Lithium hydride
Before the Castle Bravo nuclear weapons test in 1954, it was thought that only the less common isotope lithium-6 would breed tritium when struck with fast neutrons. The Castle Bravo test showed (accidentally) that the more plentiful lithium-7 also does so under extreme conditions, albeit by an endothermic reaction.
Castle Bravo
The device was called SHRIMP and had the same basic configuration (radiation implosion) as the "Ivy Mike" wet device, except with a different type of fusion fuel. "SHRIMP" used lithium deuteride (LiD), which is solid at room temperature; "Ivy Mike" used cryogenic liquid deuterium (D), which required elaborate cooling equipment. "Castle Bravo" was the first test by the United States of a practical deliverable fusion bomb, even though the TX-21 as proof-tested in the Bravo event was not weaponized. The successful test rendered obsolete the cryogenic design used by "Ivy Mike" and its weaponized derivative, the "JUGHEAD", which was slated to be tested as the initial "Castle Yankee". It also used a 7075 aluminum 9.5 cm thick ballistic case. Aluminum was used to drastically reduce bomb's weight and simultaneously provided sufficient radiation confinement time to raise yield, a departure from the heavy stainless steel casing (304L or MIM 316L) employed by contemporary weapon-projects.