Ancient Roman architecture
Although concrete had been used on a minor scale in Mesopotamia, Roman architects perfected Roman concrete and used it in buildings where it could stand on its own and support a great deal of weight. The first use of concrete by the Romans was in the town of Cosa sometime after 273 BC. Ancient Roman concrete was a mixture of lime mortar, aggregate, pozzolana, water, and stones, and was stronger than previously-used concretes. The ancient builders placed these ingredients in wooden frames where they hardened and bonded to a facing of stones or (more frequently) bricks. The aggregates used were often much larger than in modern concrete, amounting to rubble.
Self-healing material
According to a 1996 study by H. L. Erlich in "Chemical Geology" journal, the self-healing ability of concrete has been improved by the incorporation of bacteria, which can induce calcium carbonate precipitation through their metabolic activity. These precipitates can build up and form an effective seal against crack related water ingress. At the First International Conference on Self Healing Materials held in April, 2007 in The Netherlands, Henk M. Jonkers and Erik Schlangen presented their research in which they had successfully used the "alkaliphilic spore-forming bacteria" as a "self-healing agent in concrete". They were the first to incorporate bacteria within cement paste for the development of self-healing concrete. It was found that the bacteria directly added to the paste only remained viable for 4 months. Later studies saw Jonkers use expanded clay particles and Van Tittlelboom use glass tubes, to protect the bacteria inside the concrete. Other strategies to protect the bacteria have also since been reported.