Hydrogen bond
Hydrogen bonds can vary in strength from weak (1–2 kJ mol) to strong (161.5 kJ mol in the ion ). Typical enthalpies in vapor include:
Chalcogen bond
Due to a chalcogen's ability to function as an electron donor, many systems will balance between hydrogen bonding with the chalcogen as a donor or chalcogen bonding. This balance can be observed in a series of self-bonding intermolecular interactions between various substituted chalcogens. In cases with hard chalcogen atoms as acceptors, the balance favors H-bonding between chalcogen and methyl H. However, as the acceptor atoms move down the group, chalcogen-chalcogen bonding will be favored. It is hypothesized that electrostatic forces should only dominate in a chalcogen-chalcogen bond with lighter congeners, and instead that dispersion forces dominate in the cases of heavier congeners