Hydroxide
The solubility in water of the other hydroxides in this group increases with increasing atomic number. Magnesium hydroxide Mg(OH) is a strong base (up to the limit of its solubility, which is very low in pure water), as are the hydroxides of the heavier alkaline earths: calcium hydroxide, strontium hydroxide, and barium hydroxide. A solution or suspension of calcium hydroxide is known as limewater and can be used to test for the weak acid carbon dioxide. The reaction Ca(OH) + CO Ca + + OH illustrates the basicity of calcium hydroxide. Soda lime, which is a mixture of the strong bases NaOH and KOH with Ca(OH), is used as a CO absorbent.
Aluminium hydroxide
Four polymorphs of aluminium hydroxide exist, all based on the common combination of one aluminium atom and three hydroxide molecules into different crystalline arrangements that determine the appearance and properties of the compound. The four combinations are:
All polymorphs are composed of layers of octahedral aluminium hydroxide units with the aluminium atom in the centre and the hydroxyl groups on the sides, with hydrogen bonds holding the layers together. The polymorphisms vary in how the layers stack together, with the arrangements of the molecules and layers determined by the acidity, presence of ions (including salt) and the surface of the minerals the substance forms on. Under most conditions, gibbsite is the most chemically stable form of aluminium hydroxide. All forms of Al(OH) crystals are hexagonal.