Graphene
The theory of graphene was first explored by Wallace in 1947 as a starting point for understanding the electronic properties of 3D graphite. The emergent massless Dirac equation was first pointed out by Semenoff, DiVincenzo and Mele. The earliest TEM images of few-layer graphite were published by Ruess and Vogt in 1948. An early, detailed study on few-layer graphite dates to 1962 when Boehm and colleagues reported producing monolayer flakes of reduced graphene oxide. Efforts to make thin films of graphite by mechanical exfoliation started in 1990, but nothing thinner than 50 to 100 layers was produced before 2004. Initial attempts to make atomically thin graphitic films employed exfoliation techniques similar to the drawing method. Multilayer samples down to 10 nm in thickness were obtained.
Flexography
In 1890, the first such patented press was built in Liverpool, England by Bibby, Baron and Sons. The water-based ink smeared easily, leading the device to be known as "Bibby's Folly". In the early 1900s, other European presses using rubber printing plates and aniline oil-based ink were developed. This led to the process being called "aniline printing". By the 1920s, most presses were made in Germany, where the process was called "gummidruck", or rubber printing. In modern-day Germany, they continue to call the process "gummidruck".