Atomic mass
Any mass defect due to nuclear binding energy is experimentally a small fraction (less than 1%) of the mass of equal number of free nucleons. When compared to the average mass per nucleon in carbon-12, which is moderately strongly-bound compared with other atoms, the mass defect of binding for most atoms is an even smaller fraction of a dalton (unified atomic mass unit, based on carbon-12). Since free protons and neutrons differ from each other in mass by a small fraction of a dalton (about 0.0014 u), rounding the relative isotopic mass, or the atomic mass of any given nuclide given in daltons to the nearest whole number always gives the nucleon count, or mass number. Additionally, the neutron count (neutron number) may then be derived by subtracting the number of protons (atomic number) from the mass number (nucleon count).
Atomic mass unit
The standard atomic weight (or atomic weight) scale has traditionally been a relative value, that is without a unit, with the first relative atomic mass basis suggested by John Dalton in 1803 as H. Despite the initial mass of H being used as the natural unit for relative atomic mass, it was suggested by Wilhelm Ostwald that relative atomic mass would be best expressed in terms of units of mass of oxygen (). This evaluation was made prior to the discovery of the existence of elemental isotopes, which occurred in 1912.