text: The A ring synthesis (Scheme 3) started with a Diels-Alder reaction of diene 3.1 with the commercially available dienophile 2-chloroacrylonitrile 3.2 to give cyclohexene 3.3 with complete regioselectivity. Hydrolysis of the cyanochloro group and simultaneous cleavage of the acetate group led to hydroxyketone 3.4. The hydroxyl group was protected as a tert-butyldimethylsilyl ether (3.5). In preparation for a Shapiro reaction, this ketone was converted to hydrazone 3.6.