium-7 also does so under extreme conditions, albeit by an endothermic reaction.
Castle Union
Castle Union was the code name given to one of the tests in the Operation Castle series of United States nuclear tests. It was the first test of the TX-14 thermonuclear weapon (initially the "emergency capability" EC-14), one of the first deployed U.S. thermonuclear bombs.