Sumer
Sumer () is the earliest known civilization in the historical region of southern Mesopotamia, modern-day southern Iraq, during the Chalcolithic and Early Bronze ages, and one of the first civilizations in the world along with Ancient Egypt and the Indus Valley. Living along the valleys of the Tigris and Euphrates, Sumerian farmers were able to grow an abundance of grain and other crops, the surplus of which enabled them to settle in one place. Prehistoric proto-writing dates back before 3000 BC. The earliest texts, from c. 3300 BC, come from the cities of Uruk and Jemdet Nasr; early cuneiform script emerged around 3000 BC.
Conservation and restoration of copper-based objects
Alloying copper with tin to make bronze was first practiced about 4000 years after the discovery of copper smelting, and about 2000 years after "natural bronze" had come into general use. Bronze artifacts from Sumerian cities and Egyptian artifacts of copper and bronze alloys date to 3000 BC. The Bronze Age began in Southeastern Europe around 3700 - 3300 BC, in Northwestern Europe about 2500 BC. It ended with the beginning of the Iron Age, 2000-1000 BC in the Near East, 600 BC in Northern Europe. The transition between the Neolithic period and the Bronze Age was formerly termed the Chalcolithic period (copper-stone), with copper tools being used with stone tools. This term has gradually fallen out of favor because in some parts of the world the Calcholithic and Neolithic are coterminous at both ends. Brass, an alloy of copper and zinc, is of much more recent origin. It was known to the Greeks, but became a significant supplement to bronze during the Roman Empire.