
 State of Odisha - Act
-----------------------
 The Orissa Factories (Control of Major Accident Hazard) Rules, 2001
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 ODISHA
   
 India
 
 The Orissa Factories (Control of Major Accident Hazard) Rules, 2001
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 Rule THE-ORISSA-FACTORIES-CONTROL-OF-MAJOR-ACCIDENT-HAZARD-RULES-2001 of 2001
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* Published on 9 February 2000
* Commenced on 9 February 2000
 The Orissa Factories (Control of Major Accident Hazard) Rules, 2001
 
 Published vide Notification Orissa Gazette Extraordinary No. 387/15.3.2001-Notification No. 28/2001/5.1.21
 
 Labour & Employment Department
 
 S.R.O. No.28/2001. - Whereas the draft of the Orissa Factories (Control of Major Accident Hazard) Rules, 1999, was published as required by Sub-section (1)  of Section 115 of the Factories Act, 1948 (63 of 1948), in the Orissa Gazette dated the 9th February 2000, under the notification of the Government of Orissa in the Labour & Employment Department No. 15921-LL-iv(F)-9/2000, dated the 15th December 1999 as S.R.O. No.843 99, inviting objections and suggestions from all persons likely to be affected thereby to the expiry of a period of three months from the date of publication of the said notification in the Orissa Gazette :-
 
 And whereas no objection or suggestion has been received during the period so specified in respect of the said draft:
 
 Now, therefore, in exercise of the powers conferred by Section 41 read with Section 112 of the said Act, the State Government do hereby make the following rules, namely
 
### 1. Short title and commencement.
(1) These rules may be called the Orissa Factories (Control of Major Accident Hazard) Rules, 2001.
 
(2) They shall come into force on the date of their publication the Orissa Gazette.
 
### 2. Definitions.
(1) In these rules, unless the context otherwise require
 
(a) "Act" means the Factories Act, 1948;
 
(b) "Hazardous chemicals" means-
 
 (i) any chemical which satisfies any of the criterion laid down Part-I of Schedule 1 and is listed in Column (2) of Part II Schedule I;
 
 (ii) any chemical listed in Column (2) of Schedule II, and
 
 (iii) any chemical listed in Column (2) of Schedule III;
 
(c) "Industrial activity" means an operation or process carried out in a factory referred to in Schedule IV, involving or likely involve one or more hazardous chemicals and include on s storage or on site transport which is associated with that operation or process, as the case may be;
 
(d) "Isolated storage" means storage where no other manufacturing process other than pumping of hazardous chemicals is carried out and that storage involves atleast a quantity of that chemical set-out in Schedule II but does not include storage associated with a factory specified in Schedule IV on the same site;
 
(e) "Major accident" involving loss of life inside or outside site ten or more injuries inside and/or one or more injuries outs or release or toxi-chemicals or explosion or fire or spillage of hazardous chemicals resulting in process of adverse effects on the environment;
 
(f) "Schedule" means Schedule appended to these rules; and
 
(g) "Site" means any location where hazardous chemicals are manufactured or processed, stored, handled, used disposed of and includes the whole of an area under the control of an occupier.
 
(2) Words and expressions used but not defined in these rules shall have the same meaning as assigned to them in the Factories Act, 1948 and the Orissa Factories Rules, 1950.
 
### 3. Application.
 - This rule shall apply to -
 
(a) an industrial activity in which a hazardous chemicals, which satisfies any of the criterion laid down in Part I of Schedule I and is listed in column (2) of Part II, of the said Schedule is or may be involved; and
 
(b) isolated storage in which there is involved a quantity of a hazardous chemical listed in column (2) of Schedule II which is equal to or more than the threshold quantity specified in Column (3) thereof.
 
### 4. Collection development and dissemination of information.
(1) An occupier of a factory carrying on an industrial activity or isolated storage in terms of clauses (a) and (b) of rule 3 shall arrange to obtain or develop information on hazardous chemicals in the form of a material data sheet as specified in Schedule V which shall be accessible to workers upon request for their reference.
 
(2) The occupier while obtaining or developing a material data sheet as specified in Schedule V in respect of hazardous chemical handled by him shall ensure that the information is recorded accurately and reflects the scientific evidence used in making the hazard determination, in case, any significant information regarding the hazard of the chemical is available to the occupier later on, it shall immediately be added to the materials date sheet.
 
(3) An occupier of a factory carrying on an industrial activity or isolated storage shall provide information on demand to show that he has-
 
(a) identified the major accident hazards;
 
(b) taken adequate steps to-
 
 (i) Prevent such major accidents and to limit their consequences to persons and the environment; and
 
 (ii) Provide the persons working on the site with the information, training and equipment including antidotes necessary to ensure their safety and health.
 
(4) Every container of a hazardous chemical shall be clearly labelled or marked to identify-
 
(a) the contents of the container;
 
(b) the name and address of the manufacturer or importer of the hazardous chemical; and
 
(c) the physical, chemical and toxological data of the hazardous chemical;
 
(5) Where it is impractical to label a chemical in accordance with sub-rule (4) owing to the size of the container or the nature of the package, provision for identification shall be made for other effective means like tagging or accompanying documents.
 
### 5. Duties of Inspector.
 - The Inspector shall-
 
(a) Inspect the industrial or isolated storage, atleast once in a calendar year;
 
(b) send annually status report on compliance of these rules by the occupiers to the Ministry of Environment and Forests through the Directorate General of Factory Advice Service and Labour Institute and Ministry or Labour of Government of India; and
 
(c) enforce directions and procedures in respect of Industrial activities or isolated storages covered under the Act and in respect of pipe lines up to a distance of five hundred metres from the outside of the perimeter, of the factory regarding-
 
 (i) notification of the major accidents as per sub-rules (1) and (2) of rule 6;
 
 (ii) notification of sites as per rules 7 and 8;
 
 (iii) safety reports and safety audit as per rules 10 to 12; and
 
 (iv) preparation of on-site emergency plans as per rule 12 and involvement in preparation of offsite emergency plans in accordance with directions/instructions of the District Collectors or District Emergency Authority.
 
### 6. Notification of major accidents.
(1) Where a major accident occurs in a site, the occupier shall forthwith notify the Inspector and the Chief Inspector of that accident, and furnish thereafter to the Inspector and the Chief Inspector, a detailed report relating to the accident in instalment, if necessary, as specified in Schedule VI.
 
(2) The Inspector and the Chief Inspector shall on receipt of the report in accordance with sub-rule (1) above shall undertake a full analysis of the major accident and send the requisite information to the Ministry of Environment and Forests through the Directorate General of Factory Advice Services and Labour Institute and the Ministry of Labour of Government of India.
 
(3) An occupier shall inform to the Inspector the steps taken to avoid any repetition of such occurrence on a site.
 
(4) The Inspector and the Chief Inspector shall inform the occupier in writing any lacuna which in their opinion need to be rectified to avoid major accidents.
 
(5) The Inspector and the Chief Inspector shall compile information regarding major accidents and make available a copy of the same to the Ministry of Environment and Forest's through the Directorate General Factory Advice Service and Labour Institute and the Ministry of Labour of Government of India.
 
### 7. Application of certain rules.
(1) Rules 8, 12 and 14 shall apply to an industrial activity other than isolated storage which involves a threshold quantity of hazardous chemicals listed in column (2) of Schedule III which is equal to or more than the threshold quantity specified in the entry for that chemical in column (3) thereof.
 
(2) Rules 9 to 11 shall apply to an industrial activity other than isolated storage which involves a quantity of hazardous chemical listed in column (2) of Schedule III which is equal to or more than the threshold quantity specified in the entry for that chemical in column (4) thereof.
 
(3) Rule 8 shall apply to an isolated storage which involves a quantity of hazardous chemical listed in column (2) of Schedule II, which is equal to or more than the threshold quantity specified in the entry for that chemical in column (3) thereof.
 
(4) Rules 9 to 12 and 14 shall apply to an isolated storage which involves a quantity of hazardous chemical listed in column (2) of Schedule II which is equal to or more than the threshold quantity specified in the entry for that chemical in column (4) thereof.
 
### 8. Notification of Sites.
(1) An occupier shall not undertake any industrial activity or isolated storage unless he has notified in a written report to the Chief Inspector containing particulars specified in Scheduled VII atleast 90 (ninety) days before commencing the activity or before such shorter time as the Chief inspector may decide for the purpose of this sub-rule.
 
(2) An activity in which subsequently there is involved or likely to be involved, a threshed, quantity given in column (3) of Schedules II and III or, more of an additional hazardous chemical, (shall be deemed to be a different activity and shall be) notified accordingly.
 
(3) The Chief Inspector within 60 (sixty) days from the date of the receipt of the report in accordance with sub-rule (1), above shall examine the same and on examination, if he is of the opinion that contravention of the provisions of the Act or of the rules has taken place may issue notice to the occupier for compliance of the provisions of the Act or rules so contravened.
 
(4) Where an activity has been notified in accordance with Sub-rule (1) above and the occupier makes a change in it including an increase or decrease in the maximum quantity of hazardous chemical which is or is liable to be involved at the site or in the pipe line at the cessation of the activity, affecting the particulars specified in the report let or any subsequent report made under this rule, the occupier shall forthwith notify in a further report to the Inspector and the Chief Inspector.
 
### 9. Safety reports and safety Audit report.
(1) Subject to the provisions of sub-rule (2) of this rule, an occupier shall not undertake any industrial activity on isolated storage (to which these rules apply) unless he has prepared a safety report on that industrial activity or isolated storage containing the information specified in Schedule VIII and has sent a copy there of to the Chief Inspector atleast 90 (ninety) days before commencing of that activity)]
 
(2) The occupier of a factory carrying industrial activity or isolated storage shall arrange to carry out safety audit by a competent agency to be accredited by an accredition board constituted by the Ministry of Labour of Government of India in this behalf.
 
(3) The audit under sub-rules (1) and (2) shall be carried out as under-
 
(a) Internally once in a year by a team of suitable plant personnel;
 
(b) externally once in two years by a competent agency duly accredited in this behalf; and
 
(c) in the year when the external audit is carried out, internal audit need not be carried out.
 
(4) The occupier within 30 (thirty) days of the completion of the audit, shall send a report to the Chief Inspector with regard to the implementation of the audit recommendations, if any.
 
### 10. Updating of safety reports under rule 9.
(1) Where an occupier has made a safety report in accordance with sub-rule of rule 9, ne shall not make any modification to the industrial activity or isolated storage unless he has made a further report to take-into account those modifications and has sent a copy of the same to the Inspector and the Chief Inspector atleast 90 (ninety) days before making those modification.
 
(2) Where an occupier has made a report in accordance with sub-rule (1) of rule 9 and that industrial activity or isolated storage is continuing, the occupier shall within three years of the date of the submission of last such report, make a further report which shall have regard in particular to new technical knowledge which has affected the particulars in the previous report relating to safety and hazard assessment and shall within 30 (thirty) days or in such longer time as the Chief Inspector may agree in writing, send a copy of such report to the Inspector and the Chief Inspector.
 
### 11. Requirement for further information to be sent to the Inspector and the Chief Inspector.
 - Where in accordance with rules 9 and 10 an occupier has sent a safety report and safety audit report related to an industrial activity or isolated storage to the Inspector and the Chief Inspector, the Inspector and the Chief inspector may, by a notice served on the occupier, require him to provide such additional information as may be specified in the notice and the occupier shall send that information to the Inspector and the Chief Inspector within 90 (ninety)  days.
 
### 12. Preparation of on-site emergency plan by the occupier.
(1) The occupier shall prepare and keep an up-to-date on-site emergency plan containing details specified in Schedule IX giving details of dealing with the major accidents on the site on which the industrial activity or isolated storage is carried on and shall furnish to the Inspector and Chief Inspector of the same which shall also include the name of the person responsible for safety on the site and the names of those who are authorised to take action in accordance with the plan in the event of an emergency.
 
(2) The occupier shall ensure that the emergency plan prepared in accordance with sub-rule (1) above has taken into account any modification made in the industrial activity or isolated storage and that every person on the site who is concerned with the plan is informed of the relevant provisions.
 
(3) The occupier shall prepare the emergency plan required under Sub-rule (1) above-
 
(a) before the commencement of the industrial activity or isolated storage; and
 
(b) within 90 (ninety) days of coming into operation of the rules in case of an existing industrial activity or isolated storage.
 
(4) The occupier shall ensure that a mook-drill of the on-site emergency is conducted atleast once in every six months.
 
(5) A detailed report of the mock-drill conducted under sub-rule (4) shall be made immediately available to the Inspector and the Chief Inspector.
 
### 13. Information to be given to persons liable to be affected by a major accident.
(1) The occupier shall take appropriate steps to inform persons outside the site, who are likely to be affected by a major accident about-
 
(a) the nature of the major accident hazard; and
 
(b) the safety measures and the Do's and the Dont's which shall be adopted in the event of a major accident.
 
(2) The occupier shall take steps as required under sub-rule (1) above to inform persons abut an industrial activity or isolated storage before that activity is commenced except that in respect of an existing industrial activity or isolated storage, where the occupier shall comply with the requirements of sub-rule (1) of this rule within 90 (ninety) days of coming into operation of these rules.
 
### 14. Disclosures of information notified under these rules.
(1) Where for the purpose of evaluation, information furnished under rule 4 or rules 8 to 13 is required to be disclosed to some other persons by the Inspector or the Chief Inspector, as the case may be, that other person shall not use that information for any other purpose except for the purpose for which the information was disclosed to him/her by the Inspector or the Chief Inspector, as the case may be.
 
(2) Before disclosing the information to some other person as required under sub-rule (1) the Inspector or the Chief Inspector, as the case may be, shall intimate that other person regarding/his her obligation not to use the information for any other purpose, and shall obtain an undertaking from him/her in this regard.
 
