Green Arrow
Green Arrow is a fictional superhero who appears in comic books published by DC Comics. Created by Mort Weisinger and designed by George Papp, he first appeared in "More Fun Comics" #73 in November 1941. His real name is Oliver Jonas Queen, a wealthy businessman and owner of Queen Industries who is also a well-known celebrity in Star City. Sometimes shown dressed like the character Robin Hood, Green Arrow is an archer who uses his skills to fight crime in his home cities of Star City and Seattle, as well as alongside his fellow superheroes as a member of the Justice League. Though much less frequently used in modern stories, he also deploys a range of trick arrows with various special functions, such as glue, explosive-tipped, grappling hook, flash grenade, tear gas and even kryptonite arrows for use in a range of special situations. At the time of his debut, Green Arrow functioned in many ways as an archery-themed analogue of the very popular Batman character, but writers at DC subsequently developed him into a voice of left-wing politics very much distinct in character from Batman.
Arrow
The oldest evidence of stone-tipped projectiles, which may or may not have been propelled by a bow (c.f. atlatl), dating to c. 64,000 years ago, were found in Sibudu Cave, current South Africa.
The oldest evidence of the use of bows to shoot arrows dates to about 10,000 years ago; it is based on pinewood arrows found in the Ahrensburg valley north of Hamburg. They had shallow grooves on the base, indicating that they were shot from a bow. The oldest bow so far recovered is about 8,000 years old, found in the Holmegård swamp in Denmark.
Archery seems to have arrived in the Americas with the Arctic small tool tradition, about 4,500 years ago.