text: A solution of the amide (0.365 g, 0.809 mmol), Pd(PPh) (0.187 g, 0.162 mmol), and triethylamine (1.12 mL, 8.08 mmol) in MeCN (8 mL) in a sealed tube was heated slowly to 120°. After stirring for 4 hours, the reaction mixture was cooled to room temperature, and the solvent was evaporated. The residue was chromatographed (loaded with CHCl) to give the title product 316 (0.270 g, 90%) as a colorless oil; R 0.42 (EtOAc/petroleum ether 10:1); [α] +14.9 (c, 1.0, CHCl); IR 3027, 2930, 1712, 1673, 1608, 1492, 1343, 1248 cm; H NMR (400 MHz) δ 7.33–7.21 (m, 6 H), 7.07 (dd, J = 7.3, 16.4 Hz, 1 H), 7.00 (t, J = 7.5 Hz, 1 H), 6.77 (d, J = 7.7 Hz, 1 H), 6.30 (dd, J = 8.7, 11.4 Hz, 1 H), 5.32 (d, J = 15.7 Hz, 1 H), 5.04 (s, 1 H), 4.95 (s, 1 H), 4.93 (d, J = 11.1 Hz, 1 H), 4.17 (s, 1 H), 3.98 (d, J = 15.7 Hz, 1 H), 3.62 (d, J = 8.7 Hz, 1 H), 3.17 (s, 3 H), 2.56 (dd, J = 3.5, 15.5 Hz, 1 H), 2.06 (dd, J = 2.8, 15.5 Hz, 1 H); C NMR (100 MHz) δ 177.4, 172.9, 147.8, 142.2, 136.5, 132.2, 131.6, 128.8, 128.4, 128.2, 127.7, 127.1, 123.7, 122.9, 107.9, 105.9, 61.0, 54.7, 49.9, 44.4, 38.2, 26.4; HRMS Calcd. for CHNO: 370.1681. Found: 370.1692.