C-type asteroid
The largest unequivocally C-type asteroid is 10 Hygiea, although the SMASS classification places the largest asteroid, 1 Ceres, here as well, because that scheme lacks a G-type.
16 Psyche
Psyche ( ; minor planet designation: 16 Psyche) is one of the ten most massive asteroids in the asteroid belt. It is over 200 km (120 mi) in diameter and contains a little less than 1% of the mass of the entire asteroid belt. It is thought to be the exposed iron core of a protoplanet. It is the most massive metallic M-type asteroid. Psyche was discovered by the Italian astronomer Annibale de Gasparis on 17 March 1852 from Naples and named after the Greek mythological figure Psyche.