Second law of thermodynamics
The second law of thermodynamics may be expressed in many specific ways, the most prominent classical statements being the statement by Rudolf Clausius (1854), the statement by Lord Kelvin (1851), and the statement in axiomatic thermodynamics by Constantin Carathéodory (1909). These statements cast the law in general physical terms citing the impossibility of certain processes. The Clausius and the Kelvin statements have been shown to be equivalent.
Raoult's law
Raoult's law ( law) is a law of thermodynamics established by French chemist François-Marie Raoult in 1887. It states that the partial vapor pressure of each component of an ideal mixture of liquids is equal to the vapour pressure of the pure component multiplied by its mole fraction in the mixture. In consequence, the relative lowering of vapour pressure of a dilute solution of nonvolatile solute is equal to the mole fraction of solute in the solution.