7. From the set $\{1,2, \cdots, 100\}$, randomly select elements $m$ and $n$ (which can be the same). Then the probability that the unit digit of $2^{m}+3^{n}$ is 3 is $\qquad$ .
7. $\frac{3}{16}$.

Notice that, $2^{1}, 2^{2}, 2^{3}, 2^{4}, \cdots$ modulo 10 has a repeating cycle of $2, 4, 8, 6$, and $3^{1}, 3^{2}, 3^{3}, 3^{4}, \cdots$ modulo 10 has a repeating cycle of $3, 9, 7, 1$.

Since $4 | 100$, the probability that the last digit of $2^{m}$ is $2, 4, 8, 6$ is $\frac{1}{4}$ each, and the probability that the last digit of $3^{n}$ is $3, 9, 7, 1$ is $\frac{1}{4}$ each. Among these, only
$$
2+1=3, 4+9=13, 6+7=13
$$

three combinations result in the last digit of $2^{m}+3^{n}$ being 3.
Thus, the probability is $\frac{1}{4} \times \frac{1}{4} + \frac{1}{4} \times \frac{1}{4} + \frac{1}{4} \times \frac{1}{4} = \frac{3}{16}$.