Iron ore
In cast iron sulfur promotes the formation of white iron. As little as 0.5% can counteract the effects of slow cooling and a high silicon content . White cast iron is more brittle, but also harder. It is generally avoided, because it is difficult to work, except in China where high sulfur cast iron, some as high as 0.57%, made with coal and coke, was used to make bells and chimes . According to , good foundry iron should have less than 0.15% sulfur. In the rest of the world a high sulfur cast iron can be used for making castings, but will make poor wrought iron.
Cast bullet
Firearms projectiles were being cast in the 14th century. Iron was used for cannon, while lead was the preferred material for small arms. Lead was more expensive than iron, but it was softer and less damaging to the relatively weak iron barrels of early muskets. Lead could be cast in a ladle over a wood fire used for cooking or home heating, while casting iron required higher temperatures. Greater density of lead allowed lead bullets to retain velocity and energy better than iron bullets of the same weight and initial firing velocity.
Swaging, rather than casting, became a preferred manufacturing technique during the 19th century industrial revolution; but cast bullets remained popular in early rimmed black powder cartridges like the .32-20 Winchester, .32-40 Ballard, .38-40 Winchester, .38-55 Winchester, .44-40 Winchester, .45 Colt, and .45-70. Disadvantages became evident as loadings shifted to smokeless powder in the late 19th century. Higher velocity smokeless powder loadings caused lead to melt and be torn from soft bullets to remain in the barrel after firing in small deposits called "leading".. Manufacturers of high-velocity military ammunition modified their bullet swaging process to apply a thin sheet of stronger metal over the soft lead bullet. Although it took several decades to devise bullet jacket alloys and manufacturing procedures to duplicate the accuracy of cast bullets at lower velocities; jacketed bullets were more accurate at the velocity of 20th century military rifle cartridges. Jacketed bullets also functioned more reliably and are less likely to be deformed in the mechanical loading process of self-loading pistols and machine-guns.