text: Once the C-H bond of methane is activated by bonding to a transition metal complex, the net functionalization of the alkyl metal complex into another hydrocarbon containing a functional group is actually much harder to achieve. In general, alkanes of various lengths have typically been functionalized by a number of more commonly known reactions: electrophilic activation (Shilov system, see above), dehydrogenation, borylation, hydrogen-deuterium exchange, and carbene/nitrene/oxo insertion. The functionalization of methane in particular has been reported in four different methods that use homogeneous catalysts rather than heterogeneous catalysts. Heterogeneous systems, using copper- and iron exchanged Zeolite, are also investigated. In these systems, reactive oxygen species such as Alpha-Oxygen are generated which can perform a hydrogen atom abstraction.