Asteroid
Although their location in the asteroid belt excludes them from planet status, the three largest objects, Ceres, Vesta, and Pallas, are intact protoplanets that share many characteristics common to planets, and are atypical compared to the majority of "potato"-shaped asteroids. The fourth largest asteroid, Hygiea, has an undifferentiated interior, like the majority of asteroids. Between them, the four largest asteroids constitute half the mass of the asteroid belt.
Space colonization
Colonization of asteroids would require space habitats. The asteroid belt has significant overall material available, the largest object being Ceres, although it is thinly distributed as it covers a vast region of space. Unmanned supply craft should be practical with little technological advance, even crossing 500 million kilometers of space. The colonists would have a strong interest in assuring their asteroid did not hit Earth or any other body of significant mass, but would have extreme difficulty in moving an asteroid of any size. The orbits of the Earth and most asteroids are very distant from each other in terms of delta-v and the asteroidal bodies have enormous momentum. Rockets or mass drivers can perhaps be installed on asteroids to direct their path into a safe course.