An interpretation of this result and what a closer look at the physical meaning of the 
  
    
      
        λ
      
    
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   one can read the paper by Marcus.the situation at hand can be more accurately described by using the displaced harmonic oscillator model, in this model quantum tunneling is allowed. This is needed in order to explain why even at near-zero Kelvin there still are electron transfers, in contradiction to the classical theory. Without going into too much detail on how the derivation is done, it rests on using Fermis golden rule from time-dependent perturbation theory with the full Hamiltonian of the system. It is possible to look at the overlap in the wavefunctions of both the reactants and the products (the right and the left side of the chemical reaction) and therefore when their energies are the same and allow for electron transfer. As touched on before this must happen because only then conservation of energy is abided by.
An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte, a vacuum or air). Electrodes are essential parts of batteries that can consist of a variety of materials depending on the type of battery. The electrophore, invented by Johan Wilcke, was an early version of an electrode used to study static electricity. Anode and cathode in electrochemical cells
Electrodes are an essential part of any battery. The first electrochemical battery made was devised by Alessandro Volta and was aptly named the Voltaic cell. This battery consisted of a stack of copper and zinc electrodes separated by brine-soaked paper disks. Due to fluctuation in the voltage provided by the voltaic cell it wasnt very practical. The first practical battery was invented in 1839 and named the Daniell cell after John Frederic Daniell. Still making use of the zinc–copper electrode combination. Since then many more batteries have been developed using various materials (see List of batteries). The basis of all these is still making use of two electrodes which can be divided in two categories: Anodes and Cathodes. Anode
A term coined by William Whewell at Faradays request, derived from the Greek words ἄνο (ano), upwards and ὁδός (hodós), a way. The Anode is the electrode through which the conventional current enters from the electrical circuit of an electrochemical cell (battery) into the non-metallic cell. The electrons then flow to the other side of the battery.