 I
---
 See rules 2 and 3
 
 Part I – (A)  Toxic Chemicals - Chemicals having the following values of acute toxicity and which owing for their physical and chemical properties are capable of producing major accident hazards :
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|  |  |  |  |  |
| --- | --- | --- | --- | --- |
| 
 Sl. No.
  | 
 Toxicity
  | 
 Oral toxicity LD 50 (Mg./Kg.)
  | 
 Dermal toxicity LD 50 (Mg./Kg.)
  | 
 Inhalation toxicity LD 50 (Mg./Kg.)
  |
| 
 (1) | 
 (2) | 
 (3) | 
 (4) | 
 (5) |
| 
 1
  | 
 Extremely toxic
  | 
 <5
  | 
 <40
  | 
 <0.5
  |
| 
 2
  | 
 Highly toxic
  | 
 >5.50
  | 
 >40.200
  | 
 0.5-2.0
  |
| 
 3
  | 
 Toxic
  | 
 >50-200
  | 
 >200-1000
  | 
 >2-10
  |
 (B) Flammable Chemicals :
 
 (i) Flammable gases-Gases which at 20 OC. and at standard pressure of 101-3K pa. are
 
 (a) I genizable when in a mixture of 13 per cent or less by volume with air or
 
 (b) have a flammable range with air of atleast 12 percentage, points regardless of the flammable limits.
 
 Note - Flammability should be determined by tests or by calculation in accordance with methods adopted by International standard organisation I.S.O. No.10156 of 1990 or by Bureau of India Standards I.S.I. No.1446 of 1985).
 
 (ii) extremely flammable liquids-chemicals which have flash point lower than 23 °C, and holding points less than 35 °C.
 
 (iii) very highly flammable liquids-chemicals which have a flash point lower than 23 °C and initial boiling point higher than 35 °C.
 
 (iv) highly flammable liquids-chemicals which have a flashy point lower than 60 °C. but higher than 23 °C.
 
 (v) flammable liquids-chemicals which has a flash point higher than 60 °C, but lower than 90 °C.
 
 (C) Explosives- Explosives means a solid or liquid or pyrotechnic substance for a mixture of substances or an article-
 
 (a) which is in itself capable by chemical reaction or producing gas at such a temperature and pressure and as such a speed as to cause damage to the surroundings.
 
 (b) which is designed to produce an effect by heat, light, sound, gas or a move or a combination of these as the result of non-denotative self-sustaining exothermic chemical reaction.
 
