Ancient Roman architecture
Although concrete had been used on a minor scale in Mesopotamia, Roman architects perfected Roman concrete and used it in buildings where it could stand on its own and support a great deal of weight. The first use of concrete by the Romans was in the town of Cosa sometime after 273 BC. Ancient Roman concrete was a mixture of lime mortar, aggregate, pozzolana, water, and stones, and was stronger than previously-used concretes. The ancient builders placed these ingredients in wooden frames where they hardened and bonded to a facing of stones or (more frequently) bricks. The aggregates used were often much larger than in modern concrete, amounting to rubble.
Shotcrete
Shotcrete, then known as gunite, was invented in 1907 by American taxidermist Carl Akeley to repair the crumbling façade of the Field Columbian Museum in Chicago (the old Palace of Fine Arts from the World's Columbian Exposition). He used the method of blowing dry material out of a hose with compressed air, injecting water at the nozzle as it was released. In 1911, he was granted a patent for his inventions, the "cement gun", the equipment used, and "gunite", the material that was produced. There is no evidence that Akeley ever used sprayable concrete in his taxidermy work, as is sometimes suggested. F. Trubee Davison covered this and other Akeley inventions in a special issue of "Natural History" magazine.