text: Filling a clean bottle with river water is a very simple task, but a single sample is only representative of that point along the river the sample was taken from and at that point in time. Understanding the chemistry of a whole river, or even a significant tributary, requires prior investigation to understand how homogeneous or mixed the flow is and to determine if the quality changes during the course of a day and during the course of a year. Almost all natural rivers will have very significant patterns of change through the day and through the seasons. Water remote sensing offers a spatially continuous tool to improve understanding of spatial and temporal river water quality. Many rivers also have a very large flow that is unseen. This flows through underlying gravel and sand layers and is called hyporheic flow. How much mixing there is between the hyporheic zone and the water in the open channel will depend on a variety of factors, some of which relate to flows leaving aquifers which may have been storing water for many years.