Chemical element
Whereas the mass number simply counts the total number of neutrons and protons and is thus a natural (or whole) number, the atomic mass of a single atom is a real number giving the mass of a particular isotope (or "nuclide") of the element, expressed in atomic mass units (symbol: u). In general, the mass number of a given nuclide differs in value slightly from its atomic mass, since the mass of each proton and neutron is not exactly 1 u; since the electrons contribute a lesser share to the atomic mass as neutron number exceeds proton number; and (finally) because of the nuclear binding energy. For example, the atomic mass of chlorine-35 to five significant digits is 34.969 u and that of chlorine-37 is 36.966 u. However, the atomic mass in u of each isotope is quite close to its simple mass number (always within 1%). The only isotope whose atomic mass is exactly a natural number is C, which by definition has a mass of exactly 12 because u is defined as 1/12 of the mass of a free neutral carbon-12 atom in the ground state.
Atom
Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and typically a similar number of neutrons. Protons and neutrons are called nucleons. More than 99.94% of an atom's mass is in the nucleus. The protons have a positive electric charge, the electrons have a negative electric charge, and the neutrons have no electric charge. If the number of protons and electrons are equal, that atom is electrically neutral. If an atom has more or fewer electrons than protons, then it has an overall negative or positive charge, respectively, and it is called an ion.