Iron ore
In cast iron sulfur promotes the formation of white iron. As little as 0.5% can counteract the effects of slow cooling and a high silicon content . White cast iron is more brittle, but also harder. It is generally avoided, because it is difficult to work, except in China where high sulfur cast iron, some as high as 0.57%, made with coal and coke, was used to make bells and chimes . According to , good foundry iron should have less than 0.15% sulfur. In the rest of the world a high sulfur cast iron can be used for making castings, but will make poor wrought iron.
Wrought iron
Wrought iron may be welded in the same manner as mild steel, but the presence of oxide or inclusions will give defective results.
The material has a rough surface, so it can hold platings and coatings better. For instance, a galvanic zinc finish applied to wrought iron is approximately 25–40% thicker than the same finish on steel. In Table 1, the chemical composition of wrought iron is compared to that of pig iron and carbon steel. Although it appears that wrought iron and plain carbon steel have similar chemical compositions, that is deceiving. Most of the manganese, sulfur, phosphorus, and silicon are incorporated into the slag fibers present in the wrought iron, so, really, wrought iron is purer than plain carbon steel.