Mendeleev's predicted elements
Dmitri Mendeleev published a periodic table of the chemical elements in 1869 based on properties that appeared with some regularity as he laid out the elements from lightest to heaviest. When Mendeleev proposed his periodic table, he noted gaps in the table and predicted that as-then-unknown elements existed with properties appropriate to fill those gaps. He named them eka-boron, eka-aluminium and eka-silicon with atomic masses 44, 68 and 72 respectively.
Boron group
Gallium minerals were not known before August 1875, when the element itself was discovered. It was one of the elements that the inventor of the periodic table, Dmitri Mendeleev, had predicted to exist six years earlier. While examining the spectroscopic lines in zinc blende the French chemist Paul Emile Lecoq de Boisbaudran found indications of a new element in the ore. In just three months he was able to produce a sample, which he purified by dissolving it in a potassium hydroxide (KOH) solution and sending an electric current through it. The next month he presented his findings to the French Academy of Sciences, naming the new element after the Greek name for Gaul, modern France.