History of glass
The history of glass-making dates back to at least 3600 years ago in Mesopotamia. However, they may have been producing second-rate copies of glass objects from Egypt, where this complex craft originated. Other archaeological evidence suggests that the first true glass was made in coastal north Syria, Mesopotamia or Egypt. The earliest known glass objects, of the mid second millennium BC, were beads, perhaps initially created as the accidental by-products of metal-working (slags) or during the production of faience, a pre-glass vitreous material made by a process similar to glazing. Glass products remained a luxury until the disasters that overtook the late Bronze Age civilizations seemingly brought glass-making to a halt.
Glass fiber
Glass wool, which is one product called "fiberglass" today, was invented in 1932–1933 by Russell Games Slayter of Owens-Corning, as a material to be used as thermal building insulation. It is marketed under the trade name Fiberglas, which has become a genericized trademark. Glass fiber when used as a thermal insulating material, is specially manufactured with a bonding agent to trap many small air cells, resulting in the characteristically air-filled low-density "glass wool" family of products.