text: The use of P,N ligands in asymmetric hydrogenation can be traced to the C symmetric bisoxazoline ligand.  However, these symmetric ligands were soon superseded by monooxazoline ligands whose lack of C symmetry has in no way limits their efficacy in asymmetric catalysis.  Such ligands generally consist of an achiral nitrogen-containing heterocycle that is functionalized with a pendant phosphorus-containing arm, although both the exact nature of the heterocycle and the chemical environment phosphorus center has varied widely.  No single structure has emerged as consistently effective with a broad range of substrates, although certain privileged structures (like the phosphine-oxazoline or PHOX architecture) have been established.  Moreover, within a narrowly defined substrate class the performance of metallic complexes with chiral P,N ligands can closely approach perfect conversion and selectivity in systems otherwise very difficult to target. Certain complexes derived from chelating P-O ligands have shown promising results in the hydrogenation of α,β-unsaturated ketones and esters.