Names given to the Spanish language
Formally speaking, the national language of Spain, the official Spanish language, is the Castilian language (as opposed to regional Spanish languages like Galician, Catalan, Asturleonese and Basque). As such both names, "español" and "castellano", have distinct and independent meanings that may be required for clarity in some specific contexts.
Generally speaking, though, both terms can be used to refer to the (national) Spanish language as a whole, with a preference for one over the other that depends on the context or the speaker's origin. "Castellano" (as well as "Castilian" in English) has another, more restricted, meaning, relating either to the old Romance language spoken in the Kingdom of Castile in the Middle Ages, predecessor of the modern Spanish language, or to the variety of Spanish nowadays spoken in the historical region of Castile, in central Spain.
Spanish language
In Africa, Spanish is official (along with Portuguese and French) in Equatorial Guinea, as well as an official language of the African Union. In Equatorial Guinea, Spanish is the predominant language when native and non-native speakers (around 500,000 people) are counted, while Fang is the most spoken language by number of native speakers.