 Part II – List of Hazardous Chemicals
---------------------------------------
|  |  |  |  |
| --- | --- | --- | --- |
| 
 Column I
  | 
 Column II
  | 
 Column I
  | 
 Column II
  |
| 
 1.
  | 
 Accetaldehyde
  | 
 343.
  | 
 Lead azide
  |
| 
 2.
  | 
 Acctaic acid
  | 
 344.
  | 
 Lead styphanate
  |
| 
 3.
  | 
 Acceticanhydride
  | 
 345.
  | 
 Leptophos
  |
| 
 4.
  | 
 Acetone
  | 
 346.
  | 
 Lenisite
  |
| 
 5.
  | 
 Acetone cyanohydrin
  | 
 347.
  | 
 Liquified petroleum gas
  |
| 
 6.
  | 
 Acetone thiosemicarbazide
  | 
 348.
  | 
 Lithium hydride
  |
| 
 7.
  | 
 Acctonitrite
  | 
 349.
  | 
 N-Dinitrobenzen
  |
| 
 8.
  | 
 Acctyleng
  | 
 350.
  | 
 Magnesium powder or ribbon
  |
| 
 9.
  | 
 Acetylene tetra chloride
  | 
 351.
  | 
 Malathion
  |
| 
 10.
  | 
 Acrolein
  | 
 352.
  | 
 Maleic anhydride
  |
| 
 11.
  | 
 Acrylamide
  | 
 353.
  | 
 Malononitrile
  |
| 
 12.
  | 
 Acrylonitrile
  | 
 354.
  | 
 Manganese Tricarbonyl cyclopentadiene
  |
| 
 13.
  | 
 Adipenitrile
  | 
 355.
  | 
 Mechlor ethamine
  |
| 
 14.
  | 
 Aldicarb
  | 
 356.
  | 
 Mephospholan
  |
| 
 15.
  | 
 Aldrin
  | 
 357.
  | 
 Mercuric chloride
  |
| 
 16.
  | 
 Allyl alcohol
  | 
 358.
  | 
 Mercuric oxide
  |
| 
 17.
  | 
 Alylamine
  | 
 359.
  | 
 Mercury aetata
  |
| 
 18.
  | 
 Allylchloride
  | 
 360.
  | 
 Mercury fulminate
  |
| 
 19.
  | 
 Aluminium (powder) | 
 361.
  | 
 Mercury methyl chloride
  |
| 
 20.
  | 
 Aluminium acid
  | 
 362.
  | 
 Mesitylene
  |
| 
 21.
  | 
 Aluminium borohydride
  | 
 363.
  | 
 Methaacrolcin diacetate
  |
| 
 22.
  | 
 Aluminium chloride
  | 
 364.
  | 
 Methacrylic anhydride
  |
| 
 23.
  | 
 Aluminium fluoride
  | 
 365.
  | 
 Methacrylonitrile
  |
| 
 24.
  | 
 Aluminium phosphid
  | 
 366.
  | 
 Methacryloyloxycthyl isocyanate
  |
| 
 25.
  | 
 Amino diphenyl
  | 
 367.
  | 
 Methanidophos
  |
| 
 26.
  | 
 Amino pyridine
  | 
 368.
  | 
 Methanne
  |
| 
 27.
  | 
 Amnophenol-2
  | 
 369.
  | 
 Methanesulphonyl fluoride
  |
| 
 28.
  | 
 Aminopterin
  | 
 370.
  | 
 Methidathion
  |
| 
 29.
  | 
 Amiton
  | 
 371.
  | 
 Methiocarb
  |
| 
 30.
  | 
 Amiton dialate
  | 
 372.
  | 
 Methonyl
  |
| 
 31.
  | 
 Ammonia
  | 
 373.
  | 
 Methoxy ethanol (2-methylcellosolve)
  |
| 
 32.
  | 
 Ammonium chloroplatinate
  | 
 374.
  | 
 Methoxyethyl mercuric acetate
  |
| 
 33.
  | 
 Ammonium nitrate
  | 
 375.
  | 
 Methyacrylol chloride
  |
| 
 34.
  | 
 Ammonium nitrite
  | 
 376.
  | 
 Methyl 2-chloroacrylate
  |
| 
 35.
  | 
 Ammonium picrate
  | 
 377.
  | 
 methyl alcohol
  |
| 
 36.
  | 
 Anabasine
  | 
 378.
  | 
 Methylamine
  |
| 
 37.
  | 
 Aniline
  | 
 379.
  | 
 Methyl bromide (Bromomethane) |
| 
 38.
  | 
 Aniline 2, 4, 6 = Trimethy]
  | 
 380.
  | 
 Methoyl chloride
  |
| 
 39.
  | 
 Anthraquinone
  | 
 381.
  | 
 Methyl chloroform
  |
| 
 40.
  | 
 Antimony pentrafluorid
  | 
 382.
  | 
 Methyl chloroformate
  |
| 
 41.
  | 
 Antimyein A
  | 
 383.
  | 
 Methyl cyclohexene
  |
| 
 42.
  | 
 ANTU
  | 
 384.
  | 
 Methyl disulphide
  |
| 
 43.
  | 
 Arsenic pentoxide
  | 
 385.
  | 
 Methylethy, ketone peroxide (Cone. 60%)
  |
| 
 44.
  | 
 Arsenic trioxide
  | 
 386.
  | 
 Methyl formate
  |
| 
 45.
  | 
 Aresenous trichloride
  | 
 387.
  | 
 Methyl hydrazine
  |
| 
 46.
  | 
 Arsine
  | 
 388.
  | 
 Methyl isobutyl ketone
  |
| 
 47.
  | 
 Asphalt
  | 
 389.
  | 
 Methyl isoeyanate
  |
| 
 48.
  | 
 Azinpho-ethyl
  | 
 390.
  | 
 Methylisothiocyanate
  |
| 
 49.
  | 
 Azinphos-methyl
  | 
 391.
  | 
 Methyl mercuric dicyanamide
  |
| 
 50.
  | 
 Bacitracin
  | 
 392.
  | 
 Methyl Mercaptan
  |
| 
 51.
  | 
 Barium azide
  | 
 393.
  | 
 Methyl Methacrylate
  |
| 
 52.
  | 
 Barium nitrate
  | 
 394.
  | 
 Methyl phencapton
  |
| 
 53.
  | 
 Barium nitride
  | 
 395.
  | 
 Methyl phosponic dichloride
  |
| 
 54.
  | 
 Benzal chloride
  | 
 396.
  | 
 Methyl thiocyanate
  |
| 
 55.
  | 
 Benzenamine 3-Trifluoromethyl
  | 
 397.
  | 
 Methyl trichlorosilane
  |
| 
 56.
  | 
 Benzene
  | 
 398.
  | 
 Methyl vinyl ketone
  |
| 
 57.
  | 
 Benzene sulfonyl chloride
  | 
 399.
  | 
 Methylenebis (2-chloroanlllfie)
  |
| 
 58.
  | 
 Benzene I (chloromethyl) -4 Nitro
  | 
 400.
  | 
 Methylene chloride
  |
| 
 59.
  | 
 Benzeno arsenic acid
  | 
 401.
  | 
 Methylencbis-4, 4 (2 chloroaniline)
  |
| 
 60.
  | 
 Benzene
  | 
 402.
  | 
 Metolcarb
  |
| 
 61.
  | 
 Benzidine salts
  | 
 403.
  | 
 Mevinphos
  |
| 
 62.
  | 
 Benzimidazole, 4, 5-Dichloro-2 (Trifluoromethyl) | 
 404.
  | 
 Mezacarbate
  |
| 
 63.
  | 
 Benzoquinon-P
  | 
 405.
  | 
 Mitomycin C
  |
| 
 64.
  | 
 Benzotrichloride
  | 
 406.
  | 
 Molybdenum powder
  |
| 
 65.
  | 
 Benzoyl chloride
  | 
 407.
  | 
 Monocrotophos
  |
| 
 66.
  | 
 Benzoyl peroxide
  | 
 408.
  | 
 Morpholine
  |
| 
 67.
  | 
 Benzyl chloride
  | 
 409.
  | 
 Muscinol
  |
| 
 68.
  | 
 Beryllium (Powder) | 
 410.
  | 
 Mustard gas
  |
| 
 69.
  | 
 Bicyclo (2,2,1) Heptane-2 carbonitrile
  | 
 411.
  | 
 N-Butylacctate
  |
| 
 70.
  | 
 Biphenyl
  | 
 412.
  | 
 N-Butylalcohol
  |
| 
 71.
  | 
 Bis (2-chloroethyl) sulphide
  | 
 413.
  | 
 N-Hexane
  |
| 
 72.
  | 
 Bis (chloromethyl)  ketone
  | 
 414.
  | 
 N. Methyl-N, 2, 4, 6-Tetranitroaniline
  |
| 
 73.
  | 
 Bis (Tert-butyl peroxy) cyclohexane
  | 
 415.
  | 
 Naphtha
  |
| 
 74.
  | 
 Bis (terbutylperoxy)  butane
  | 
 416.
  | 
 Naphtha solvent
  |
| 
 75.
  | 
 Bis (2, 4, 6-Trimitrophenylamine)
  | 
 417.
  | 
 Naphthalene
  |
| 
 76.
  | 
 Bis (Chloromethyl)  Other
  | 
 418.
  | 
 Naphthyl amine
  |
| 
 77.
  | 
 Bismuth and compounds
  | 
 419.
  | 
 Nickel carbony/nickel tetracarnolyl
  |
| 
 78.
  | 
 Bisphenol-A
  | 
 420.
  | 
 Nickel powder
  |
| 
 79.
  | 
 Bitoseanate
  | 
 421.
  | 
 Nicotine
  |
| 
 80.
  | 
 Boron powder
  | 
 422.
  | 
 Nicotine sulphate
  |
| 
 81.
  | 
 Boron trichloride
  | 
 423.
  | 
 Nitric acid
  |
| 
 82.
  | 
 Boron trifluoride
  | 
 424.
  | 
 Nitric oxide
  |
| 
 83.
  | 
 Boron trifluoride Comp, with methyiether, 1:1
  | 
 425.
  | 
 Nitrobenzene
  |
| 
 84.
  | 
 Bromine
  | 
 426.
  | 
 Nitrocellulose (dry) |
| 
 85.
  | 
 Bromine pentafluroride
  | 
 427.
  | 
 Nitrochlorobenzene
  |
| 
 86.
  | 
 Bromo chloro methane
  | 
 428.
  | 
 Nitrocyclohexane
  |
| 
 87.
  | 
 Bromodialone
  | 
 429.
  | 
 Nitrogen
  |
| 
 88.
  | 
 Butadiene
  | 
 430.
  | 
 Nitrogen dioxide
  |
| 
 89.
  | 
 Butane
  | 
 431.
  | 
 Nitrogen oxide
  |
| 
 90.
  | 
 Butanone-2
  | 
 432.
  | 
 Nitrogen trifluouide
  |
| 
 91.
  | 
 Butylamine tert
  | 
 433.
  | 
 Nitroglycerine
  |
| 
 92.
  | 
 Butyl glycidal ether
  | 
 434.
  | 
 Nitropropane-1
  |
| 
 93.
  | 
 Butyl isovalarate
  | 
 435.
  | 
 Nitropropane-2
  |
| 
 94.
  | 
 Butyl peroxymaleate tert
  | 
 436.
  | 
 Nitroso dimethyl amine
  |
| 
 95.
  | 
 Butyl vinyl ether
  | 
 437.
  | 
 Nonanc
  |
| 
 96.
  | 
 Butyl-n mercaptan
  | 
 438.
  | 
 Norbormide
  |
| 
 97.
  | 
 C.I. Basic green
  | 
 439.
  | 
 O-Cresol
  |
| 
 98.
  | 
 Cadmium oxide
  | 
 440.
  | 
 O-Nitro Toluene
  |
| 
 99.
  | 
 Cadmium sterate
  | 
 441.
  | 
 O-Toludine
  |
| 
 100.
  | 
 Calcium arsenate
  | 
 442.
  | 
 O-Xylene
  |
| 
 101.
  | 
 Calcium carbide f
  | 
 443.
  | 
 O/P Nitroaniline
  |
| 
 102.
  | 
 Calcium cyanide A .
  | 
 444.
  | 
 Oleum
  |
| 
 103.
  | 
 Camphecholor (Toxaphene) | 
 445.
  | 
 O.O. Diethyl Sethylsuph. methyl phos
  |
| 
 104.
  | 
 Cantharidin
  | 
 446.
  | 
 O.O. Diethyl S. propythio methyl phosdithioate.
  |
| 
 105.
  | 
 Captan
  | 
 447.
  | 
 O.O. Diethyl sethylsulphinylmethyl phoshorothicate.
  |
| 
 106.
  | 
 Carbachol chirodie
  | 
 448.
  | 
 O.O. Diethyls ethylsulphonylmethyl phospherothioate.
  |
| 
 107.
  | 
 Carbaryl
  | 
 449.
  | 
 O.O. Diethylse thylthiomethyl phosphorothioate.
  |
| 
 108.
  | 
 Carbofuran (Furadan) | 
 450.
  | 
 Oganorhodium complex
  |
| 
 109.
  | 
 Carbon tetrachloride
  | 
 451.
  | 
 Orotic acid
  |
| 
 110.
  | 
 Carbon disulphide
  | 
 452.
  | 
 Osmium tetroxide
  |
| 
 111.
  | 
 Carbon monoxide
  | 
 453.
  | 
 Oxabaia
  |
| 
 112.
  | 
 Carbophenothion
  | 
 454.
  | 
 Oxamyl
  |
| 
 113.
  | 
 Carvone
  | 
 455.
  | 
 Oxetane, 3, 3, -bis (chloromethyl) |
| 
 114.
  | 
 Cellulose nitrate
  | 
 456.
  | 
 Oxidiphenoxiarsine
  |
| 
 115.
  | 
 Chloroacctic acid
  | 
 457.
  | 
 Oxy disulfoton
  |
| 
 116.
  | 
 Chlordane
  | 
 458.
  | 
 Oxygen (liquid) |
| 
 117.
  | 
 Chlorofenvinphos
  | 
 459.
  | 
 Oxygen difluoride
  |
| 
 118.
  | 
 Chlorinated benzene
  | 
 460.
  | 
 Ozone
  |
| 
 119.
  | 
 Chlorine
  | 
 461.
  | 
 P-Mitrophenol
  |
| 
 120.
  | 
 Chlorine oxide
  | 
 462.
  | 
 Paraffin
  |
| 
 121.
  | 
 Chlorine trifluoride
  | 
 463.
  | 
 Paraoxn (Diethyl 4 Nitropheynl phosphate)
  |
| 
 122.
  | 
 Chlormephos
  | 
 464.
  | 
 Paraquat
  |
| 
 123.
  | 
 Chlormequat chloride
  | 
 465.
  | 
 Paraquat methosulphate
  |
| 
 124.
  | 
 Chloroacctal chloride
  | 
 466.
  | 
 Parathion
  |
| 
 125.
  | 
 Chloroacetaldehyde
  | 
 467.
  | 
 Parathion methyl
  |
| 
 126.
  | 
 Chloroaniline-2
  | 
 468.
  | 
 Paris green
  |
| 
 127.
  | 
 Chloroaniline-4
  | 
 469.
  | 
 Penta borane
  |
| 
 128.
  | 
 Chlorobenzene
  | 
 470.
  | 
 Penta chloro ethane
  |
| 
 129.
  | 
 Chloroethyl chloroformate
  | 
 471.
  | 
 Penta chlophenol
  |
| 
 130.
  | 
 Chloroform
  | 
 472.
  | 
 Pentabromophenol
  |
| 
 131.
  | 
 Chloroformyl morpholine
  | 
 473.
  | 
 Pentachioro naphthalene
  |
| 
 132.
  | 
 Chlormethane
  | 
 474.
  | 
 Pentadecyl-amine
  |
| 
 133.
  | 
 Chlormethyl methylether
  | 
 475.
  | 
 Pentacry thaiotol tetranitrate
  |
| 
 134.
  | 
 Chloromtrobenzene
  | 
 476.
  | 
 Pentane
  |
| 
 135.
  | 
 Chlorophacineone
  | 
 477.
  | 
 Pentanone
  |
| 
 136.
  | 
 Chlorosulphenic acid
  | 
 478.
  | 
 Perchloric acid
  |
| 
 137.
  | 
 Chlorothiophos
  | 
 479.
  | 
 Perchlorcethylene
  |
| 
 138.
  | 
 Chloroxuron
  | 
 480.
  | 
 Peroxyacertic acid
  |
| 
 139.
  | 
 Chromic acid
  | 
 481.
  | 
 Phenol
  |
| 
 140.
  | 
 Chromic chloride
  | 
 482.
  | 
 Phenol, 2, 2 - thiobis (4-6-Dichloro)
  |
| 
 141.
  | 
 Chromium powder
  | 
 483.
  | 
 Phenol, 2, -2 thiobis (4 chloro 6 methyl phenol)
  |
| 
 142.
  | 
 Cobalt carbonyl
  | 
 484.
  | 
 Phenol, 3-(1-methylethyl) methyl carbamate
  |
| 
 143.
  | 
 Cobalt Nitrimethyidyne compound
  | 
 485.
  | 
 Phenylhydrazine hydrochloride
  |
| 
 144.
  | 
 Cobalt (Powder) | 
 486.
  | 
 Phenyl mercury acetate
  |
| 
 145.
  | 
 Colchicine
  | 
 487.
  | 
 Phenyl silatrane
  |
| 
 146.
  | 
 Copper and compounds
  | 
 488.
  | 
 Phenyl thiourea
  |
| 
 147.
  | 
 Copperoxychloride
  | 
 489.
  | 
 Phenylene P. diamine
  |
| 
 148.
  | 
 Coumafuryl
  | 
 490.
  | 
 Phorate
  |
| 
 149.
  | 
 Coumaphos
  | 
 491.
  | 
 Phosazetin
  |
| 
 150.
  | 
 Coumateriralyl
  | 
 492.
  | 
 Phosfolan
  |
| 
 151.
  | 
 Crimidine
  | 
 493.
  | 
 Phosgene
  |
| 
 152.
  | 
 Crotenaldehyde
  | 
 494.
  | 
 Phosmet
  |
| 
 153.
  | 
 Crotonaldehyde
  | 
 495.
  | 
 Phosphamidon
  |
| 
 154.
  | 
 Cumene
  | 
 496.
  | 
 Phosphine
  |
| 
 155.
  | 
 Cyanogen bromide
  | 
 497.
  | 
 Phosphoric acid
  |
| 
 156.
  | 
 Cyanogeniodide
  | 
 498.
  | 
 Phospheric acid dimethyl (4-methithiophenyl).
  |
| 
 157.
  | 
 Cyanophos
  | 
 499.
  | 
 Phosphorothioic acid dimethyl S (2-Bis) Ester.
  |
| 
 158.
  | 
 Cyanothoate
  | 
 500.
  | 
 Phosphorothioic acid methyl (ester) |
| 
 159.
  | 
 Cyanyric fluoride
  | 
 501.
  | 
 Phosphorothioic acid O Dimethyl S-(2-methyl).
  |
| 
 160.
  | 
 Cyclohexylymine
  | 
 502.
  | 
 Phosphorothioic, methyl-ethyl ester
  |
| 
 161.
  | 
 Cyclohexane
  | 
 503.
  | 
 Phosphorous
  |
| 
 162.
  | 
 Cyclohexanone
  | 
 504.
  | 
 Phosphorous oxychloride
  |
| 
 163.
  | 
 Cycloheximide
  | 
 505.
  | 
 Phosphorous Pentaoxide
  |
| 
 164.
  | 
 Cyclopentadiene
  | 
 506.
  | 
 Phosphorous trichoride
  |
| 
 165.
  | 
 Cylopentane
  | 
 507.
  | 
 Phosphorous Penta chloride
  |
| 
 166.
  | 
 Cyclotetramethylenetetranit-ramine
  | 
 508.
  | 
 Phthalic anhydride
  |
| 
 167.
  | 
 Cyclotrimethylenetrinnit-ranine
  | 
 509.
  | 
 Phylloqurnone
  |
| 
 168.
  | 
 Cypermerthrin
  | 
 510.
  | 
 Physostignine
  |
| 
 169.
  | 
 DDT
  | 
 511.
  | 
 Physostignine silicylate (1.1.)
  |
| 
 170.
  | 
 Decaborane(1:4)
  | 
 512.
  | 
 Pieric acid (2-4, 6-trinitrophenol)
  |
| 
 171.
  | 
 Demeton
  | 
 513.
  | 
 Picrotoxin
  |
| 
 172.
  | 
 Demeton S. Methyl
  | 
 514.
  | 
 Piperbine
  |
| 
 173.
  | 
 Di-n-propyl propyl peroxydicarbonate (Cone = 80%)
  | 
 515.
  | 
 Piprotal
  |
| 
 174.
  | 
 Dialifos
  | 
 516.
  | 
 Pirtnifos-ethyl
  |
| 
 175.
  | 
 Diazodinitrophenol
  | 
