Mendeleev's predicted elements
Dmitri Mendeleev published a periodic table of the chemical elements in 1869 based on properties that appeared with some regularity as he laid out the elements from lightest to heaviest. When Mendeleev proposed his periodic table, he noted gaps in the table and predicted that as-then-unknown elements existed with properties appropriate to fill those gaps. He named them eka-boron, eka-aluminium and eka-silicon with atomic masses 44, 68 and 72 respectively.
History of the periodic table
His book, Die modernen Theorien der Chemie, which he began writing in Breslau in 1862 and which was published two years later, contained an early version of the periodic table containing 28 elements, classified elements into six families by their valence—for the first time, elements had been grouped according to their valence. Works on organizing the elements by atomic weight, until then had been stymied by inaccurate measurements of the atomic weights.