KHON-TV
On October 23, 2006, KHON-TV was announced as the Honolulu affiliate of The CW, carrying the network on its second digital subchannel. Beginning in March 2006 (two months after the network's launch was announced), The CW had struggled to find an affiliate in Honolulu after the market's then-WB affiliate KFVE, which was seen by many as the likeliest candidate to join The CW, signed with competing network MyNetworkTV, and former UPN affiliate KIKU (which aired the network's programming in the afternoons) declined to take the CW affiliation.
KPXJ
On March 7, 2006, in a press release announcement by the network, KPXJ was confirmed as The CW's Shreveport charter affiliate. Since the network chose its charter stations based on which of them among The WB and UPN's respective affiliate bodies was the highest-rated in each market, KPXJ was chosen to join The CW over KSHV-TV as it had been the higher-rated of the two stations at the time of its agreement despite channel 45 having had a four-year headstart on KPXJ operation-wise. Eight days later on March 15, News Corporation announced that it had signed an agreement with White Knight Broadcasting, in which KSHV would become the market's MyNetworkTV affiliate, as part of a deal that also saw Fox-affiliated sister station WNTZ-TV in Alexandria being committed to join the network under a secondary affiliation.