Uranium
Uranium-238 is the most stable isotope of uranium, with a half-life of about 4.468 years, roughly the age of the Earth. Uranium-235 has a half-life of about 7.13 years, and uranium-234 has a half-life of about 2.48 years.
For natural uranium, about 49% of its alpha rays are emitted by each of U atom, and also 49% by U (since the latter is formed from the former) and about 2.0% of them by the U. When the Earth was young, probably about one-fifth of its uranium was uranium-235, but the percentage of U was probably much lower than this.
Neptunium
Recovering uranium and plutonium from spent nuclear fuel for reuse is one of the major processes of the nuclear fuel cycle. As it has a long half-life of just over 2 million years, the alpha emitter Np is one of the major isotopes of the minor actinides separated from spent nuclear fuel. Many separation methods have been used to separate out the neptunium, operating on small and large scales. The small-scale purification operations have the goals of preparing pure neptunium as a precursor of metallic neptunium and its compounds, and also to isolate and preconcentrate neptunium in samples for analysis.