text: The general location of the proton drip line is well established. For all elements occurring naturally on earth and having an odd number of protons, at least one species with a proton separation energy less than zero has been experimentally observed. Up to germanium, the location of the drip line for many elements with an even number of protons is known, but none past that point are listed in the evaluated nuclear data. There are a few exceptional cases where, due to nuclear pairing, there are some particle-bound species outside the drip line, such as B and Au. One may also note that nearing the magic numbers, the drip line is less understood. A compilation of the first unbound nuclei known to lie beyond the proton drip line is given below, with the number of protons, Z and the corresponding isotopes, taken from the National Nuclear Data Center.