History of glass
Glass remained a luxury material, and the disasters that overtook Late Bronze Age civilizations seem to have brought glass-making to a halt. It picked up again in its former sites, Syria and Cyprus, in the 9th century BC, when the techniques for making colorless glass were discovered. The first glassmaking "manual" dates back to ca. 650 BC. Instructions on how to make glass are contained in cuneiform tablets discovered in the library of the Assyrian king Ashurbanipal. In Egypt glass-making did not revive until it was reintroduced in Ptolemaic Alexandria. Core-formed vessels and beads were still widely produced, but other techniques came to the fore with experimentation and technological advancements. During the Hellenistic period many new techniques of glass production were introduced and glass began to be used to make larger pieces, notably table wares. Techniques developed during this period include 'slumping' viscous (but not fully molten) glass over a mould in order to form a dish and 'millefiori' (meaning 'thousand flowers') technique, where canes of multicolored glass were sliced and the slices arranged together and fused in a mould to create a mosaic-like effect. It was also during this period that colorless or decolored glass began to be prized and methods for achieving this effect were investigated more fully.
Early Christian art and architecture
Gold sandwich glass or gold glass was a technique for fixing a layer of gold leaf with a design between two fused layers of glass, developed in Hellenistic glass and revived in the 3rd century. There are a very fewer larger designs, but the great majority of the around 500 survivals are roundels that are the cut-off bottoms of wine cups or glasses used to mark and decorate graves in the Catacombs of Rome by pressing them into the mortar. The great majority are 4th century, extending into the 5th century. Most are Christian, but many pagan and a few Jewish, and had probably originally been given as gifts on marriage, or festive occasions such as New Year. Their iconography has been much studied, although artistically they are relatively unsophisticated. Their subjects are similar to the catacomb paintings, but with a difference balance including more portraiture of the deceased (usually, it is presumed). The progression to an increased number of images of saints can be seen in them. The same technique began to be used for gold tesserae for mosaics in the mid-1st century in Rome, and by the 5th century these had become the standard background for religious mosaics.