text: The  and  distances are 117 and 158 pm.  By contrast, in methyl thiocyanate,  and  distances are 116 and 176 pm.
  Typical bond angles for  in aryl isothiocyanates are near 165°. Again, the thiocyanate isomers are quite different with  angle near 100°.  In both isomers the  angle approaches 180°.