Raspes Munchausen became a sensation, establishing a literary exemplar of a bombastic liar or exaggerator.In 1951, Richard Asher was the first to describe a pattern of self-harm, wherein individuals fabricated histories, signs, and symptoms of illness. Remembering Baron Munchausen, Asher named this condition Munchausens Syndrome in his article in The Lancet in February 1951, quoted in his obituary in the British Medical Journal:

Here is described a common syndrome which most doctors have seen, but about which little has been written. Like the famous Baron von Munchausen, the persons affected have always travelled widely; and their stories, like those attributed to him, are both dramatic and untruthful. Accordingly the syndrome is respectfully dedicated to the Baron, and named after him. Ashers nomenclature sparked some controversy, with medical authorities debating the appropriateness of the name for about fifty years. While Asher was praised for bringing cases of factitious disorder to light, participants in the debate objected variously that a literary allusion was inappropriate given the seriousness of the disease; that its use of the anglicized spelling "Munchausen" showed poor form; that the name linked the disease with the real-life Münchhausen, who did not have it; and that the names connection to works of humor and fantasy, and to the essentially ridiculous character of the fictional Baron Munchausen, was disrespectful to patients with the disorder.Originally, this term was used for all factitious disorders.
Iron(III) pyrophosphate is an inorganic chemical compound with the formula Fe4(P2O7)3. Synthesis
Anhydrous iron(III) pyrophosphate can be prepared by heating the mixture of iron(III) metaphosphate and iron(III) phosphate under oxygen with the stoichiometric ratio 1:3. The reactants can be prepared by reacting iron(III) nitrate nonahydrate with phosphoric acid.It can be also prepared via the following reaction:
3 Na4P2O7(aq) + 4 FeCl3(aq) → Fe4(P2O7)3(s) + 12 NaCl(aq)

References
External links
"Ferric pyrophosphate". Drug Information Portal. U.S. National Library of Medicine. "Ferric pyrophosphate nonahydrate". Drug Information Portal. U.S. National Library of Medicine. "Ferric pyrophosphate citrate". Drug Information Portal. U.S. National Library of Medicine.