Cobalt blue
Cobalt blue in impure forms had long been used in Chinese porcelain, but it was independently discovered as a pure alumina-based pigment by Louis Jacques Thénard in 1802. Commercial production began in France in 1807. The first recorded use of "cobalt blue" as a color name in English was in 1777. The leading world manufacturer of cobalt blue in the 19th century was Benjamin Wegner's Norwegian company Blaafarveværket ("blue colour works" in Dano-Norwegian). Germany was also famous for production, especially the blue colour works ("Blaufarbenwerke") in the Ore Mountains of Saxony.
Blue
Blue was a latecomer among colours used in art and decoration, as well as language and literature. Reds, blacks, browns, and ochres are found in cave paintings from the Upper Paleolithic period, but not blue. Blue was also not used for dyeing fabric until long after red, ochre, pink and purple. This is probably due to the perennial difficulty of making good blue dyes and pigments. The earliest known blue dyes were made from plants – woad in Europe, indigo in Asia and Africa, while blue pigments were made from minerals, usually either lapis lazuli or azurite.