text: There are two main types of transmetalation, redox-transmetalation (RT) and redox-transmetalation/ligand-exchange (RTLE). Below, M is usually a 4d or 5d transition metal and M is usually a main group or 3d transition metal. By looking at the electronegativities of the metals and ligands, one can predict whether the RT or RTLE reaction will proceed and what products the reaction will yield. For example, one can predict that the addition of 3 HgPh to 2 Al will yield 3 Hg and 2 AlPh because Hg is a more electronegative element than Al.