text: Several syntheses of oxoiron(IV) species have been reported. These compounds model biological complexes such as cytochrome P450, NO synthase, and isopenicillin N synthase. Two such reported compounds are thiolate-ligated oxoiron(IV) and cyclam-acetate oxoiron(IV).
  Thiolate-ligated oxoiron(IV) is formed by the oxidation of a precursor, [Fe(TMCS)](PF) (TMCS = 1-mercaptoethyl-4,8,11-trimethyl-1,4,8,11-tetraza cyclotetradecane), and 3-5 equivalents of HO at -60 ˚C in methanol. The iron(IV) compound is deep blue in color and shows intense absorption features at 460 nm, 570 nm, 850 nm, and 1050 nm. This species Fe(=O)(TMCS)+ is stable at -60 ˚C, but decomposition is reported as temperature increases. Compound 2 was identified by Mössbauer spectroscopy, high resolution electrospray ionization mass spectrometry (ESI-MS), X-ray absorption spectroscopy, extended X-ray absorption fine structure (EXAFS), ultraviolet–visible spectroscopy (UV-vis), Fourier-transform infrared spectroscopy (FT-IR), and results were compared to density functional theory (DFT) calculations.
  Tetramethylcyclam oxoiron(IV) is formed by the reaction of Fe(TMC)(OTf), TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane; OTf = CFSO, with iodosylbenzene (PhIO) in CHCN at -40 ˚C. A second method for formation of cyclam oxoiron(IV) is reported as the reaction of Fe(TMC)(OTf) with 3 equivalents of HO for 3 hours. This species is pale green in color and has an absorption maximum at 820 nm. It is reported to be stable for at least 1 month at -40 ˚C. It has been characterized by Mössbauer spectroscopy, ESI-MS, EXAFS, UV-vis, Raman spectroscopy, and FT-IR.
  High-valent iron bispidine complexes can oxidize cyclohexane to cyclohexanol and cyclohexanone in 35% yield with an alcohol to ketone ratio up to 4.