 517.
  | 
 Platinous chloride
  |
| 
 176.
  | 
 Dihenzyl peroxy dicarbonate (Cone>90%)
  | 
 518.
  | 
 Plantinum tertrachloride
  |
| 
 177.
  | 
 Diborane
  | 
 519.
  | 
 Potassium arsenite
  |
| 
 178.
  | 
 Dichloroacetyiene
  | 
 520.
  | 
 Potassium chlorate
  |
| 
 179.
  | 
 Dichlorobenzalkonium chloride
  | 
 521.
  | 
 Potassium cyanide
  |
| 
 180.
  | 
 Dischloroethyl ether
  | 
 522.
  | 
 Potassium hydroxide
  |
| 
 181.
  | 
 Dicchloromethyl Phenylsilane
  | 
 523.
  | 
 Potassium nitride
  |
| 
 182.
  | 
 Dichlorophenol-2, 6
  | 
 524.
  | 
 Potassium nitrite
  |
| 
 183.
  | 
 Dichlorophenol-2, 4
  | 
 525.
  | 
 Potassium peroxida
  |
| 
 184.
  | 
 Dichlorophenoxy accetic acid
  | 
 526.
  | 
 Potassium silver cyanide
  |
| 
 185.
  | 
 Dichloropropene-2, 2
  | 
 527.
  | 
 Powdered metals and mixtures
  |
| 
 186.
  | 
 Dichlorosalicylic acid-3, 5
  | 
 528.
  | 
 Promeoarb
  |
| 
 187.
  | 
 Dichlorvos (DDVP) | 
 529.
  | 
 Promurit
  |
| 
 188.
  | 
 Dicrotophos
  | 
 530.
  | 
 Propanesultone
  |
| 
 189.
  | 
 Dicldrin
  | 
 531.
  | 
 Propargyl alcohol
  |
| 
 190.
  | 
 Dicpoxy butane
  | 
 532.
  | 
 Propargyl bromide
  |
| 
 191.
  | 
 Diethyl carbamazine citrate
  | 
 533.
  | 
 Propen-2-chloro-1, 3-dion diacotate
  |
| 
 192.
  | 
 Diethyl chlorophosphate
  | 
 534.
  | 
 Propiolactone beta
  |
| 
 193.
  | 
 Dicthyi enthanolamine
  | 
 535.
  | 
 Propionitrile
  |
| 
 194.
  | 
 Dicthl peroxydicarbonatex (cone = 30%)
  | 
 536.
  | 
 Propionitrile, 3-chloro
  |
| 
 195.
  | 
 Dicthyl phenylene diamine
  | 
 537.
  | 
 Propiopnenone, 4-amino
  |
| 
 196.
  | 
 Dicthylamine
  | 
 538.
  | 
 Propylene Chloroformate
  |
| 
 197.
  | 
 Dichtylene glycol
  | 
 539.
  | 
 Propylene dichloride
  |
| 
 198.
  | 
 Diclyone glocol dinitrate
  | 
 540.
  | 
 Propylene glycol, allylether
  |
| 
 199.
  | 
 Dicthylene triamine
  | 
 541.
  | 
 Propylene imine
  |
| 
 200.
  | 
 Dicthloneglycol butyi ether
  | 
 542.
  | 
 Propylene oxide
  |
| 
 201.
  | 
 Diglycidyl ether
  | 
 543.
  | 
 Prothoate
  |
| 
 202.
  | 
 Digitoxin
  | 
 544.
  | 
 Peseudocumene
  |
| 
 203.
  | 
 Dihydroperoxypropane (Con.>30%)
  | 
 545.
  | 
 Pyrozoxon
  |
| 
 204.
  | 
 Dilsobutyl peroxide
  | 
 546.
  | 
 Pyrene
  |
| 
 205.
  | 
 Dimefox
  | 
 547.
  | 
 Pyridine
  |
| 
 206.
  | 
 Dimethoate
  | 
 548.
  | 
 Pyrudine, 2-methyl-3-vinyl
  |
| 
 207.
  | 
 Dimethyl dichlorosilane
  | 
 549.
  | 
 Pyridine, 4-nitro-l-oxide
  |
| 
 208.
  | 
 Dimethyl hydrazine
  | 
 550.
  | 
 Pyridine, 4-nitro-l-oxide
  |
| 
 209.
  | 
 Dimethyl nitrosoamine
  | 
 551.
  | 
 Pyriminil
  |
| 
 210.
  | 
 Dimethyl P phenylene diamine
  | 
 552.
  | 
 Quinaliphos
  |
| 
 211.
  | 
 Dimethyl phosphoramidi cyanidic acid (TABUM) | 
 553.
  | 
 Quinone
  |
| 
 212.
  | 
 Dimethl Pho phorochloridothioate
  | 
 554.
  | 
 Rhydium trichloride
  |
| 
 213.
  | 
 Dimethyl sufolane (DMS) | 
 555.
  | 
 Salcomine
  |
| 
 214.
  | 
 Dimethyl sulphide
  | 
 556.
  | 
 Sarine
  |
| 
 215.
  | 
 Dimethylamine
  | 
 557.
  | 
 Selenious acid
  |
| 
 216.
  | 
 Dimethylaniline
  | 
 558.
  | 
 Selenium Hexafluoride
  |
| 
 217.
  | 
 Dimethylcarbonyl chloride
  | 
 559.
  | 
 Selenum oxychloride
  |
| 
 218.
  | 
 Dimetilan
  | 
 560.
  | 
 Semicarbazide hydrochloride
  |
| 
 219.
  | 
 Dinitro O-cresol
  | 
 561.
  | 
 Sillane (4-amino butyl), diethyxymeth
  |
| 
 220.
  | 
 Dinitrophenol
  | 
 562.
  | 
 Sodium
  |
| 
 221.
  | 
 Dinitrotoluene
  | 
 563.
  | 
 Sodium anthra-quinononc-1-sulphonato
  |
| 
 222.
  | 
 Dinoseb
  | 
 564.
  | 
 Sodium arsenate
  |
| 
 223.
  | 
 Dinoterb
  | 
 565.
  | 
 Sodium arsenite
  |
| 
 224.
  | 
 Dioxane-p
  | 
 566.
  | 
 Sodium azide
  |
| 
 225.
  | 
 Dioxathion
  | 
 567.
  | 
 Sodium cacodylato
  |
| 
 226.
  | 
 Dioxine N
  | 
 568.
  | 
 Sodium chlorate
  |
| 
 227.
  | 
 Diphacinone
  | 
 569.
  | 
 Sodium cyanide
  |
| 
 228.
  | 
 Diphosphoramide octamethyl
  | 
 570.
  | 
 Sodium fluro-acctate
  |
| 
 229.
  | 
 Diphenyl methane de-isocynate (MDI) | 
 571.
  | 
 Sodium hydroxide
  |
| 
 230.
  | 
 Dipropylene Glycol Butylether
  | 
 572.
  | 
 Sodium pentachloro-phenate
  |
| 
 231.
  | 
 Dipropylene glycolmethyleter
  | 
 573.
  | 
 Sodium picramate
  |
| 
 232.
  | 
 Disee-butyl peroxydicarbonate (Cone. 80%).
  | 
 574.
  | 
 Sodium selenate
  |
| 
 233.
  | 
 Disufoton
  | 
 575.
  | 
 Sodium solenite
  |
| 
 234.
  | 
 Dithiazamne redide
  | 
 576.
  | 
 Sodium sulphide
  |
| 
 235.
  | 
 Dithiobiurate
  | 
 577.
  | 
 Sodium tellorite
  |
| 
 236.
  | 
 Endosulfan
  | 
 578.
  | 
 Stannane aceloxy triphenyl
  |
| 
 237.
  | 
 Endothion
  | 
 579.
  | 
 Stibine (Antimony hydride)
  |
| 
 238.
  | 
 Endrin
  | 
 580.
  | 
 Strychine
  |
| 
 239.
  | 
 Epichlorohydrine
  | 
 581.
  | 
 Strychine sulphate
  |
| 
 240.
  | 
 E. P. N.
  | 
 582.
  | 
 Styphinic acid (2-4, 6-trinitroresorcinol)
  |
| 
 241.
  | 
 Ergocalciferol
  | 
 583.
  | 
 Stryne
  |
| 
 242.
  | 
 Erogotamine tartarate
  | 
 584.
  | 
 Sulphotec
  |
| 
 243.
  | 
 Ethanesulfenyl chloride, 2 chloro
  | 
 585.
  | 
 Sulphoxide, 3-chloropropyloctyl
  |
| 
 244.
  | 
 Ethanol 1-2 dichloracetate
  | 
 586.
  | 
 Sulphur dichlaride
  |
| 
 245.
  | 
 Ethion
  | 
 587.
  | 
 Sulphur dioxide
  |
| 
 246.
  | 
 Ethoprophos
  | 
 588.
  | 
 Sulpher monochloride
  |
| 
 247.
  | 
 Ethyl acetate
  | 
 589.
  | 
 Sulphur tetrufluoride
  |
| 
 248.
  | 
 Ethyl alcohol
  | 
 590.
  | 
 Sulphur trioxide
  |
| 
 249.
  | 
 Ethyl benzene
  | 
 591.
  | 
 Sulphuric acid
  |
| 
 250.
  | 
 Ethyl bisamine
  | 
 592.
  | 
 Tellurium (powder) |
| 
 251.
  | 
 Ethyl bromide
  | 
 593.
  | 
 Tellurium hexoffuoride
  |
| 
 252.
  | 
 Ethyl carbamate
  | 
 594.
  | 
 TEPP (Tetracthylpyrophosphate) |
| 
 253.
  | 
 Ethyl ether
  | 
 595.
  | 
 Terbufos
  |
| 
 254.
  | 
 Ethyl hexanol-2
  | 
 596.
  | 
 Tert-Butyl alcohol
  |
| 
 255.
  | 
 Ethyl mercaptan
  | 
 597.
  | 
 Tert-Butylperoxy carbonate
  |
| 
 256.
  | 
 Ethyl mercuric phosphate
  | 
 598.
  | 
 Tert-Butylperoxy isopropyl
  |
| 
 257.
  | 
 Ethyl methacrylate
  | 
 599.
  | 
 Tert-Butylperoxyncetate (Cone 70%)
  |
| 
 258.
  | 
 Ethyl nitrate
  | 
 600.
  | 
 Tert-Butylperoxypi valate (Cone.+77%)
  |
| 
 259.
  | 
 Ethyl thiocyanate
  | 
 601.
  | 
 Tert-Butyperoxylso-butyrate
  |
| 
 260.
  | 
 Ethylamine
  | 
 602.
  | 
 Terta hydrofuram
  |
| 
 261.
  | 
 Ethylene
  | 
 603.
  | 
 Terta methyl lead
  |
| 
 262.
  | 
 Ethylene chlorohydrine
  | 
 604.
  | 
 Tetra nitromethane
  |
| 
 263.
  | 
 Ethylene dibromide
  | 
 605.
  | 
 Terta-chlorodibenzo-p-dioxin, 1, 2, 3, 7, 8 (TCDD) .
  |
| 
 264.
  | 
 Ethylene diamine
  | 
 606.
  | 
 Tetraethyllead
  |
| 
 265.
  | 
 Ethylene diamine hydrochloride
  | 
 607.
  | 
 Tert-fluoriethyne
  |
| 
 266.
  | 
 Ethylene flourohydrine
  | 
 608.
  | 
 Tetramethylene disulphoteramine
  |
| 
 267.
  | 
 Ethylene glycol
  | 
 609.
  | 
 Thallic oxide
  |
| 
 268.
  | 
 Ethylene gyecol dinitrate
  | 
 610.
  | 
 Thallium carbonate
  |
| 
 269.
  | 
 Ethylene oxid
  | 
 611.
  | 
 Thallium sulphate
  |
| 
 270.
  | 
 Ethylenimine
  | 
 612.
  | 
 Thallous chloride
  |
| 
 271.
  | 
 Ethylene dichloride
  | 
 613.
  | 
 Thallous maionate
  |
| 
 272.
  | 
 Femamiphos
  | 
 614.
  | 
 Thallous sulphate
  |
| 
 273.
  | 
 Femitrothion
  | 
 615.
  | 
 Thiocarbazide
  |
| 
 274.
  | 
 Fensulphothion
  | 
 616.
  | 
 Thiocynamicacid, 2-(Benzothiazolythio)  methyl.
  |
| 
 275.
  | 
 Flumetil
  | 
 617.
  | 
 Thiotamox
  |
| 
 276.
  | 
 Fluorine
  | 
 618.
  | 
 Thiometon
  |
| 
 277.
  | 
 Flouro 2-bydroxy butyric acid amid salt ester.
  | 
 619.
  | 
 Thionazin
  |
| 
 278.
  | 
 Fluoraccitamide
  | 
 620.
  | 
 Thionyl chloride
  |
| 
 279.
  | 
 Fluoraacetic acid amide salts and caters
  | 
 621.
  | 
 Thiophenol
  |
| 
 280.
  | 
 Fluoroacetylchloride
  | 
 622.
  | 
 Thiosemicarbazide
  |
| 
 281.
  | 
 Fluorobutyric acid amide salt esters
  | 
 623.
  | 
 Thiourea (2-choloro-pheny)
  |
| 
 282.
  | 
 Fluorocrotonic acid amides salts esters
  | 
 624.
  | 
 Thiourea (2-methylphenyl)
  |
| 
 283.
  | 
 Fluorouracil
  | 
 625.
  | 
 Tirpate (2, 4, -dimethyl-1-3-di-thiolone)
  |
| 
 284.
  | 
 Fonofos
  | 
 626.
  | 
 Titanium powder
  |
| 
 285.
  | 
 Formaidchyde
  | 
 627.
  | 
 Titanium tetra-chloride
  |
| 
 286.
  | 
 Formtanate hydrochloride
  | 
 628.
  | 
 Tolueno
  |
| 
 287.
  | 
 Formic acid
  | 
 629.
  | 
 Toluene 2, 4, -di isocyanate
  |
| 
 288.
  | 
 Formoparanate
  | 
 630.
  | 
 Tolune 2, 6-di isodyanate
  |
| 
 289.
  | 
 Formothion
  | 
 631.
  | 
 Trans-1, 4-di chloro-butene
  |
| 
 290.
  | 
 Fosthiotan
  | 
 632.
  | 
 Tri nitro anisole
  |
| 
 291.
  | 
 Fuberidazole
  | 
 633.
  | 
 Tri (Cyclohexyl)  mothylstannyl 1, 2, 4 trinzole
  |
| 
 292.
  | 
 Furan
  | 
 634.
  | 
 Tri (Cylohexyl)  stanyl-III-1, 2, 3, -triazole
  |
| 
 293.
  | 
 Gallium Trichloride
  | 
 635.
  | 
 Triaminotrinitrobenzene
  |
| 
 294.
  | 
 Glyconitrile (Hydroxyacetonitrile) | 
 636.
  | 
 Triamphos
  |
| 
 295.
  | 
 Guanyl-4-nitrosaminoguynyl-1-tetrazene
  | 
 637.
  | 
 Triazophos
  |
| 
 296.
  | 
 Heptachlor
  | 
 638.
  | 
 Tribromophenol 2, 4, 6
  |
| 
 297.
  | 
 Hexa methyl terta-oxyacyclononate (Con. 75%)
  | 
 639.
  | 
 Trichloro napthalene
  |
| 
 298.
  | 
 Hexechlorobenzene
  | 
 640.
  | 
 Trichloro chloromethyl silane
  |
| 
 299.
  | 
 Hexachlorocyclohexan (Liudane) | 
 641.
  | 
 Trichloroacetylchloride
  |
| 
 300.
  | 
 Hexachlorocyclopenthdiene
  | 
 642.
  | 
 Trichlorodichlorophenyl silane
  |
| 
 301.
  | 
 Hexachlorodibenzo-p-dioxin
  | 
 643.
  | 
 Trichloroctbyl silane
  |
| 
 302.
  | 
 Hexachioronnapthalene
  | 
 644.
  | 
 Trichloroethylene
  |
| 
 303.
  | 
 Hexafluoropropanone sesquihydrate
  | 
 645.
  | 
 Trichloromethane sulphonyl chloride
  |
| 
 304.
  | 
 Hexamethyl phosphoromide
  | 
 646.
  | 
 Trichloronate
  |
| 
 305.
  | 
 Hexamethylene diamine N N dibutyl
  | 
 647.
  | 
 Trichlorophenol 2, 3, 6
  |
| 
 306.
  | 
 Hexane
  | 
 648.
  | 
 Trichlorophenol 2, 4, 5
  |
| 
 307.
  | 
 Hexanitrostilbene 2 2 4 4 6 6
  | 
 649.
  | 
 Trichloro Phenylsilane
  |
| 
 308.
  | 
 Hexene
  | 
 650.
  | 
 Trichlorophon
  |
| 
 309.
  | 
 Hydrogen selenide
  | 
 651.
  | 
 Trioxysilane
  |
| 
 310.
  | 
 Hydrogen sulphide
  | 
 652.
  | 
 Triethylamine
  |
| 
 311.
  | 
 Hydrazine
  | 
 653.
  | 
 Triethylene melamine
  |
| 
 312.
  | 
 Hydrazine nitrate
  | 
 654.
  | 
 Trimethyl chlorosilane
  |
| 
 313.
  | 
 Hydrochloric acid (gas) | 
 655.
  | 
 Trimothyl propane phosphite
  |
| 
 314.
  | 
 Hydrogen
  | 
 656.
  | 
 Trimethyl tin chloride
  |
| 
 315.
  | 
 Hydrogen bromide
  | 
 657.
  | 
 Trinitroanilne
  |
| 
 316.
  | 
 Hydrogen cyanide
  | 
 658.
  | 
 Trinitro benzene
  |
| 
 317.
  | 
 Hydrogen fluoride
  | 
 659.
  | 
 Trinitro benzoic acid
  |
| 
 318.
  | 
 Hydrogen peroxide
  | 
 660.
  | 
 Trinitro phenetole
  |
| 
 319.
  | 
 Hydroquinone
  | 
 661.
  | 
 Trinitro-m-cresol
  |
| 
 320.
  | 
 Indene
  | 
 662.
  | 
 Trinitrotolune
  |
| 
 321.
  | 
 Indium powder
  | 
 663.
  | 
 Triothocrecyl phosphate
  |
| 
 322.
  | 
 Indomethacin
  | 
 664.
  | 
 Triphenyl tin chloride
  |
| 
 323.
  | 
 Iodine
  | 
 665.
  | 
 Tris (2-chloroethyl) amine
  |
| 
 324.
  | 
 Iridium tetrachloride
  | 
 666.
  | 
 Turpentine
  |
| 
 325.
  | 
 Ironpentacarbonyl
  | 
 667.
  | 
 Uranium and its compounds
  |
| 
 326.
  | 
 Iso benzan
  | 
 668.
  | 
 Valino mycin
  |
| 
 327.
  | 
 Isoamyl alcohol
  | 
 669.
  | 
 Vanadiumpentaoxide
  |
| 
 328.
  | 
 Isobutylacohol
  | 
 670.
  | 
 Vinyl acetate mononer
  |
| 
 329.
  | 
 Isobutyro nitrile
  | 
 671.
  | 
 Vinyl bromide
  |
| 
 330.
  | 
 Isocyanic acid 34-dichlorophenyl ester
  | 
 672.
  | 
 Vinyl chloride
  |
| 
 331.
  | 
 Isodrin
  | 
 673.
  | 
 Vinyl cyclohexane dioxide
  |
| 
 332.
  | 
 IsofluoroPhophate
  | 
 674.
  | 
 Vinyl floride
  |
| 
 333.
  | 
 Isophrone dilisocyanate
  | 
 675.
  | 
 Vinyl norbornene
  |
| 
 334.
  | 
 Isopropyl alcohol
  | 
 676.
  | 
 Vinyl tolune
  |
| 
 335.
  | 
 Isopropyl chlorocarbonate
  | 
 677.
  | 
 Vinyledeno chloride
  |
| 
 336.
  | 
 Isopropyl formate
  | 
 678.
  | 
 Warfarin
  |
| 
 337.
  | 
 Isopropyl methyl pyrozolyl dimeihyl carbamate
  | 
 679.
  | 
 Warfarin Sodium
  |
| 
 338.
  | 
 Juglone (5-Hydroxy Napthalene-1, 4 dione)
  | 
 680.
  | 
 Xylene dichloride
  |
| 
 339.
  | 
 Kotene
  | 
 681.
  | 
 Xylidine
  |
| 
 340.
  | 
 Lactonitrile
  | 
 682.
  | 
 Zinc dichloropentnnitrile
  |
| 
 341.
  | 
 Lead arsenite
  | 
 683.
  | 
 Zinc phosphide
  |
| 
 342.
  | 
 Lead at high temp, (molten) | 
 684.
  | 
 Zirconium & compounds
  |

