Chirale polyzyklische aromatische Kohlenwasserstoffe mit Affensattel-Topologie [Data]
<|begin_of_text|><|start_header_id|>system<|end_header_id|> You are a research archivist expert in dataset metadata. Answer the question truthfully.  <|eot_id|><|start_header_id|>user<|end_header_id|> Here is the Description of a dataset. Description:'In this thesis, the first chiral polycyclic aromatic hydrocarbon (PAH) with a monkey saddle topology is presented. Starting from a truxene building block that is readily preparatively accessible, the monkey saddle PAH could easily be obtained in three steps. By using additional functionalized precursors, a series of twelve derivatives has been obtained and characterized. Solid-state structures confirmed the three-dimensional shape of the PAHs unambiguously, which is induced by the five-, six- and eight-membered rings. This makes the PAH a section of a Mackay-type crystal. Due to the curvature, the target compounds exhibit triple axial chirality. Separation of the enantiomers was possible and characterization of these via CD spectroscopy and the investigation of racemization revealed half-lives ranging from a few milliseconds to several ' . Please return only a json list of at most 3 Keywords corresponding to the Description:.<|eot_id|><|start_header_id|>assistant<|end_header_id|> {"Answer" : ["chirality","monkey saddle","negative curvature","N-heteroarene","polycyclic aromatic hydrocarbons"]} <|eot_id|>
 Here is the Description of a dataset. Description:'In this thesis, the first chiral polycyclic aromatic hydrocarbon (PAH) with a monkey saddle topology is presented. Starting from a truxene building block that is readily preparatively accessible, the monkey saddle PAH could easily be obtained in three steps. By using additional functionalized precursors, a series of twelve derivatives has been obtained and characterized. Solid-state structures confirmed the three-dimensional shape of the PAHs unambiguously, which is induced by the five-, six- and eight-membered rings. This makes the PAH a section of a Mackay-type crystal. Due to the curvature, the target compounds exhibit triple axial chirality. Separation of the enantiomers was possible and characterization of these via CD spectroscopy and the investigation of racemization revealed half-lives ranging from a few milliseconds to several ' . Please return only a json list of at most 3 Keywords corresponding to the Description:.
In this thesis, the first chiral polycyclic aromatic hydrocarbon (PAH) with a monkey saddle topology is presented. Starting from a truxene building block that is readily preparatively accessible, the monkey saddle PAH could easily be obtained in three steps. By using additional functionalized precursors, a series of twelve derivatives has been obtained and characterized. Solid-state structures confirmed the three-dimensional shape of the PAHs unambiguously, which is induced by the five-, six- and eight-membered rings. This makes the PAH a section of a Mackay-type crystal. Due to the curvature, the target compounds exhibit triple axial chirality. Separation of the enantiomers was possible and characterization of these via CD spectroscopy and the investigation of racemization revealed half-lives ranging from a few milliseconds to several 
chirality; monkey saddle; negative curvature; N-heteroarene; polycyclic aromatic hydrocarbons