KHON-TV
On October 23, 2006, KHON-TV was announced as the Honolulu affiliate of The CW, carrying the network on its second digital subchannel. Beginning in March 2006 (two months after the network's launch was announced), The CW had struggled to find an affiliate in Honolulu after the market's then-WB affiliate KFVE, which was seen by many as the likeliest candidate to join The CW, signed with competing network MyNetworkTV, and former UPN affiliate KIKU (which aired the network's programming in the afternoons) declined to take the CW affiliation.
KZJO
On January 24, 2006, Time Warner announced that the company would merge the operations of The WB with CBS Corporation's UPN (which CBS acquired one month earlier in December 2005 following its split from Viacom), to form a joint venture called The CW Television Network. The network signed a ten-year affiliation agreement with Tribune Broadcasting for 13 of the 16 WB affiliates that the company owned at the time. KTWB was one of the three Tribune stations passed over for an affiliation as CBS-owned UPN affiliate KSTW (which was included in 11 of 14 CBS-owned UPN affiliates) was chosen as The CW's Seattle-Tacoma charter station. KTWB was slated to revert to an independent station, but on May 15, 2006, Tribune announced that it would affiliate channel 22 (and two other WB affiliates that were not included in the CW affiliation deal) with MyNetworkTV, a competing network created by News Corporation that is run by the company's Fox Television Stations and Twentieth Television units.