 II
----
 [See sub-rules (3)  and (4) of rule 7 and sub-rule (2) of rule 8]
 
 (a) The threshold quantities set-out below relate to each installations belonging to the same occupier where the distance between installations is not sufficient to avoid in foresuable circumstances, any aggrevation of major accident hazards. These threshold quantities apply in any case to each group of installations belonging to the same occupier where the distance between the installations is less than 500 metres.
 
 (b) For the purpose of determining the threshold quantity of a hazardous chemical at an isolated storage, account shall also be taken of any hazardous chemical which is-
 
 (i) in that part of any pipeline under the control of the occupier having control of the site, which is within 500 metres of that site and connected to it;
 
 (ii) at any other site under the control of the same occupier any part of the boundary of which is within 500 metres of the said site; and
 
 (iii) in any vehicle, vessel, aircraft or hovercraft the control of the same occupier which is used for storage purpose either at the site or within 500 metres of it.
 
 But no account shall be taken if any hazardous chemical which is in a vehicle, vessel, aircraft or hovercraft used for transporting it.
 
|  |  |  |
| --- | --- | --- |
| 
 Sl. No.
  | 
 Chemicals
  | 
 Threshold quantities (tonnes) |
| 
 For application of Rules 4, 5, 7 to 9 and 13 to
 
 15
  | 
 For application of Rules 10 to 12
  |
| 
 (1) | 
 (2) | 
 (3) | 
 (4) |
| 
 1
  | 
 Acrylonitrile
  | 
 350.000
  | 
 5,000.000
  |
| 
 2
  | 
 Ammonia
  | 
 60.000
  | 
 600.000
  |
| 
 3
  | 
 Ammonium nitrate (a) | 
 350.000
  | 
 2,500.000
  |
| 
 4
  | 
 Ammonium nitrate fertilizers (b) | 
 1,250.000
  | 
 10,000.000
  |
| 
 5
  | 
 Chlorine
  | 
 10.000
  | 
 25.000
  |
| 
 6
  | 
 Flammable gasses as defined in Schedule 1, Paragraph (b)  (i)
  | 
 50.000
  | 
 3,000.000
  |
| 
 7
  | 
 Extremely flammable liquids as defined in Schedule 1,
 
 Paragraph (b)  (ii)
  | 
 5,000.000
  | 
 50,000.000
  |
| 
 8
  | 
 Liquid oxygen
  | 
 2,000.000
  | 
 2,000.000
  |
| 
 9
  | 
 Sodium chlorate
  | 
 25.000
  | 
 250.000
  |
| 
 10
  | 
 Sulphur dioxide
  | 
 20.000
  | 
 500.000
  |
| 
 11
  | 
 Sulphur trioxide
  | 
 15.000
  | 
 100.000
  |
| 
 12
  | 
 Carbonyl chloride
  | 
 0.750
  | 
 0.750
  |
| 
 13
  | 
 Hydrogen sulphide
  | 
 5.000
  | 
 50.000
  |
| 
 14
  | 
 Hydrogen fluoride
  | 
 5.000
  | 
 50.000
  |
| 
 15
  | 
 Hydrogen cyanide
  | 
 5.000
  | 
 20.000
  |
| 
 16
  | 
 Carbon disulphide
  | 
 20.000
  | 
 200.000
  |
| 
 17
  | 
 Uromine
  | 
 50.000
  | 
 500.000
  |
| 
 18
  | 
 Ethylene oxide
  | 
 5.000
  | 
 501.000
  |
| 
 19
  | 
 Propylene oxide
  | 
 5.000
  | 
 50.000
  |
| 
 20
  | 
 2-Propenal (Acrolein) | 
 20.000
  | 
 200.000
  |
| 
 21
  | 
 Bromomethane (methyl bromide)
  | 
 20.000
  | 
 200.000
  |
| 
 22
  | 
 Methyl Inocyanate
  | 
 0.150
  | 
 0.150
  |
| 
 23
  | 
 Tetraethyllead or tetramethyl lead
  | 
 5.000
  | 
 50.000
  |
| 
 24
  | 
 1, 2 Dibromocthane (Ethylene dibromide)
  | 
 5.000
  | 
 25.000
  |
| 
 25
  | 
 Hydrogen chloride (liquified gas)
  | 
 50.000
  | 
 250.000
  |
| 
 26
  | 
 Diphenyl methane di-isocyanate (HDI) | 
 20.000
  | 
 200.000
  |
| 
 27
  | 
 Tolune di-sioncynate (TDI) | 
 10.000
  | 
 100.000
  |
| 
 28
  | 
 Very highly flammable liquids as defined in Schedule of
 
 paragraph (b)  (iii)
  | 
 7,000.000
  | 
 7,000.000
  |
| 
 29
  | 
 Highly flammable liquids as defined in Schedule I, paragraph
 
 (b)  (ii)
  | 
 10,000.000
  | 
 10,000.000
  |
| 
 30
  | 
 Flammable liquids as defined in Schedule I, paragraph (b)  (V)
  | 
 15,000.000
  | 
 1,00.000.000
  |
 Foot notes-
 
 (a) This applies to ammonium nitrate and mixture of ammonium nitrate where the nitrogen content derived from the ammonium nitrate is greater than 20 per cent by weight and to aqueous solutions of ammonium nitrate where the concentration of ammonium nitrate is greater than 90 per cent by weight.
 
 (b) This applies to straight ammonium nitrate fertilizer and to compound fertilizers where the nitrogen content derived from the ammonium nitrate is greater than 28 per cent by weight (A compound-fertilizer contains ammonium nitrate together with phosphata and/or potash).
 
 III
-----
 [See sub-rule (1)  of Rule 7 and sub-rule (2) of Rule 8]
 
 (a) The quantities set-out below relate to each installation of group of installations belonging to the same occupier where the distance between the installation is not sufficient to avoid, in forceable circumstances, any aggravation of major accident hazards. These quantities apply in any case to each group of installations belonging to the same occupier where the distance between the installations is less than 500 metres.
 
 (b) For the purpose of determining the threshold quantity of hazardous chemical in an industrial installation, account shall also be taken of any. hazardous chemicals which is-
 
 (i) in that part of any pipe line under the control of the occupier having control of the site which is within 500 metres of that site and connected to it;
 
 (ii) at any other site under the control of the same occupier any part of the boundary of which is within 500 metres of the said site; and
 
 (iii) in any vehicle, vessel, aircraft or hovercraft under the control of the same occupier which is used for storage purpose either at the site or within 500 meters of its.
 
 But no account shall be taken of any hazardous chemical which is in a vehicle, vessel, aircraft or hovercraft used for transporting it.
 
