Second law of thermodynamics
The second law of thermodynamics may be expressed in many specific ways, the most prominent classical statements being the statement by Rudolf Clausius (1854), the statement by Lord Kelvin (1851), and the statement in axiomatic thermodynamics by Constantin Carathéodory (1909). These statements cast the law in general physical terms citing the impossibility of certain processes. The Clausius and the Kelvin statements have been shown to be equivalent.
Edward A. Guggenheim
Guggenheim produced eleven books and more than 100 papers. His first book,"Modern Thermodynamics by the Methods of Willard Gibbs" (1933), was a 206-page, detailed study, with text, figures, index, and preface by F. G. Donnan, showing how the analytical thermodynamic methods developed by Willard Gibbs leads in a straightforward manner to relations such as phases, constants, solution, systems, and laws, that are unambiguous and exact. This book, together with Gilbert N. Lewis and Merle Randall's 1923 textbook "Thermodynamics and the Free Energy of Chemical Substances", are said to be responsible for the inception of the modern science of chemical thermodynamics.