text: Metal carbene complexes are often classified into two types. The Fischer carbenes, named after Ernst Otto Fischer, feature strong π-acceptors at the metal and are electrophilic at the carbene carbon atom. Schrock carbenes, named after Richard R. Schrock, are characterized by more nucleophilic carbene carbon centers; these species typically feature higher oxidation state (valency) metals. N-Heterocyclic carbenes (NHCs) were popularized following Arduengo's isolation of a stable free carbene in 1991. Reflecting the growth of the area, carbene complexes are now known with a broad range of different reactivities and diverse substituents. Often it is not possible to classify a carbene complex solely with regards to its electrophilicity or nucleophilicity.