text: Due to redox-disequilibrium, selenium could be very reluctant to abiotic chemical reduction and would be released from the waste (spent fuel or vitrified waste) as selenate (), a soluble Se(VI) species, not sorbed onto clay minerals. Without solubility limit and retardation for aqueous selenium, the dose of Se is comparable to that of I. Moreover, selenium is an essential micronutrient as it is present in the catalytic centers in the glutathione peroxidase, an enzyme needed by many organisms for the protection of their  cell membrane against oxidative stress damages; therefore, radioactive Se can be easily bioconcentrated in the food web. In the presence of nitrate () released in deep geological clay formations by bituminized waste issued from the spent fuel dissolution step during their reprocessing, even reduced forms of selenium could be easily oxidised and mobilised.