C-type asteroid
The largest unequivocally C-type asteroid is 10 Hygiea, although the SMASS classification places the largest asteroid, 1 Ceres, here as well, because that scheme lacks a G-type.
532 Herculina
Herculina is one of the larger members of the main asteroid belt. It is believed to rank among the top 20 in size, but the exact dimensions of many large asteroids are still uncertain. The current estimate for its mass would rank it close to the top 10.