text: In 1850, T. J. Mulvany was probably the first investigator to use mathematical modeling in a stream hydrology context, although there was no chemistry involved. By 1892 M.E. Imbeau had conceived an event model to relate runoff to peak rainfall, again still with no chemistry. Robert E. Horton’s seminal work on surface runoff along with his coupling of quantitative treatment of erosion laid the groundwork for modern chemical transport hydrology.