text: A variation of the heat flow technique is called power compensation calorimetry. This method uses a cooling jacket operating at constant flow and temperature. The process temperature is regulated by adjusting the power of the electrical heater. When the experiment is started, the electrical heat and the cooling power (of the cooling jacket) are in balance. As the process heat load changes, the electrical power is varied in order to maintain the desired process temperature. The heat liberated or absorbed by the process is determined from the difference between the initial electrical power and the demand for electrical power at the time of measurement. The power compensation method is easier to set up than heat flow calorimetry but it suffers from the similar limitations since any change in product composition, liquid level, process temperature, agitation rate or viscosity will upset the calibration. The presence of an electrical heating element is also undesirable for process operations. The method is further limited by the fact that the largest heat it can measure is equal to the initial electrical power applied to the heater.
  : = current supplied to heater
  : = voltage supplied to heater
  : = current supplied to heater at equilibrium (assuming constant voltage / resistance)