Atomic mass
Any mass defect due to nuclear binding energy is experimentally a small fraction (less than 1%) of the mass of equal number of free nucleons. When compared to the average mass per nucleon in carbon-12, which is moderately strongly-bound compared with other atoms, the mass defect of binding for most atoms is an even smaller fraction of a dalton (unified atomic mass unit, based on carbon-12). Since free protons and neutrons differ from each other in mass by a small fraction of a dalton (about 0.0014 u), rounding the relative isotopic mass, or the atomic mass of any given nuclide given in daltons to the nearest whole number always gives the nucleon count, or mass number. Additionally, the neutron count (neutron number) may then be derived by subtracting the number of protons (atomic number) from the mass number (nucleon count).
Whole number rule
During the 1920s, it was thought that the atomic nucleus was made of protons and electrons, which would account for the disparity between the atomic number of an atom and its atomic mass. In 1932, James Chadwick discovered an uncharged particle of approximately the mass as the proton, which he called the neutron. The fact that the atomic nucleus is composed of protons and neutrons was rapidly accepted and Chadwick was awarded the Nobel Prize in Physics in 1935 for his discovery.