text: Arenediazonium salts have been reported as an alternative to aryl halides for the Sonogashira coupling reaction. Gold(I) chloride has been used as co-catalyst combined with palladium(II) chloride in the coupling of arenediazonium salts with terminal alkynes, a process carried out in the presence of bis-2,6-diisopropylphenyl dihydroimidazolium chloride (IPr NHC) (5 mol%) to in situ generate a NHC–palladium complex, and 2,6-di-tert-butyl-4-methylpyridine (DBMP) as base in acetonitrile as solvent at room temperature. This coupling can be carried out starting from anilines by formation of the diazonium salt followed by in situ
  Sonogashira coupling,  where anilines are transformed into diazonium salt and furtherly converted into alkyne by coupling with phenylacetylene.