Writing
The invention of the first writing systems is roughly contemporary with the beginning of the Bronze Age of the late 4th millennium BC. The Sumerian archaic cuneiform script and the Egyptian hieroglyphs are generally considered the earliest writing systems, both emerging out of their ancestral proto-literate symbol systems from 3400 to 3200 BC with earliest coherent texts from about 2600 BC. It is generally agreed that Sumerian writing was an independent invention; however, it is debated whether Egyptian writing was developed completely independently of Sumerian, or was a case of cultural diffusion.
Conservation and restoration of copper-based objects
Alloying copper with tin to make bronze was first practiced about 4000 years after the discovery of copper smelting, and about 2000 years after "natural bronze" had come into general use. Bronze artifacts from Sumerian cities and Egyptian artifacts of copper and bronze alloys date to 3000 BC. The Bronze Age began in Southeastern Europe around 3700 - 3300 BC, in Northwestern Europe about 2500 BC. It ended with the beginning of the Iron Age, 2000-1000 BC in the Near East, 600 BC in Northern Europe. The transition between the Neolithic period and the Bronze Age was formerly termed the Chalcolithic period (copper-stone), with copper tools being used with stone tools. This term has gradually fallen out of favor because in some parts of the world the Calcholithic and Neolithic are coterminous at both ends. Brass, an alloy of copper and zinc, is of much more recent origin. It was known to the Greeks, but became a significant supplement to bronze during the Roman Empire.