Castle Bravo
Castle Bravo was the first in a series of high-yield thermonuclear weapon design tests conducted by the United States at Bikini Atoll, Marshall Islands, as part of "Operation Castle". Detonated on March 1, 1954, the device was the most powerful nuclear device detonated by the United States and its first lithium deuteride fueled thermonuclear weapon. Castle Bravo's yield was 15 megatons of TNT, 2.5 times the predicted 6.0 megatons, due to unforeseen additional reactions involving Li, which led to the unexpected radioactive contamination of areas to the east of Bikini Atoll.
Castle Bravo
This resultant extra fuel (both lithium-6 and lithium-7) contributed greatly to the fusion reactions and neutron production and in this manner greatly increased the device's explosive output. The test used lithium with a high percentage of lithium-7 only because lithium-6 was then scarce and expensive; the later "Castle Union" test used almost pure lithium-6. Had sufficient lithium-6 been available, the usability of the common lithium-7 might not have been discovered.