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Synthesis, Characterization and Performance of Cu2SnSe3 for Solar Cell Application | Eraky | Renewable Energy and Sustainable Development
Research Assistant at Central Metallurgical Research and Development Institute (CMRDI), Helwan, Egypt
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Synthesis, Characterization and Performance of Cu2SnSe3 for Solar Cell Application
Mostafa Shawky Eraky, Atef Y. Shenouda, Ibrahim A. Ibrahim
Abstract - Cu2SnSe3 (CTSe) powders were prepared by solvothermal (SR) and solid state reactions (SSR) using low cost starting materials. The crystal structure, morphology, UV-Vis absorbance, electrochemical and solar energy properties were investigated using X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), Electrochemical Impedance Spectroscopy (EIS) and solar energy applications using I-V characteristics measurements. Also, the toxicity of elements like cadmium makes these materials lower applicable. A single cubic Cu2SnSe3 was obtained for the two methods of preparations. The calculated crystallite size values for CTSe prepared by SR and SSR are 24.1 and 30.3 nm, respectively. UV-Vis. spectra for SR and SSR preparations showed maximum absorbencies at 240 nm with band gap values of 0.9 and 1.4 eV, respectively. The charge transfer resistances (Rct) were equal to 3.5 and 24 W for photoelectrochemical cells (PEC) and the calculated conductivities were equal to 3x10-2 and 2x10-2 S.cm-1 for samples that prepared by SR and SSR methods, respectively. A good photoelectrochemical cell (PCE) was accomplished power conversion efficiency per unit area of about 0.84 and 0.64 % for cells prepared by SR and SSR, respectively.
CTSe; Solvothermal; Solid State Reaction; Optical properties; Photoelcetrochemical cell (PEC).
J.J. Scragg, P.J. Dale, L.M. Peter, G. Zoppi and I. Forbes. "Synthesis and characterization of Cu2ZnSnS4 absorber layers by an electrodeposition annealing route,"Physica Status Solidi(b), vol. 245, pp 1772, 2008.
C. Wadia, A.P. Alivisatos and D.M. Kammen. "Materials availability expands the opportunity for largescale photovoltaics deployment, "Environmental Science and Technology, vol. 43, no. 6,pp. 2072–2077, 2009.
S.Ch. Ray and K. Mallick. "Cadmium Telluride (CdTe) thin film for photovoltaic applications," International Journal of Chemical Engineering and Applications, vol. 4, no. 4, pp. 183-186, Aug. 2013.
X. Chen, X.Wang, Ch. Anne, J. Liu and Y. Qian. "Preparation and characterization of ternary Cu–
Sn–E (E=S, Se) semiconductor nanocrystallites via a solvothermal element reaction route," Journal of Crystal Growth, vol.256, pp.368–376, 2003.
D. Avellaneda, M.T.S. Nair and P.K. Nair."Cu2SnS3 and Cu4SnS4 thin films via chemical deposition for photovoltaic application," Journal of the Electrochemical Society, vol. 157, pp. 346–352, 2010.
P.A. Fernandes, P.M.P. Salomé and A.F. da Cunha."CuxSnSx+1 (x = 2, 3) thin films grown by sulfurization of metallic precursors deposited by dc magnetron sputtering,"Physica Status Solidi(C), vol. 7, 901–904, 2010.
P.Y. Lee, Sh.Ch. Shei, E.H. Hsu and Sh.J. Chang. "A novel synthesis of Cu2SnSe3 nanoink prepared via elemental sources and isophorondiamine chelation," Materials Letters, vol. 102–103, pp.120–122,2013.
G. Gurieva, S. Levcenko, S. Schorr, M. León, R. Serna, A. Nateprov and E. Arushanov. "Characterization of Cu2 SnSe3 by spectroscopic ellipsometry," Thin Solid Films, vol. 535, pp.384–
Q. Lia, Y. Dingb, X. Liu and Y. Qiana. "Preparation of ternary I–IV–VI nanocrystallines via a mild solution route," Materials Research Bulletin, vol. 36,pp. 2649 –2656, 2001.
G.E. Delgado, A.J. Mora, G. Marcanob and C. Rinco. "Crystal structure refinement of the semiconducting compound Cu2SnSe3 from X-ray powder diffraction data," Materials Research Bulletin, vol. 38, pp. 1949–1955, 2003.
G. Marcano, L.M. de Chalbaud, C. Rinco´n and G. S.Pe´rez. "Crystal growth and structure of the
semiconductor Cu2SnSe3," Materials Letters, vol.53, pp.151–154, 2002.
D.H. Kuo, W.D. Haung, Y.Sh. Huang, J.D. Wu and Y.J. Lin. "Single-step sputtered Cu2SnSe3 films using the targets composed of Cu2Se and SnSe2," Thin Solid Films,vol. 518, no. 24, pp.7218–7221, 1 October 2010.
