Uranium
Uranium-238 is the most stable isotope of uranium, with a half-life of about 4.468 years, roughly the age of the Earth. Uranium-235 has a half-life of about 7.13 years, and uranium-234 has a half-life of about 2.48 years.
For natural uranium, about 49% of its alpha rays are emitted by each of U atom, and also 49% by U (since the latter is formed from the former) and about 2.0% of them by the U. When the Earth was young, probably about one-fifth of its uranium was uranium-235, but the percentage of U was probably much lower than this.
Spent nuclear fuel
If using a thorium fuel to produce fissile U-233, the SNF (Spent Nuclear Fuel) will have U-233, with a half-life of 159,200 years (unless this uranium is removed from the spent fuel by a chemical process). The presence of U-233 will affect the long-term radioactive decay of the spent fuel. If compared with MOX fuel, the activity around one million years in the cycles with thorium will be higher due to the presence of the not fully decayed U-233.