Uranium–uranium dating
U, with a half-life of about 4.5 billion years, decays to U through emission of an alpha particle to thorium-234 (Th), which is comparatively unstable with a half-life of just 24 days. Th then decays through beta particle emission to protactinium-234 (Pa)). This decays with a half-life of 6.7 hours, again through emission of a beta particle, to U. This isotope has a half-life of about 245,000 years. The next decay product, thorium-230 (Th), has a half-life of about 75,000 years and is used in the uranium-thorium technique. Although analytically simpler, in practice U/U requires knowledge of the ratio at the time the material under study was formed and is generally used only for samples older than the ca. 450,000 year upper limit of the Th/U technique. For those materials (principally marine carbonates) for which these conditions apply, it remains a superior technique.
Isotopes of uranium
Uranium-233 is produced by the neutron irradiation of thorium-232. When thorium-232 absorbs a neutron, it becomes thorium-233, which has a half-life of only 22 minutes. Thorium-233 decays into protactinium-233 through beta decay. Protactinium-233 has a half-life of 27 days and beta decays into uranium-233; some proposed molten salt reactor designs attempt to physically isolate the protactinium from further neutron capture before beta decay can occur.