Z. Tang, Y. Nukui, K. Kosaka, N.Ashida, H. Uegaki and T. Minemoto. "Reduction of secondary phases in Cu2SnSe3 absorbers for solar cell application," Journal of Alloys and Compounds, vol. 608, pp.213–219, 2014 .
D.H. Kuo, Y.J. Lin, Y.Sh. Huang, W.D. Haung and J.D. Wu. "Effect of post-deposition annealing
on the performance of D.C. sputtered Cu2SnSe3 thin films, "Surface and Coatings Technology, vol. 205, no. 1, pp.196–200, 25 December 2010.
K.M. Kim, H. Tampo, H. Shibata and Sh. Niki. “Growth and characterization of co evaporated Cu2SnSe3 thin films for photovoltaic applications," Thin Solid Films, vol. 536, pp. 111–114, 2013.
G.S. Babu, Y.B. Kishore, Y.B. Kumar and V.S. Raja. "Growth and characterization of Cu2SnSe3 thin films," Materials Chemistry and Physics, vol.96, pp. 442–446, 2006.
K.M. Kim, H. Tampo, H. Shibata and Sh. Niki. "Temperature induced phase transformation in coevaporated Cu2SnSe3 thin films," Materials Letters, vol. 116, pp. 61–63, 2014.
M. Ibanez, D. Cadavid, U.A. Tamburini, R. Zamani, S. Gorsse, W. Li, A.M. Lo´pez, J.R. Morante, J. Arbiold and A. Cabot."Colloidal synthesis and thermoelectric properties of Cu2SnSe3 nanocrystals," Journal of Materials Chemistry A, vol. 1, pp. 1421-1426, 2013.
J. Wang, A. Singh, P. Liu, Sh. Singh, C. Coughlan, Y. Guo and K. Ryan. "Colloidal synthesis of Cu2SnSe3 Tetrapod Nanocrystals," Journal of the American Chemical Society, vol.135, no. 21, pp. 7835–7838, 2013.
J.M. Song, Y. Liu, H.L. Niu, Ch.J. Mao, L.J. Cheng, S.Y. Zhang and Y.H. Shen. "Hot-injection synthesis and characterization of monodispersed ternary Cu2SnSe3 nanocrystals for thermoelectric applications," Journal of Alloys and Compounds, vol. 581, pp.646–652, 2013.
V.D. Das and D.R. Shankar."Fabrication and characterization of photoelectrochemical (PEC) solar cellsbased on 0.1% indium-doped CdSe0.7Te0.3 thin-film electrode," Surface and Coatings Technology, vol. 146, pp. 498–501,2001.
A. Monshi, M.R. Foroughi and M.R. Monshi."Modified Scherrer equation to estimate more accurately nano-crystallite size using XRD," World Journal of Nano Science and Engineering, vol. 2, pp. 154-160, 2012.
A. Tumuluri, K.L. Naidu and K.C.Raju.“Band gap determination using Tauc’s plot for LiNbO3 Thin films," International Journal of Chemical Technology Research, vol.6, no.6, pp 33533356, 2014.
P.U. Bhaskar, G.S. Babu, Y.B. Kumar and V.S. Raja. "Investigations on co-evaporated Cu2SnSe3 and Cu2SnSe3 -ZnSe thin films," Applied Surface Science, vol. 257, pp 8529–8534, 2011.
G.H. Chandra, O.L. Kumar, R.P. Rao, S.Uthanna. "Colloidal synthesis and thermoelectric properties of Cu2SnSe3 nanocrystals," Journal of Materials Science, vol. 46, pp 6952–6959, 2011.
A. Astam.“Structural and optical characterization of Cu2SnSe3 thin films prepared by SILAR method,” Thin Solid Films, vol. 615, pp 324–328, 2016.
A. Prasad and A. Basu."Dielectric and impedance properties of sintered magnesium aluminium silicate glass-ceramic," Journal of Advanced Ceramics, vol. 2, pp. 71–78, 2013.
A. Chaouchi and S. Kennour."Impedance spectroscopy studies on lead free (Ba0.85Ca0.15) (Ti0.9Zr0.1) O3 ceramics," Processing and Application of Ceramics, vol. 6, pp. 201–207, 2012.
M. David, B.J. Marc, A. Cyril, B. Annelise, D. Laurentand D. Elisabeth. "Influence of crystallinity and particle size on the electrochemical properties of spray pyrolyzed Nd2NiO4+d powders,"Electrochimica Acta, vol. 87, pp. 330-335, 2013.
K.Prasad, A. Rao, K. Tyagi, N. Chauhan, B. Gahtori, S. Bathula, A. Dhar. "Enhanced thermoelectric performance of Pb doped Cu2SnSe3 synthesized employing spark plasma sintering,"Physica B, vol. 512, pp 39–44, 2017.