Examples include:

Prilocaine hydrochloride and epinephrine (trade name Citanest Forte)
Lidocaine, bupivacaine, and epinephrine (recommended final concentrations of 0.5, 0.25, and 0.5%, respectively)
Iontocaine, consisting of lidocaine and epinephrine
Septocaine (trade name Septodont), a combination of articaine and epinephrineOne combination product of this type is used topically for surface anaesthesia, TAC (5-12% tetracaine,1/2000 (0.05%, 500 ppm, 1⁄2 per mille) adrenaline, 4 or 10% cocaine). Using LA with vasoconstrictor is safe in regions supplied by end arteries. The commonly held belief that LA with vasoconstrictor can cause necrosis in extremities such as the nose, ears, fingers, and toes (due to constriction of end arteries), is invalidated, since no case of necrosis has been reported since the introduction of commercial lidocaine with epinephrine in 1948. Ester group
Benzocaine
Chloroprocaine
Cocaine
Cyclomethycaine
Dimethocaine (Larocaine)
Piperocaine
Propoxycaine
Procaine (Novocaine)
Proparacaine
Tetracaine (Amethocaine)

Amide group
Articaine
Bupivacaine
Cinchocaine (Dibucaine)
Etidocaine
Levobupivacaine
Lidocaine (Lignocaine)
Mepivacaine
Prilocaine
Ropivacaine
Trimecaine

Naturally derived
Saxitoxin
Neosaxitoxin
Tetrodotoxin
Menthol
Eugenol
Cocaine
SpilantholMost naturally occurring local anesthetics with the exceptions of menthol, eugenol and cocaine are neurotoxins, and have the suffix -toxin in their names. Cocaine binds the intracellular side of the channels while saxitoxin, neosaxitoxin and tetrodotoxin bind to the extracellular side of sodium channels. History
In Peru, the ancient Incas are believed to have used the leaves of the coca plant as a local anaesthetic in addition to its stimulant properties. It was also used for slave payment and is thought to play a role in the subsequent destruction of Incas culture when Spaniards realized the effects of chewing the coca leaves and took advantage of it. Cocaine was first used as a local anesthetic in 1884.
Epidural anesthesia is an LA injected into the epidural space, where it acts primarily on the spinal nerve roots; depending on the site of injection and the volume injected, the anesthetized area varies from limited areas of the abdomen or chest to large regions of the body. Spinal anesthesia is an LA  injected into the cerebrospinal fluid, usually at the lumbar spine (in the lower back), where it acts on spinal nerve roots and part of the spinal cord; the resulting anesthesia usually extends from the legs to the abdomen or chest. Intravenous regional anesthesia (Biers block) is when blood circulation of a limb is interrupted using a tourniquet (a device similar to a blood-pressure cuff), then a large volume of LA is injected into a peripheral vein. The drug fills the limbs venous system and diffuses into tissues, where peripheral nerves and nerve endings are anesthetized. The anesthetic effect is limited to the area that is excluded from blood circulation and resolves quickly once circulation is restored. Local anesthesia of body cavities includes intrapleural anesthesia and intra-articular anesthesia. Transincision (or transwound) catheter anesthesia uses a multilumen catheter inserted through an incision or wound and aligned across it on the inside as the incision or wound is closed, providing continuous administration of local anesthetic along the incision or woundsDental-specific techniques include:

Vazirani-Alkinosi Technique
The Vazirani-alkinosi technique is also known as the closed-mouth mandibular nerve block.