To date, numerous SMPs based on various structures have been developed, including polyurethane, polystyrene copolymer, and epoxy-based polymers. Among them, the thermal-induced shape memory polyurethane (SMPU) has been mostly used in practice because of its competitive mechanical and shape memory properties, e.g., high specific strength, high parameters of shape fixity and shape recovery, and a transition temperature that can be approximately tuned to room and body temperature . A variety of SMPUs have been reported with a wide range of activation temperatures and applications, such as medical devices, heat shrinkable packages, mechanical actuators, sensors, and self-deployable structures. However, common SMPUs cannot satisfy the growing trend of new multi-functional materials. Recently, the important development of shape memory polymer composites (SMPCs) with different fillers has significantly broadened the varieties and functionalities of SMPs, which significantly expand their applications . For example, spatially controlled electro-active shape recovery is achieved in CNT-filled SMPCs . Selective light heating is reported in gold nanoparticle-filled SMPCs . Multiple-SMEs have also been developed in the norbornyl-polyhedral oligomeric silsesquioxanes (POSS) copolymer . These studies indicate that the investigation of SMPCs is one of the most important research directions in the field of SMPs and polymer composites. It provides a new way to prepare polymer composites with diversified shape memory properties and more functionality .