Castle Bravo
Castle Bravo was the first in a series of high-yield thermonuclear weapon design tests conducted by the United States at Bikini Atoll, Marshall Islands, as part of "Operation Castle". Detonated on March 1, 1954, the device was the most powerful nuclear device detonated by the United States and its first lithium deuteride fueled thermonuclear weapon. Castle Bravo's yield was 15 megatons of TNT, 2.5 times the predicted 6.0 megatons, due to unforeseen additional reactions involving Li, which led to the unexpected radioactive contamination of areas to the east of Bikini Atoll.
Castle Bravo
The Soviet Union had previously used lithium deuteride in its Sloika design (known as the "Joe-4" in the U.S.), in 1953. It was not a true hydrogen bomb; fusion provided only 15–20% of its yield, most coming from boosted fission reactions. Its yield was 400 kilotons, and it could not be infinitely scaled, as with a true thermonuclear device.