Ancient Roman architecture
Although concrete had been used on a minor scale in Mesopotamia, Roman architects perfected Roman concrete and used it in buildings where it could stand on its own and support a great deal of weight. The first use of concrete by the Romans was in the town of Cosa sometime after 273 BC. Ancient Roman concrete was a mixture of lime mortar, aggregate, pozzolana, water, and stones, and was stronger than previously-used concretes. The ancient builders placed these ingredients in wooden frames where they hardened and bonded to a facing of stones or (more frequently) bricks. The aggregates used were often much larger than in modern concrete, amounting to rubble.
Pumice
Pumice is widely used to make lightweight concrete or insulative low-density cinder blocks. When used as an additive for cement, a fine-grained version of pumice called pozzolan is mixed with lime to form a light-weight, smooth, plaster-like concrete. This form of concrete was used as far back as Roman times. Roman engineers used it to build the huge dome of the Pantheon and as construction material for many aqueducts.