Cobalt blue
Cobalt blue in impure forms had long been used in Chinese porcelain, but it was independently discovered as a pure alumina-based pigment by Louis Jacques Thénard in 1802. Commercial production began in France in 1807. The first recorded use of "cobalt blue" as a color name in English was in 1777. The leading world manufacturer of cobalt blue in the 19th century was Benjamin Wegner's Norwegian company Blaafarveværket ("blue colour works" in Dano-Norwegian). Germany was also famous for production, especially the blue colour works ("Blaufarbenwerke") in the Ore Mountains of Saxony.
Orange (colour)
In 1797 a French scientist Louis Vauquelin discovered the mineral crocoite, or lead chromate, which led in 1809 to the invention of the synthetic pigment chrome orange. Other synthetic pigments, cobalt red, cobalt yellow, and cobalt orange, the last made from cadmium sulfide plus cadmium selenide, soon followed. These new pigments, plus the invention of the metal paint tube in 1841, made it possible for artists to paint outdoors and to capture the colours of natural light.