text: The natural bite angle (β) of diphosphines, obtained using molecular mechanics calculations, is defined as the preferred chelation angle determined only by ligand backbone and not by metal valence angles (Figure 3).
  Both steric bite angle effect and the electronic bite angle effects are recognized. The steric bite angle effect involves the steric interactions between ligands or between a ligand and a substrate. The electronic bite angle effect, on the other hand, relates to the electronic changes that occur when the bite angle is modified. This effect is sensitive to the hybridization of metal orbitals. This flexibility range accounts for the diverse conformations of the ligand with energies slightly above the strain energy of the natural bite angle.
  The bite angle of a diphosphine ligand also indicates the distortion from the ideal geometry of a complex based on VSEPR models. Octahedral and square planar complexes prefer angles near 90° while tetrahedral complexes prefer angles near 110°. Since catalysts often interconvert between various geometries, the rigidity of the chelate ring can be decisive. A bidentate phosphine with a natural bite angle of 120° may preferentially occupy two equatorial sites in a trigonal bipyramidal complex whereas a bidentate phosphine with a natural bite angle of 90° may preferentially occupy apical-equatorial positions. Diphosphine ligands with bite angles of over 120° are obtained using a bulky, stiff diphosphine backbones. Diphosphines of wide bite angles are used in some industrial processes.