Dmitri Mendeleev
Unaware of the earlier work on periodic tables going on in the 1860s, he made the following table:
By adding additional elements following this pattern, Mendeleev developed his extended version of the periodic table. On 6 March 1869, he made a formal presentation to the Russian Chemical Society, titled "The Dependence between the Properties of the Atomic Weights of the Elements", which described elements according to both atomic weight (now called "relative atomic mass") and valence. This presentation stated that
Thorium
In the periodic table published by Dmitri Mendeleev in 1869, thorium and the rare-earth elements were placed outside the main body of the table, at the end of each vertical period after the alkaline earth metals. This reflected the belief at that time that thorium and the rare-earth metals were divalent. With the later recognition that the rare earths were mostly trivalent and thorium was tetravalent, Mendeleev moved cerium and thorium to group IV in 1871, which also contained the modern carbon group (group 14) and titanium group (group 4), because their maximum oxidation state was +4. Cerium was soon removed from the main body of the table and placed in a separate lanthanide series; thorium was left with group 4 as it had similar properties to its supposed lighter congeners in that group, such as titanium and zirconium.