Ancient Roman architecture
Although concrete had been used on a minor scale in Mesopotamia, Roman architects perfected Roman concrete and used it in buildings where it could stand on its own and support a great deal of weight. The first use of concrete by the Romans was in the town of Cosa sometime after 273 BC. Ancient Roman concrete was a mixture of lime mortar, aggregate, pozzolana, water, and stones, and was stronger than previously-used concretes. The ancient builders placed these ingredients in wooden frames where they hardened and bonded to a facing of stones or (more frequently) bricks. The aggregates used were often much larger than in modern concrete, amounting to rubble.
Pavement (architecture)
Segmental pavers have been used for thousands of years. The Romans built roads with them that are still there. But it was not until the mid-1940s that pavers began to be produced out of concrete. It started in the Netherlands where all the roads are made to be flexible because the country is below sea level and the ground shifts, moves and sinks. Poured concrete is not an option because it will crack. Individual units not set in concrete, and placed in sand perform far better than concrete. Before the paver was made from concrete, either real stone or a clay product was used.