Cast iron
Cast iron is made from pig iron, which is the product of smelting iron ore in a blast furnace. Cast iron can be made directly from the molten pig iron or by re-melting pig iron, often along with substantial quantities of iron, steel, limestone, carbon (coke) and taking various steps to remove undesirable contaminants. Phosphorus and sulfur may be burnt out of the molten iron, but this also burns out the carbon, which must be replaced. Depending on the application, carbon and silicon content are adjusted to the desired levels, which may be anywhere from 2–3.5% and 1–3%, respectively. If desired, other elements are then added to the melt before the final form is produced by casting.
Surface chemistry of cooking
Cast iron cookware is seasoned with oil. The surface of the cast iron is not very smooth; it has pits and peaks that are not conducive to cooking. Typically, the cookware is seasoned with oil. This process leaves a thin coat of oil in the pits and on top of the peaks on the surface of the pan. This thin coat actually polymerizes, making it durable and lasting. It also prevents the cast iron from rusting, which it is prone to do. The oil that is used in a seasoned pan combines with any liquid that is used in the cooking process and creates a good contact between pan and food. Even though the cast iron itself is a poor heat conductor, the oil makes the pan effective when it is at a high temperature.