14. (10 points) Fill in each cell with a number from $1 \sim 6$, such that no number is repeated in any row or column. The number on the right indicates the sum of the three-digit number, the two-digit number, and the single-digit number formed by the first three numbers, the middle two numbers, and the last number, respectively, separated by thick lines. What is the five-digit number $\overline{\mathrm{ABCDE}}=$ $\qquad$
【Solution】Solution: First, determine $D$. In the intersecting cells of $D$, the numbers 12345 are present. Therefore, $D=6$.
Next, look at $A$. The sum of the digits is 696. For a two-digit number, the maximum tens digit is 6, so the hundreds place of $A$ must be the largest digit 6.

Now, consider $B, 165-35=130$, and subtracting a single-digit number less than 7 will still result in a number greater than 120. Therefore, $B=2$. According to the sum of the digits in the fourth row being 381, then $381-7=374$, the resulting units digit must be 4. Based on the first cell in the fifth column, which corresponds to $1,3,4,5,6$, the only possible number is 2.
$E \neq 1$, so $E=3$.
Then, based on the second row in the third column, which corresponds to $1,2,3,5,6$, the only possible number is 4. In the fifth row of the third column, there is an $E$ which is the number 3, so it can only be 2.

Therefore, $C=3$.
The answer is: 62363.