Hydroxide
Hydroxide is a diatomic anion with chemical formula OH. It consists of an oxygen and hydrogen atom held together by a covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. A hydroxide attached to a strongly electropositive center may itself ionize, liberating a hydrogen cation (H), making the parent compound an acid.
Hydroxide
In aqueous solution the hydroxide ion is a base in the Brønsted–Lowry sense as it can accept a proton from a Brønsted–Lowry acid to form a water molecule. It can also act as a Lewis base by donating a pair of electrons to a Lewis acid. In aqueous solution both hydrogen and hydroxide ions are strongly solvated, with hydrogen bonds between oxygen and hydrogen atoms. Indeed, the bihydroxide ion has been characterized in the solid state. This compound is centrosymmetric and has a very short hydrogen bond (114.5 pm) that is similar to the length in the bifluoride ion (114 pm). In aqueous solution the hydroxide ion forms strong hydrogen bonds with water molecules. A consequence of this is that concentrated solutions of sodium hydroxide have high viscosity due to the formation of an extended network of hydrogen bonds as in hydrogen fluoride solutions.