text: In a loss-of-coolant accident (LOCA) it is thought that the surface of the cladding could reach a temperature between 800 and 1400 K, and the cladding will be exposed to steam for some time before water is reintroduced into the reactor to cool the fuel. During this time when the hot cladding is exposed to steam some oxidation of the zirconium will occur to form a zirconium oxide which is more zirconium rich than zirconia. This Zr(O) phase is the α-phase, further oxidation forms zirconia. The longer the cladding is exposed to steam the less ductile it will be. One measure of the ductility is to compress a ring along a diameter (at a constant rate of displacement, in this case 2 mm min) until the first crack occurs, then the ring will start to fail. The elongation which occurs between when the maximum force is applied and when the mechanical load is declined to 80% of the load required to induce the first crack is the L value in mm. The more ductile a sample is the greater this L value will be.
  In one experiment the zirconium is heated in steam to 1473 K, the sample is slowly cooled in steam to 1173 K before being quenched in water. As the heating time at 1473 K is increased the zirconium becomes more brittle and the L value declines.