Atomic mass
The atomic mass and relative isotopic mass are sometimes confused, or incorrectly used, as synonyms of standard atomic weight (also known as atomic weight) and the standard atomic weight (a particular variety of atomic weight, in the sense that is a standardized atomic weight). However, as noted in the introduction, atomic weight and standard atomic weight represent terms for (abundance-weighted) averages of atomic masses in elemental samples, not for single nuclides. As such, atomic weight and standard atomic weight often differ numerically from relative isotopic mass and atomic mass, and they can also have different units than atomic mass when this quantity is not expressed in unified atomic mass units (see the linked article for atomic weight).
Atomic mass constant
In practice, the atomic mass constant is determined as the ratio of the electron rest mass "m" to the electron relative atomic mass "A"(e) (that is, the mass of the electron on a scale where C = 12). The relative atomic mass of the electron can be measured in cyclotron experiments, while the rest mass of the electron can be derived from other physical constants.
The current uncertainty in the value of the atomic mass constant – one part in 20 million – is almost entirely due to the uncertainty in the value of the Planck constant.