text: Clathrate hydrates were discovered in 1810 by Humphry Davy. Clathrates were studied by P. Pfeiffer in 1927 and in 1930, E. Hertel defined "molecular compounds" as substances decomposed into individual components following the mass action law in solution or gas state. Clathrate hydrates were discovered to form blockages in gas pipelines in 1934 by Hammerschmidt that led to increase in research to avoid hydrate formation. In 1945, H. M. Powell analyzed the crystal structure of these compounds and named them clathrates. Gas production through methane hydrates has since been realized and has been tested for energy production in Japan and China.