C-type asteroid
The largest unequivocally C-type asteroid is 10 Hygiea, although the SMASS classification places the largest asteroid, 1 Ceres, here as well, because that scheme lacks a G-type.
Asteroid family
Additionally, some interlopers from the heterogeneous background asteroid population are expected even in the central regions of a family. Since the true family members caused by the collision are expected to have similar compositions, most such interlopers can in principle be recognised by spectral properties which do not match those of the bulk of family members. A prominent example is 1 Ceres, the largest asteroid, which is an interloper in the family once named after it (the Ceres family, now the Gefion family).