 III
-----
 Part 1 – Named Chemicals
--------------------------
|  |  |  |  |
| --- | --- | --- | --- |
| 
 Sl. No.
  | 
 Chemical
  | 
 Threshold Quantity
  | 
 CAS Number
  |
| 
 For application of Rules 5, 7, 8 and 13 and 15
  | 
 For application of Rules 10 to 12
  |
| 
 (1) | 
 (2) | 
 (3) | 
 (4) | 
 (5) |
| 
 | 
 GROUP 1 TOXIC CHEMICALS
  | 
 | 
 | 
 |
| 
 1
  | 
 Adicarb
  | 
 100 Kg.
  | 
 ...
  | 
 116-06-3
  |
| 
 2
  | 
 4-Aminodiphenyl
  | 
 1 Kg.
  | 
 ...
  | 
 96-67-1
  |
| 
 3
  | 
 Amiton
  | 
 1 Kg.
  | 
 ...
  | 
 78-53-5
  |
| 
 4
  | 
 Anabasine
  | 
 100 Kg.
  | 
 ...
  | 
 494-52-0
  |
| 
 5
  | 
 Ardanic pentoxide, Arsenic (V)  acid & salts
  | 
 500 Kg
  | 
 ...
  | 
 ...
  |
| 
 6
  | 
 Arsenic trioxide, Arsenious (III)  acid & salts.
  | 
 100 Kg
  | 
 ...
  | 
 ...
  |
| 
 7
  | 
 Arsine (Aresnic hydride)
  | 
 10 Kg.
  | 
 ...
  | 
 7784-42-1
  |
| 
 8
  | 
 Azinphos-ethyl
  | 
 100 Kg.
  | 
 ...
  | 
 2642-71-9
  |
| 
 9
  | 
 Azinphos-methyl
  | 
 100 Kg.
  | 
 ...
  | 
 86-50-0
  |
| 
 10
  | 
 Benzidine
  | 
 1 Kg.
  | 
 ...
  | 
 92-87-5
  |
| 
 11
  | 
 Benzidine salts
  | 
 1 Kg.
  | 
 ...
  | 
 92-87-5
  |
| 
 12
  | 
 Beryllium (powders compounds)
  | 
 10 Kg.
  | 
 ...
  | 
 ...
  |
| 
 13
  | 
 Bis (2-chloroethyl) sulphide
  | 
 1 Kg.
  | 
 ...
  | 
 505-60-2
  |
| 
 14
  | 
 Bis (Chloromethyl) ether
  | 
 1 Kg.
  | 
 ...
  | 
 542-88-1
  |
| 
 15
  | 
 Carbofuran
  | 
 100 Kg.
  | 
 ...
  | 
 1563-66-2
  |
| 
 16
  | 
 Carbophenothion
  | 
 100 Kg.
  | 
 ...
  | 
 786-19-6
  |
| 
 17
  | 
 Chlorfenvinphos
  | 
 100 Kg.
  | 
 ...
  | 
 470-90-6
  |
| 
 18
  | 
 4-(Chloroformyl)  morpholine
  | 
 1 Kg.
  | 
 ...
  | 
 15159-40-7
  |
| 
 19
  | 
 Chloromethyl methyl ether
  | 
 1 Kg.
  | 
 ...
  | 
 107-30-2
  |
| 
 20
  | 
 Crbalt (Metal, oxides, carbonates, sulphides as powders).
  | 
 1 t.
  | 
 ...
  | 
 ...
  |
| 
 21
  | 
 Crimidine
  | 
 100 Kg.
  | 
 ...
  | 
 535-89-7
  |
| 
 22
  | 
 Cyanthoste
  | 
 100 Kg.
  | 
 ...
  | 
 3734-95-0
  |
| 
 23
  | 
 Cycloheximide
  | 
 100 Kg.
  | 
 ...
  | 
 66-81-9
  |
| 
 24
  | 
 Demeton
  | 
 100 Kg.
  | 
 ...
  | 
 8065-48-3
  |
| 
 25
  | 
 Dialifos
  | 
 100 Kg.
  | 
 ...
  | 
 10311-84-9
  |
| 
 26
  | 
 00-Diethyl Sethylsulphinyl methyl phosphorothioate.
  | 
 100 Kg.
  | 
 ...
  | 
 60-81-9
  |
| 
 27
  | 
 00-Diethyl S-ethylsulphonyl methyl phosphosphorothioate.
  | 
 100 Kg.
  | 
 ...
  | 
 2588-05-8
  |
| 
 28
  | 
 00-Diethyl S-isopropylthio methyl phosphorodithioate.
  | 
 100 Kg.
  | 
 ...
  | 
 2600-69-3
  |
| 
 29
  | 
 00-Diethyl S-isopropylthio methyl phosphorodithioate
  | 
 100 Kg.
  | 
 ...
  | 
 78-52-4
  |
| 
 30
  | 
 00-Diethyl S-propylthiomethyl phosphorodithioate.
  | 
 100 Kg.
  | 
 ...
  | 
 3309-68-0
  |
| 
 31
  | 
 Dimefox
  | 
 100 Kg.
  | 
 ...
  | 
 115-26-4
  |
| 
 32
  | 
 Dimethylcarbamoyl chloride
  | 
 1 Kg.
  | 
 ...
  | 
 79-44-7
  |
| 
 33
  | 
 Dimethylnitrosamine
  | 
 1 Kg.
  | 
 ...
  | 
 62-75-9
  |
| 
 34
  | 
 Dimethyl phosphoramido cyanidic acid
  | 
 1 t.
  | 
 ...
  | 
 63917-41-9
  |
| 
 35
  | 
 Diphacinone
  | 
 100 Kg.
  | 
 ...
  | 
 82-66-6
  |
| 
 36
  | 
 Disulfoton
  | 
 100 Kg.
  | 
 ...
  | 
 298-04-4
  |
| 
 37
  | 
 EPN
  | 
 100 Kg.
  | 
 ...
  | 
 2104-64-5
  |
| 
 38
  | 
 Ethion
  | 
 100 Kg.
  | 
 ...
  | 
 563-12-2
  |
| 
 39
  | 
 Fensulfothion
  | 
 100 Kg.
  | 
 ...
  | 
 115-90-2
  |
| 
 40
  | 
 Fluenetil
  | 
 100 Kg.
  | 
 ...
  | 
 4301-50-2
  |
| 
 41
  | 
 Fluoroacetic acid
  | 
 1 Kg.
  | 
 ...
  | 
 144-49-0
  |
| 
 42
  | 
 Flouroacetic acid, salts
  | 
 1 Kg.
  | 
 ...
  | 
 ...
  |
| 
 43
  | 
 Fluoroacetic acid, esters
  | 
 1 Kg.
  | 
 ...
  | 
 ...
  |
| 
 44
  | 
 Fluoroacetic acid, amides
  | 
 1 Kg.
  | 
 ...
  | 
 ...
  |
| 
 45
  | 
 4-Fluorobutyric acid
  | 
 1 Kg.
  | 
 ...
  | 
 462-23-7
  |
| 
 46
  | 
 4-Fluorobutyric acid, salts
  | 
 1 Kg.
  | 
 ...
  | 
 ...
  |
| 
 47
  | 
 4-Fluorobutyric acid, esters
  | 
 1 Kg.
  | 
 ...
  | 
 ...
  |
| 
 48
  | 
 4-Fluorobutyric acid, amides.
  | 
 1 Kg.
  | 
 ...
  | 
 ...
  |
| 
 49
  | 
 4-Fluorocrotonic acid
  | 
 1 Kg.
  | 
 ...
  | 
 37759-72-1
  |
| 
 50
  | 
 4-Fluorocrotonic acid, salts
  | 
 1 Kg.
  | 
 ...
  | 
 ...
  |
| 
 51
  | 
 4-Flurocrotonic acid, esters
  | 
 1 Kg.
  | 
 ...
  | 
 ...
  |
| 
 52
  | 
 4-Flurocrotonic acid, amides
  | 
 1 Kg.
  | 
 ...
  | 
 ...
  |
| 
 53
  | 
 4-Fluoro-2-hydroxybutyric acid
  | 
 1 Kg.
  | 
 ...
  | 
 ...
  |
| 
 54
  | 
 4-Fluoro-2-hydroxybutyric acid, salts
  | 
 1 Kg.
  | 
 ...
  | 
 ...
  |
| 
 55
  | 
 4-Fluoro-2 hydroxybutryic acid, esters
  | 
 1 Kg
  | 
 ...
  | 
 ...
  |
| 
 56
  | 
 4-Fluoro-hydroxybutyric acid, amides
  | 
 1 Kg.
  | 
 ...
  | 
 ...
  |
| 
 57
  | 
 Glycolonitrile (hydroxyacetonitrilo) | 
 100 Kg
  | 
 ...
  | 
 107-16-4
  |
| 
 58
  | 
 1, 2, 3, 7, 8, 9 -Hexachlorodibenzo-P-dixin.
  | 
 100 Kg
  | 
 ...
  | 
 19408-74-3
  |
| 
 59
  | 
 Hexamethylphosphoramide
  | 
 1 Kg
  | 
 ...
  | 
 680-31-9
  |
| 
 60
  | 
 Hydrogen selenide
  | 
 10 Kg.
  | 
 ...
  | 
 7783-07-5
  |
| 
 61
  | 
 Isobenzan
  | 
 100 Kg.
  | 
 ...
  | 
 297-78-9
  |
| 
 62
  | 
 Isodrin
  | 
 100 Kg.
  | 
 ...
  | 
 465-73-6
  |
| 
 63
  | 
 Juglone (5-Hydroxynaph-thelene 1, 4 -dione)
  | 
 100 Kg.
  | 
 ...
  | 
 181-39-0
  |
| 
 64
  | 
 4, Methylenebis (2-chloroaniline)
  | 
 10 Kg.
  | 
 ...
  | 
 101-14-4
  |
| 
 65
  | 
 Methyliscyanate
  | 
 150 Kg.
  | 
 150 Kg.
  | 
 624-83-9
  |
| 
 66
  | 
 Mevinphos
  | 
 100 Kg.
  | 
 ...
  | 
 7786-34-7
  |
| 
 67
  | 
 2-Naphthylamine
  | 
 1 Kg
  | 
 ...
  | 
 91-59-8
  |
| 
 68
  | 
 Nickel (Metal, oxides, carbonatos sulphide, as powders)
  | 
 1 t
  | 
 ...
  | 
 ...
  |
| 
 69
  | 
 Nickel tetracarbonyl
  | 
 10 Kg.
  | 
 ...
  | 
 13463-9-3
  |
| 
 70
  | 
 Oxydisulfoton
  | 
 100 Kg.
  | 
 ...
  | 
 2497-07-6
  |
| 
 71
  | 
 Oxygenfifluoride
  | 
 10 Kgs
  | 
 ...
  | 
 7783-41-7
  |
| 
 72
  | 
 Paraxon (Diethyl 4 nitrophenylphosphate)
  | 
 100 Kg
  | 
 ...
  | 
 311-45-5
  |
| 
 73
  | 
 Parathion
  | 
 100 Kg.
  | 
 ...
  | 
 56-38-2
  |
| 
 74
  | 
 Parathion-methyl
  | 
 100 Kg.
  | 
 ...
  | 
 298-00-0
  |
| 
 75
  | 
 Pentaborane
  | 
 100 Kg.
  | 
 ...
  | 
 19624-22-7
  |
| 
 76
  | 
 Phoroto
  | 
 100 Kg.
  | 
 ...
  | 
 298-02-2
  |
| 
 77
  | 
 Phosacetim
  | 
 100 Kg.
  | 
 ...
  | 
 4104-14-7
  |
| 
 78
  | 
 Phosgene (carbonyl chloride)
  | 
 750 Kg.
  | 
 ...
  | 
 75-44-5
  |
| 
 79
  | 
 Phosphamiden
  | 
 100 Kg.
  | 
 ...
  | 
 13171-21-6
  |
| 
 80
  | 
 Phosphine (Hydrogenphosphide) | 
 100 Kg.
  | 
 ...
  | 
 7803-51-2
  |
| 
 81
  | 
 Promurit [1-(3, 4-Dicheoropheny)-3
 
 -trinazenethiocarb-oxamide]
  | 
 100 Kg.
  | 
 ...
  | 
 5836-73-7
  |
| 
 82
  | 
 1, 3-Propanesultone
  | 
 1 Kg.
  | 
 ...
  | 
 1120-71-4
  |
| 
 83
  | 
 1-Propen-2-chloro-1, 3-diol diacetate
  | 
 10 Kg.
  | 
 ...
  | 
 10118-72-6
  |
| 
 84
  | 
 Pyrazoxon
  | 
 100 Kg.
  | 
 100 Kg.
  | 
 108-34-9
  |
| 
 85
  | 
 Selenium hexafluoride
  | 
 10 Kg.
  | 
 ...
  | 
 7783-79-1
  |
| 
 86
  | 
 Sodium scienite
  | 
 100 Kg.
  | 
 ...
  | 
 10102-18-8
  |
| 
 87
  | 
 Stibine (Antimony hydride)
  | 
 100 Kg.
  | 
 ...
  | 
 7303-52-3
  |
| 
 88
  | 
 Sulfotep
  | 
 100 Kg.
  | 
 ...
  | 
 3689-24-5
  |
| 
 89
  | 
 Sulphr dichloride
  | 
 1t.
  | 
 ...
  | 
 10545-99-0
  |
| 
 90
  | 
 Tellurium hexafluoride
  | 
 100 Kg.
  | 
 ...
  | 
 7783-80-4
  |
| 
 91
  | 
 TEPP
  | 
 100 Kg.
  | 
 ...
  | 
 107-49-3
  |
| 
 92
  | 
 2, 3, 7, 8,-Teterachlorodi-benjo-P-dioxin (TCDD) | 
 1 Kg.
  | 
 ...
  | 
 1746-01-6
  |
| 
 93
  | 
 Tetramethylendisulpho-tetramine
  | 
 1 Kg.
  | 
 ...
  | 
 80-12-6
  |
| 
 94
  | 
 Thionazin
  | 
 100 Kg.
  | 
 ...
  | 
 197-97-2
  |
| 
 95
  | 
 Tirpate (2, 4-Dimethel-1, 3-dithiolane-2 carboxaldehyde
 
 O-methylcarbamoyloxime)
  | 
 100 Kg.
  | 
 ...
  | 
 24419-73-8
  |
| 
 96
  | 
 Trichioromethanesulphenyl chloride
  | 
 100 Kg.
  | 
 ...
  | 
 594-42-3
  |
| 
 97
  | 
 1-Tri (cyclohexyl)  stannyl-1H-1, 2, 4,-triazole
  | 
 100 Kg
  | 
 ...
  | 
 41083-11-8
  |
| 
 98
  | 
 Tricthylenemelamine
  | 
 10 Kg.
  | 
 ...
  | 
 51-18-3
  |
| 
 99
  | 
 Warfarin
  | 
 100 Kg
  | 
 ...
  | 
 81-81-2
  |
| 
 | 
 GROUP 2-TOXIC SUBSTANCES
  | 
 | 
 ...
  | 
 |
| 
 100
  | 
 Acetone cyanohydrin (2- Cyanopropan-2-01)
  | 
 200 t.
  | 
 ...
  | 
 75-86-5
  |
| 
 101
  | 
 Acrolein (2-Propenal)
  | 
 20 t.
  | 
 ...
  | 
 107-02-8
  |
| 
 102
  | 
 Acrylonitrile
  | 
 20 t.
  | 
 200 t.
  | 
 107-13-1
  |
| 
 103
  | 
 Allylalochal (Propen-1-01)
  | 
 200 t
  | 
 ...
  | 
 107-18-6
  |
| 
 104
  | 
 Allylamine
  | 
 200 t
  | 
 ...
  | 
 107-11-9
  |
| 
 105
  | 
 Ammonia
  | 
 50 t.
  | 
 500 t.
  | 
 7665-41-7
  |
| 
 106
  | 
 Bromine
  | 
 40 t.
  | 
 ...
  | 
 7726-95-6
  |
| 
 107
  | 
 Carbon disulphide
  | 
 20 t.
  | 
 200 t.
  | 
 75-15-0
  |
| 
 108
  | 
 Chlorine
  | 
 10 t.
  | 
 25 t.
  | 
 7782-50-5
  |
| 
 109
  | 
 Diphenyl methane di-socynate (MDI) | 
 20 t
  | 
 ...
  | 
 101-68-8
  |
| 
 110
  | 
 Ethylene diteromide (1, 2-Dibronloethane)
  | 
 5 t.
  | 
 ...
  | 
 106-93-4
  |
| 
 111
  | 
 Ethyieneeimine
  | 
 50 t.
  | 
 ...
  | 
 151-56-4
  |
| 
 112
  | 
 Formaldehyde (concentration -90%)
  | 
 5 t.
  | 
 ...
  | 
 50-00-C
  |
| 
 113
  | 
 Hydrogen chloride (liqufied gas)
  | 
 25 t.
  | 
 250 t.
  | 
 7647-01-0
  |
| 
 114
  | 
 Hydrogen Cyanide
  | 
 5 t.
  | 
 20 t.
  | 
 74-90-8
  |
| 
 115
  | 
 Hydrogen fluoride
  | 
 5 t.
  | 
 50 t.
  | 
 7664-39-3
  |
| 
 116
  | 
 Hydrogen sulphide
  | 
 5 t.
  | 
 50 t.
  | 
 7783-06-4
  |
| 
 117
  | 
 Methyl bromide (Bromomethane) | 
 20 t.
  | 
 ...
  | 
 74-83-9
  |
| 
 118
  | 
 Nitrogen oxides
  | 
 50 t.
  | 
 ...
  | 
 11104-93-1
  |
| 
 119
  | 
 Propyleneimine
  | 
 50 t.
  | 
 ...
  | 
 75-55-8
  |
| 
 120
  | 
 Suipher dioxide
  | 
 20 t.
  | 
 250 t.
  | 
 7446-09-5
  |
| 
 121
  | 
 Sulphur trioxide
  | 
 15 t.
  | 
 75 t.
  | 
 7446-11-9
  |
| 
 122
  | 
 Tetraethyl lead
  | 
 5 t.
  | 
 ...
  | 
 78-00-2
  |
| 
 123
  | 
 Tetramethyl lead
  | 
 5 t.
  | 
 ...
  | 
 75-74-1
  |
| 
 124
  | 
 Tolune di-isocyanate (TDI) | 
 10 t.
  | 
 ...
  | 
 584-84-9
  |
| 
 | 
 GROUP 3-HIGHLY REACTIVE SUBSTANCES
  | 
 | 
 | 
 |
| 
 125
  | 
 Acetylene (ethyne) | 
 5 t.
  | 
 ...
  | 
 74-86-2
  |
| 
 126
  | 
 a. Ammonoium nitrate (1) | 
 350 t.
  | 
 2500 t.
  | 
 6484-52-2
  |
| 
 | 
 b. Ammonium nitrate in form of fertiliser (2) | 
 1250 t
  | 
 ...
  | 
 ...
  |
| 
 127
  | 
 2,2-Bis (tert-butylperoxy) butane (concentration=70%)
  | 
 5 t.
  | 
 ...
  | 
 2167-23-9
  |
| 
 128
  | 
 1,1-Bis (tert-butylperoxy) cyclohexane (concentration=80%)
  | 
 5 t.
  | 
 ...
  | 
 3006-86-8
  |
| 
 129
  | 
 tert-Butylperoxyacetate (concentration=70%)
  | 
 5 t.
  | 
 ...
  | 
 107-71-1
  |
| 
 130
  | 
 tert-Butyl peroxyisobutyrate (concentration=80%)
  | 
 5 t.
  | 
 ...
  | 
 109-13-7
  |
| 
 131
  | 
 tert-Butyl peroxy is isopropyl carbonate (concentration =
 
