Lithium hydride
Before the Castle Bravo nuclear weapons test in 1954, it was thought that only the less common isotope lithium-6 would breed tritium when struck with fast neutrons. The Castle Bravo test showed (accidentally) that the more plentiful lithium-7 also does so under extreme conditions, albeit by an endothermic reaction.
Nuclear technology
Military accidents usually involve the loss or unexpected detonation of nuclear weapons. The Castle Bravo test in 1954 produced a larger yield than expected, which contaminated nearby islands, a Japanese fishing boat (with one fatality), and raised concerns about contaminated fish in Japan. In the 1950s through 1970s, several nuclear bombs were lost from submarines and aircraft, some of which have never been recovered. The last twenty years have seen a marked decline in such accidents.