Uranium–uranium dating
U, with a half-life of about 4.5 billion years, decays to U through emission of an alpha particle to thorium-234 (Th), which is comparatively unstable with a half-life of just 24 days. Th then decays through beta particle emission to protactinium-234 (Pa)). This decays with a half-life of 6.7 hours, again through emission of a beta particle, to U. This isotope has a half-life of about 245,000 years. The next decay product, thorium-230 (Th), has a half-life of about 75,000 years and is used in the uranium-thorium technique. Although analytically simpler, in practice U/U requires knowledge of the ratio at the time the material under study was formed and is generally used only for samples older than the ca. 450,000 year upper limit of the Th/U technique. For those materials (principally marine carbonates) for which these conditions apply, it remains a superior technique.
Environmental isotopes
One way uranium isotopes are used is to date rocks from millions to billions of years ago. This is through uranium-lead dating. This technique uses zircon samples and measures the lead content in them. Zircon incorporates uranium and thorium atoms into its crystal structure, but strongly rejects lead. Thus, the only sources of lead in a zircon crystal are through decay of uranium and thorium. Both the uranium-235 and uranium-238 series decay into an isotope of lead. The "half-life" of converting U to Pb is 710 million years, and the "half-life" of converting U to Pb is 4.47 billion years. Because of high resolution mass-spectroscopy, both chains can be used to date rocks, giving complementary information about the rocks. The large difference in half-lives makes the technique robust over long time scales, from on the order of millions of years to on the order of billions of years.