 80%)
  | 
 5t.
  | 
 ...
  | 
 2372-21-6
  |
| 
 132
  | 
 tert-Butyl peroxymaleate (concentratidn=80%)
  | 
 5 t.
  | 
 ...
  | 
 1931-2-0
  |
| 
 133
  | 
 tert-Butyl peroxynivalate (concentration=77%)
  | 
 50 t.
  | 
 ...
  | 
 927-07-1
  |
| 
 134
  | 
 Dibenzyl peroxydicarbonate (concentration=90%)
  | 
 5 t.
  | 
 ...
  | 
 2144-45-8
  |
| 
 135
  | 
 Di-scc-butyl peroxydicarbonate (concentration=80%)
  | 
 5 t.
  | 
 ...
  | 
 19910-5-0
  |
| 
 136
  | 
 Diethyl peroxydicarbonate (concentration=30%)
  | 
 50 t.
  | 
 ...
  | 
 14666-78-5
  |
| 
 137
  | 
 2,2-Dihydroperoxypropane (concentration=30%)
  | 
 5 t.
  | 
 ...
  | 
 2614-76-8
  |
| 
 138
  | 
 Di-isobutyryl peroxide (concentration=50%)
  | 
 50 t.
  | 
 ...
  | 
 3437-84-1
  |
| 
 139
  | 
 Din-propyl peroxydicarbonate (concentration =80%)
  | 
 5 t.
  | 
 ...
  | 
 16066-39-9
  |
| 
 140
  | 
 Ethylene oxide
  | 
 5 t.
  | 
 50 t.
  | 
 75-21-8 0
  |
| 
 141
  | 
 Ethyl nitrate
  | 
 50 t.
  | 
 ...
  | 
 625-58-1
  |
| 
 142
  | 
 3, 3, 6, 6, 9, 9-Hexarnethyl-1 tetroxacy-clononenence 2, 4,
 
 5, (concentration-75%).
  | 
 50 t.
  | 
 ...
  | 
 22397-33-7
  |
| 
 143
  | 
 Hydrogen
  | 
 2 t.
  | 
 50 t.
  | 
 1333-74-0
  |
| 
 144
  | 
 Liquid oxygen
  | 
 200 t.
  | 
 ...
  | 
 7782-44-7
  |
| 
 145
  | 
 Methyl ethyl ketone peroxide (concentration- 60%)
  | 
 5 t.
  | 
 ...
  | 
 1338-23-4
  |
| 
 146
  | 
 Methyl isobuty ketone peroxide (concentration -60%).
  | 
 50 t.
  | 
 ...
  | 
 37206-20-5
  |
| 
 147
  | 
 Peracetic acid (concentration-60%)
  | 
 50 t.
  | 
 ...
  | 
 79-21-0
  |
| 
 148
  | 
 Propylene oxide
  | 
 5 t.
  | 
 ...
  | 
 75-56-9
  |
| 
 149
  | 
 Sodium chlorate
  | 
 25 t.
  | 
 ...
  | 
 7775-09-9
  |
| 
 | 
 GROUP 4-EXPLOSIVE SUBSTANCES
  | 
 | 
 ...
  | 
 |
| 
 150
  | 
 Barium azide
  | 
 50 t.
  | 
 ...
  | 
 18810-58-7
  |
| 
 151
  | 
 Bis (2,4,6-trinitropheny) amine
  | 
 50 t.
  | 
 ...
  | 
 131-73-7
  |
| 
 152
  | 
 Chlorotrinitrobenzene
  | 
 50 t.
  | 
 50 t.
  | 
 28260-61-9
  |
| 
 153
  | 
 Cellulote nitrate containing (12%6 Nitrogen)
  | 
 50 t.
  | 
 ...
  | 
 9004-70-0
  |
| 
 154
  | 
 Cycloterramethylenctcrani-tramine
  | 
 50 t.
  | 
 ...
  | 
 2691-51-0
  |
| 
 155
  | 
 Cyclotrimethylenctrini-tramine
  | 
 50 t.
  | 
 ...
  | 
 121-82-4
  |
| 
 156
  | 
 Diazodinitrophenol
  | 
 10 t.
  | 
 ...
  | 
 7008-81-3
  |
| 
 157
  | 
 Diethylene glycol dinitrate
  | 
 10 t.
  | 
 ...
  | 
 693-21-0
  |
| 
 158
  | 
 Dinitrophenol, salts
  | 
 50 t.
  | 
 ...
  | 
 |
| 
 159
  | 
 Ethylene glycol dinitrate
  | 
 10 t.
  | 
 ...
  | 
 628-96-6
  |
| 
 160
  | 
 1-Guanyl-4-nitorsa minoguannyl-1-tetrazene.
  | 
 10 t.
  | 
 ...
  | 
 109-27-3
  |
| 
 161
  | 
 '2','2','4,'4','6,6' -Hexanitrostibene
  | 
 50 t.
  | 
 ...
  | 
 20062-22-0
  |
| 
 162
  | 
 Hydrazine nitrate
  | 
 50 t.
  | 
 ...
  | 
 13464-97-6
  |
| 
 163
  | 
 Lead oxide
  | 
 50 t.
  | 
 ...
  | 
 13424-46-9
  |
| 
 164
  | 
 Lead styphnate (Lead 2, 4, 6-trinitroresor-einoxide).
  | 
 50 t.
  | 
 ...
  | 
 15245-44-0
  |
| 
 165
  | 
 Mercury fulminate
  | 
 10 t.
  | 
 ...
  | 
 20820-45-5-628-86-4
  |
| 
 166
  | 
 N-Methyl-N, 2,4,6-tetranitroaniline
  | 
 50 t.
  | 
 ...
  | 
 479-45-8
  |
| 
 167
  | 
 Nitroglycerine
  | 
 10 t.
  | 
 10 t.
  | 
 55-63-0
  |
| 
 168
  | 
 Pentacrythritol tetranitrate
  | 
 50 t.
  | 
 ...
  | 
 78-11-5
  |
| 
 169
  | 
 Priorio acid (2,4,6-Trinitrophenol
  | 
 50 t.
  | 
 ...
  | 
 88-89-1
  |
| 
 170
  | 
 Sodium pleramate
  | 
 50 t.
  | 
 ...
  | 
 831-52-7
  |
| 
 171
  | 
 Styphnic acid (2, 4, 6-Trinitroresorcinol)
  | 
 50 t.
  | 
 ...
  | 
 82-71-2
  |
| 
 172
  | 
 1,3,5, - Triamine-2,4,6,-trinitrobenzen
  | 
 50 t.
  | 
 ...
  | 
 3058-38-6
  |
| 
 173
  | 
 Trinitroaniline
  | 
 50 t.
  | 
 ...
  | 
 26952-42-1
  |
| 
 174
  | 
 2,4,6,-Trinitroanisole
  | 
 50 t.
  | 
 ...
  | 
 606-35-9
  |
| 
 175
  | 
 Trinitrobenzene
  | 
 50 t.
  | 
 ...
  | 
 25377-32-6
  |
| 
 176
  | 
 Trinitrobenzoic acid
  | 
 50 t.
  | 
 ...
  | 
 35860-50-5
  |
| 
 177
  | 
 Trinitroceresol
  | 
 50 t.
  | 
 ...
  | 
 28905-71-7
  |
| 
 178
  | 
 2, 4, 6,-Trinitrophenetole
  | 
 50 t.
  | 
 ...
  | 
 4732-14-3
  |
| 
 179
  | 
 2, 4, 6,-Trinitrophenetole
  | 
 50 t.
  | 
 50 t.
  | 
 118-96-7
  |
 Part II – Classes of substances as defined in Part I, Schedule I and not specifically named in Part I this Schedule (tonne) .
------------------------------------------------------------------------------------------------------------------------------
|  |  |  |  |
| --- | --- | --- | --- |
| 
 Sl. No.
  | 
 Chemical
  | 
 Threshold Quantity (tonnes) | 
 CAS Number
  |
| 
 For application of Rules 5, 7, 8, 13 and 15
  | 
 For application of Rules 10 to 12
  |
| 
 (1) | 
 (2) | 
 (3) | 
 (4) | 
 (5) |
| 
 1
  | 
 Flammable gases
  | 
 15 T.
  | 
 200 T
  | 
 |
| 
 2
  | 
 Extremely flammable liquids
  | 
 1000 T.
  | 
 5000 T
  | 
 |
| 
 3
  | 
 Very highly flammable liquids
  | 
 1500 T.
  | 
 10,000 T
  | 
 |
| 
 4
  | 
 Highly flammable liquids remains liquid under pressure.
  | 
 25 T.
  | 
 200 T
  | 
 |
| 
 5
  | 
 Highly flammable liquids
  | 
 2300 T.
  | 
 20,000 T
  | 
 |
| 
 6
  | 
 Flammable liquids
  | 
 5000 T.
  | 
 50,000 T
  | 
 |
| 
 As Number (Chemical Abstracts Service Number) means the
 
 number assigned to the Chemical by the Chemical Abstract
 
 Service.
  |

 IV
----
 [See clause (c)  of sub-rule (1) of Rule 2]
 
### 1. Factories involving in production, processing or treatment of organic or inorganic chemicals using for this purpose, among others : (a) alkylation .
 
 (b) amination by amonolysis
 
 (c) carbonylation
 
 (d) condensation
 
 (e) dehydrogenation
 
 (f) estefication
 
 (g) halogenation and manufacture of halogens
 
 (h) hydrolyis
 
 (i) oxidation
 
 (j) polymerization
 
 (k) sulphonation
 
 (l) desulphurization, manufacture and transformation of sulphur containing compounds
 
 (m) nitration and manufacture of nitrogen containing compounds
 
 (n) manufacture of phosphorous containing compounds
 
 (o) formulation of pesticides and of pharmaceutical products
 
 (p) distillation
 
 (q) extraction
 
 (r) solvation
 
 (s) mixing
 
### 2. Factories involving in distillation refining or other processing petroleum or petroleum products. ###
 3. Factories involving in total or partial disposal of solid or liquid chemicals by incineration or chemical decomposition.
### 4. Factories involving in productibn processing or treatment of energy gases, for example, L.P.G. L.H.G., S.H.Q. ###
 5. Factories involving in dry distillation of coal or lignite.
### 6. Factories involving in production of metals or non-metals by a wet process or by means of electric energy. V
---
 (See Rule 4)
 
 Format of a Safety Data Sheet)
 
### 1. IDENTITY OF MATERIAL |  |  |
| --- | --- |
| 
 Product Name
  | 
 Chemical Designation
  |
| 
 Trade Name
  | 
 | 
 | 
 Synonymus
  |
| 
 Formula
  | 
 Label Category class
  | 
 CAS Number
  | 
 UN Number
  |
| 
 Regulated identification
  | 
 Shipping Name Codes/Label
  | 
 | 
 HAZCHEM Code
  |
| 
 | 
 Hazardous waste
  | 
 | 
 |
| 
 | 
 Identification Number
  | 
 | 
 |
| 
 Hazardous Ingredients
  | 
 CAS Number
  |
| 
 1.
 
 ….............................................................................................................................................................
  |
| 
 2.
 
 ….............................................................................................................................................................
  |
| 
 3.
 
 ….............................................................................................................................................................
  |
| 
 4.
 
