Iron ore
In cast iron sulfur promotes the formation of white iron. As little as 0.5% can counteract the effects of slow cooling and a high silicon content . White cast iron is more brittle, but also harder. It is generally avoided, because it is difficult to work, except in China where high sulfur cast iron, some as high as 0.57%, made with coal and coke, was used to make bells and chimes . According to , good foundry iron should have less than 0.15% sulfur. In the rest of the world a high sulfur cast iron can be used for making castings, but will make poor wrought iron.
Surface chemistry of cooking
Cast iron cookware is seasoned with oil. The surface of the cast iron is not very smooth; it has pits and peaks that are not conducive to cooking. Typically, the cookware is seasoned with oil. This process leaves a thin coat of oil in the pits and on top of the peaks on the surface of the pan. This thin coat actually polymerizes, making it durable and lasting. It also prevents the cast iron from rusting, which it is prone to do. The oil that is used in a seasoned pan combines with any liquid that is used in the cooking process and creates a good contact between pan and food. Even though the cast iron itself is a poor heat conductor, the oil makes the pan effective when it is at a high temperature.