text: Relatively few in-situ reactions have been reported involving gray arsenic due to its low solubility, although it reacts in air to form gaseous AsO . Two examples of the reactivity of gray arsenic towards transition metals are known. In these reactions, cyclopentadienyl complexes of molybdenum, tungsten and chromium proceed via loss of carbon monoxide to react with gray arsenic and form mono-, di-, and triarsenic compounds.