Lithium hydride
Before the Castle Bravo nuclear weapons test in 1954, it was thought that only the less common isotope lithium-6 would breed tritium when struck with fast neutrons. The Castle Bravo test showed (accidentally) that the more plentiful lithium-7 also does so under extreme conditions, albeit by an endothermic reaction.
Operation Castle
Because "Castle Bravo" greatly exceeded its expected yield, JTF-7 was caught unprepared. Much of the permanent infrastructure on Bikini Atoll was heavily damaged. The intense thermal flash ignited a fire at a distance of on the island of Eneu (base island of Bikini Atoll). The ensuing fallout contaminated all of the atoll, so much so, that it could not be approached by JTF-7 for 24 hours after the test, and even then exposure times were limited. As the fallout spread downwind to the east, more atolls were contaminated by radioactive calcium ash from the incinerated underwater coral banks. Although the atolls were evacuated soon after the test, 239 Marshallese on the Utirik, Rongelap, and Ailinginae Atolls were subjected to significant levels of radiation. 28 Americans stationed on the Rongerik Atoll were also exposed. Follow-up studies of the contaminated individuals began soon after the blast as Project 4.1, and though the short-term effects of the radiation exposure for most of the Marshallese were mild and/or hard to correlate, the long-term effects were pronounced. Additionally, 23 Japanese fishermen aboard "Daigo Fukuryū Maru" were also exposed to high levels of radiation. They suffered symptoms of radiation poisoning, and one crew member died in September 1954.