 ….............................................................................................................................................................
  |
### 2. PHYSICAL AND CHEMICAL PROPERTIES |  |  |  |
| --- | --- | --- |
| 
 Physical state : (Gas, Liquid, Solid)
  | 
 Poling point in degree C
  | 
 Vapour pressure at 35 degree C mm Hg.
  |
| 
 Appearance
  | 
 Melting/Freezing point in degree C
  | 
 Evaporation rate 30° C
  |
| 
 Odour
  | 
 Vapour Density (air-1)
  | 
 Solubility in water at 30 degree C
  |
| 
 Others
  | 
 Specific Gravity
  | 
 PH.
  |
| 
 (Corrosivity, etc.)
  | 
 Water-1
  | 
 |
### 3. FIRE AND EXPLOSIVE HAZARDS DATA |  |  |  |  |
| --- | --- | --- | --- |
| 
 Explosion/flammability
  | 
 Flash point (deg.C)
  | 
 LEL
  | 
 Autoignition Temperature degree C
  |
| 
 | 
 Flash point deg. C.
  | 
 UEL
  | 
 TDG Flammability (Classification) |
### 4. REACTIVE HAZARDS |  |  |  |
| --- | --- | --- |
| 
 Stability to
  | 
 Import
 
 Static Discharge
 
 Reactivity
  | 
 (Hazardous Composition Products)
 
 (Hazardous Decomposition Products)
 
 (Conditions to avoid).
  |
| 
 Hazardous Polymerisation
  | 
 May/may not occur
  | 
 (Conditions to avoid)
  |
| 
 Incompatibility
  | 
 (Materials to avoid)
  | 
 |
### 5. HEALTH HAZARD DATA |  |
| --- |
| 
 Routes of Entry : (Inhalation, skin, mucuous membranes and
 
 eye contact and ingestion)
  |
| 
 Effects of Exposure/Symptoms :
  |
| 
 L.D. 50 (in rat) absorption
  | 
 (Orally or percutaneous (mg/kg body weight)
  | 
 L.C.50 (in rat) (mg/1) 4 hours
  |
| 
 Permissible Exposure Limit (PEL)  Threshold
  | 
 ppm
  | 
 mg/cu.m
  | 
 Short term Exposure Limit (STEL) | 
 ppm
  | 
 mg/cu.m
  |
| 
 Value (TLV)  Limit of ACGIH
  | 
 ppm
  | 
 mg/cu.m
  | 
 Odour Threshold
  | 
 ppm
  | 
 mg/cu.m
  |
| 
 Emergency Treatment :
  | 
 | 
 | 
 | 
 | 
 |
### 6. HAZARDS SPECIFICATION |  |  |  |  |  |
| --- | --- | --- | --- | --- |
| 
 NFPA Hazard signal
  | 
 Health
  | 
 Flammability
  | 
 Stability
  | 
 Special
  |
| 
 Known Hazards
  | 
 | 
 |
| 
 Combustible Liquid
  | 
 Auter Reactive Material
  | 
 Irritant
  |
| 
 Flammable Material
  | 
 Oxidiser
  | 
 Sensitizer
  |
| 
 Pyrophoric material
  | 
 Organic Peroxide
  | 
 Carcinogen
  |
| 
 Explosive Material
  | 
 Corrosive material
  | 
 Mutagen
  |
| 
 Unstable material
  | 
 Compressed Gas
  | 
 Others (specify) |
### 7. SAFE USAGE DATA |  |  |
| --- | --- |
| 
 Ventilation
  | 
 General/Mechanical Local Exhaust
  |
| 
 Protective Equipment Required
  | 
 Eyes (specify) Respiratory (specify)
 
 Gloves (specify) Clothing (specify)
 
 Others (specify) |
| 
 Precautions
  | 
 Handling & Storage Others (specify) |
### 8. EMERGENCY RESPONSE DATA |  |  |
| --- | --- |
| 
 Fire
  | 
 Fire Existing Media
 
 Special Procedure
 
 Unusual Hazards
  |
| 
 Exposure (inhalation,skin First
 
 Aid Measures and eye contact, ingection)
  |
| 
 Spills
  | 
 Steps to be taken Waste Disposal Method
  |
### 9. ADDITIONAL INFORMATION ###
 10. SOURCES USED
|  |
| --- |
| 
 Reference to books, journals, etc.
  |
### 11. Manufacturer/Supplier Data |  |  |
| --- | --- |
| 
 Firms name
  | 
 Standard Packing
  |
| 
 Mailing Address
  | 
 |
| 
 Telephone Number
  | 
 |
| 
 Telex Number
  | 
 Other
  |
| 
 Telegraphic Address
  | 
 Other
  |
| 
 Contact person in emergency
  | 
 Emergency Tel. in Transit Areas
  |
| 
 Acronyms and Glossary of Terms :
  |
| 
 GAS-Chemical Abstract Service Registration Number
  |
| 
 UN Number-United Nations Number
  |
| 
 | 
 Emergency Action Code (EAC) , allocated by the joint committee
 
 of Brigade Operations, UK.
  |
| 
 TDC Flammability-Transport of
 
 Dangerous Goods-Flammability classification by United Nations.
 
 NFPA-National Fire Protection
 
 Association, USA LD 50 AND LC 50 represent the does in rhg/Kg.
 
 of body weight and the concentration in mg/1 for 4 hours having
 
 lethal effect on 50% of the animals (rats)  treated.
 
 PEL-Permissible Exposure Limit as
 
 laid down in the statutes
 
 TLV-Threshold Limit Value as laid
 
 down by he American Conference of Governmental Industrial
 
 Hygienists, (ACG III), USA.
 
 STEL-Short-Term Exposure Limit as
 
 laid down in the statutes or by the ACG III GUIDELINES :
 
 All efforts should be made to fill in all the columns. No
 
 column should be left blank. In case certain information is not.
  |

 VI
----
 (See Rule 6)
 
 Information to be furnished regarding notification of a Major Accident
 
 Report Number.................
 
 of the particular accident.
 
|  |  |  |
| --- | --- | --- |
| 
 1.
  | 
 General data-
  | 
 |
| 
 | 
 (a) | 
 Name of the site
  | 
 |
| 
 | 
 (b) | 
 Name and address of the occupier (Also state the
 
 telephone/telex number)
  | 
 |
| 
 | 
 (c) | 
 (i)  Registration number
  | 
 |
| 
 | 
 | 
 (ii)  Licence number (As may have been allotted under any
 
 statute applicable to the site, e.g. the Factories Act.)
  | 
 |
| 
 | 
 (d) | 
 (i)  Nature of industrial activity (mention what is actually
 
 manufactured, stored etc.)
  | 
 |
| 
 | 
 | 
 (ii)  National Industrial Classification 1987 at the four digit
 
 level.
  | 
 |
| 
 2.
  | 
 Type of major accident Explosion......... Fire........
 
 Emission of hazardous chemical .........
  | 
 |
| 
 3.
  | 
 Description of the major accident-
  | 
 |
| 
 | 
 (a) | 
 Date, shift and hour of the accident.
  | 
 |
| 
 | 
 (b) | 
 Department/Section and exact place where the accident took
 
 place.
  | 
 |
| 
 | 
 (c) | 
 The process/operation undertaken in the Department/Section
 
 where the accident took place, (Attach a flow chart, if
 
 necessary).
  | 
 |
| 
 | 
 (d) | 
 The circumstances of the accident and the hazardous chemical
 
 involved.
  | 
 |
| 
 4.
  | 
 Emergency measures taken and measures envisaged to be taken to
 
 alleviate short term effects of the accident.
  | 
 |
| 
 5.
  | 
 Causes of the major accident known.
  | 
 |
| 
 | 
 (to be specified)
  | 
 .............................
  |
| 
 | 
 Not known
  | 
 .............................
  |
| 
 | 
 Information will be supplied as soon as possible
  | 
 .............................
  |
| 
 6.
  | 
 Nature and extent of damage
  | 
 |
| 
 | 
 (a)  within the establishment casualties
  | 
 .............................Killed
  |
| 
 | 
 | 
 .............................injured
  |
| 
 | 
 | 
 .............................Poisoned
  |
| 
 | 
 -Persons exposed to the major accident
  | 
 .............................
  |
| 
 | 
 -material damage
  | 
 .............................
  |
| 
 | 
 -danger is still present
  | 
 .............................
  |
| 
 | 
 -danger no longer exists
  | 
 .............................
  |
| 
 | 
 (b)  Outside the establishment
  | 
 |
| 
 | 
 -Causalities
  | 
 .............................Killed
  |
| 
 | 
 | 
 .............................injured
  |
| 
 | 
 | 
 .............................Poisoned
  |
| 
 | 
 -persons exposed to the major accident
  | 
 .............................
  |
| 
 | 
 -material damage
  | 
 .............................
  |
| 
 | 
 -damage to environment
  | 
 .............................
  |
| 
 | 
 -damage is still present
  | 
 .............................
  |
| 
 | 
 -danger no longer exists
  | 
 .............................
  |
| 
 7.
  | 
 Data available for assessing the effects of the accident on
 
 persons and environment.
  | 
 |
| 
 | 
 Steps already taken or envisaged-
  | 
 |
| 
 | 
 (a) | 
 to alleviate medium or long term effects of the accident.
  | 
 |
| 
 | 
 (b) | 
 to prevent recurrence of similar major accident.
  | 
 |
| 
 | 
 (c) | 
 Any other relevant information
  | 
 |

 VII
-----
 (See Rule 8)
 
 Information to be furnished for the notification of site
 
 Particulars to be included in a notification of site-
 
### 1. The name and address of the occupier making the notification. ###
 2. The full Postal address of the site where the notifiable industrial activity will be carried on.
### 3. The area of the site covered by the notification and of any adjacent site which is required to be taken into account by virtue of Schedule 2 (b)  and Schedule 3(b). ###
 4. The date on which it is anticipated that the notificable industrial activity will commence or if it has already commenced a statement to that effect.
### 5. The name and maximum quantity liable to be on the site of each hazardous chemical for which notification is being made. ###
 6. Orgnaisation structure, namely, organisation diagram for the proposed industrial activity and set up for ensuring safety and health.
### 7. Information relating to the potential for major accident, namely- (a) identification for major accident hazards :
 
 (b) the condition of events which could be significant in bringing one about;
 
 (c) a brief description of the measures taken.
 
### 8. Information relating to the site, namely- (a) a map of the site and its surrounding area to a scale large enough to show any features that may be significant in the assessment of the hazard or risk associated with the site;
 
 (i) area likely to be affected by the major accident
 
 (ii) population distribution in the vicinity
 
 (b) a scale plan of the site showing the location and quantity of all significant inventories of the hazardous chemicals;
 
 (c) a description of the processes or storages involving the hazardous chemicals, the maximum amount of such a hazardous chemical in the given process or storage and an indication of the condition under which it is normally held;
 
 (d) the maximum number of persons likely to be present on site.
 
### 9. The arrangement for training of workers and equipment necessary to ensure safety of such workers. VIII
------
 (See Rule 10)
 
 Information to be furnished in a Safety Report
 
### 1. The Name and address of the person furnishing the information ###
 2. Description of the industrial activity, namely-
 (a) site.
 
 (b) construction design,
 
 (c) protection zones (explosion protection separation distances)
 
 (d) accessibility of plant,
 
 (e) maximum number of persons working on the site and particularly of those person exposed to the hazard.
 
### 3. Description of the processes, namely- (a) technical purpose of the industrial activity,
 
 (b) basic principles of the technological process,
 
 (c) process and safety-related data individual process stages,
 
 (d) process description,
 
 (e) safety-related types of utilities,
 
### 4. Description of the hazardous chemicals, namely- (a) chemicals (quantities, substance data on physical and chemical properties, safety-related data on explosive limits flash-point, thermal stability, toxicological data and threshold limit values, lethal concentrations.)
 
 (b) the form in which the chemicals may occur of into which they may be transformed in the event of abnormal conditions.
 
 (c) the degree of purity of the hazardous chemical,
 
### 5. Information on the Preliminary Hazard Analysis, namely- (a) type of accident,
 
 (b) system element or foreseen events that can lead to a major accident
 
 (c) hazards,
 
 (d) safety-relevant components
 
### 6. Description of safety- relevant units, among others- (a) special design criteria,
 
 (b) controls and alarms,
 
 (c) pressure relief system,
 
 (d) quick-acting valves,
 
 (e) collecting tanks/dump tanks,
 
 (f) sprinkler systems
 
 (g) fire protection.
 
### 7. Information on the hazard assessment, namely- (a) identification of hazards,
 
 (b) the causes of major accidents,
 
 (c) assessment of hazards according to their occurrence frequency,
 
 (d) assessment of accident consequences,
 
 (e) safety system,
 
 (f) known accident history,
 
### 8. Description of information on organisational systems used to carry on industrial activity safety, namely : (a) maintenance and inspection schedules,
 
 (b) guidelines for the training of personnel
 
 (c) allocation and delegation of responsibility for plant safety,
 
 (d) implementation of safety procedures,
 
### 9. Information on assessment of the consequences of major accidents, namely- (a) assessment of the possible release of hazardous chemicals or of energy,
 
 (b) possible dispersion released chemicals.
 
 (c) assessment of the effects of the releases (size of the affected area, health effects, property damage).
 
### 10. Information on the mitigation of major accidents, namely- (a) fire brigade,
 
 (b) alarm systems
 
 (c) emergency plan containing system of organisation used to fight the emergency, the alarm and the communication routes, guide lines for fighting the emergency, examples of possible accident sequences.
 
 (d) co-ordination with the District Collector or the District Emergency Authority and its off-site emergency plan.
 
 (e) notification of the nature and scope of the hazard in the event of an accident,
 
 (f) antidotes in the event of a release of hazardous chemical
 

 IX
----
 (See Rule 12)
 
 Details to be furnished in the on-site emergency plan
 
### 1. Name and address of the person furnishing the information. ###
 2. Key personnel of the organisation and responsibilities assigned to them is case of an emergency.
### 3. Outside organisations if involved in assisting during on-site emergency- (a) type of accidents,
 
 (b) responsibility assigned
 
### 4. Details of liaison arrangement between the organisations ###
 5. Information on the preliminary hazard analysis-
 (a) type of accidents,
 
 (b) system elements or events that can lead to a major accident,
 
 (c) hazards.
 
 (d) safety relevant components
 
### 6. Detail about the site- (a) location of dangerous substances
 
 (b) seat of key personnel.
 
 (c) emergency control room.
 
### 7. Description of hazardous chemicals at plant site- (a) chemical (Quantities and toxilogical data)
 
 (b) transformation if any which could occour,
 
 (c) purity of hazardous chemicals
 
### 8. Likely dangers to the plant ###
 9. Emunerate of affects of
 (i) stress and strain caused during normal operation,
 
 (ii) fire and explosion inside the plant and effect if any of fire and explosion outside.
 
### 10. Details regarding- (i) warning alarm and safety and security system,
 
 (ii) alarm and hazard control plans in line with disaster control and hazard control planning, ensuring the necessary technical and organisational precaution.
 
 (iii) reliable measuring instruments, control units and servicing of such equipments.
 
 (iv) precaution in designing of the foundation and load bearing parts of the building,
 
 (v) continuous survilleance of operations,
 
 (vi) maintenance and prepair work according to the generally reorganised rules of good engineering practices.
 
### 11. Details of communication facilities available during emergency and those required for an off-site emergency. ###
 12. Details of fire fighting and other facilities available and those required for an off-site emergency.
### 13. Details of first-aid and hospital services available and it adequacy] .

