text: Human activities have a major effect on the global sulfur cycle.  The burning of coal, natural gas, and other fossil fuels has greatly increased the amount of sulfur in the atmosphere and ocean and depleted the sedimentary rock sink.  Without human impact sulfur would stay tied up in rocks for millions of years until it was uplifted through tectonic events and then released through erosion and weathering processes.  Instead it is being drilled, pumped and burned at a steadily increasing rate.  Over the most polluted areas there has been a 30-fold increase in sulfate deposition.   
  Although the sulfur curve shows shifts between net sulfur oxidation and net sulfur reduction in the geologic past, the magnitude of the current human impact is probably unprecedented in the geologic record.  Human activities greatly increase the flux of sulfur to the atmosphere, some of which is transported globally.  Humans are mining coal and extracting petroleum from the Earths crust at a rate that mobilizes 150 x 10 gS/yr, which is more than double the rate of 100 years ago.  The result of human impact on these processes is to increase the pool of oxidized sulfur (SO) in the global cycle, at the expense of the storage of reduced sulfur in the Earths crust.  Therefore, human activities do not cause a major change in the global pools of sulfur, but they do produce massive changes in the annual flux of sulfur through the atmosphere.
  When SO is emitted as an air pollutant, it forms sulfuric acid through reactions with water in the atmosphere.  Once the acid is completely dissociated in water the pH can drop to 4.3 or lower causing damage to both man-made and natural systems.  According to the EPA, acid rain is a broad term referring to a mixture of wet and dry deposition (deposited material) from the atmosphere containing higher than normal amounts of nitric and sulfuric acids.  Distilled water (water without any dissolved constituents), which contains no carbon dioxide, has a neutral pH of 7.  Rain naturally has a slightly acidic pH of 5.6, because carbon dioxide and water in the air react together to form carbonic acid, a very weak acid. Around Washington, D.C., however, the average rain pH is between 4.2 and 4.4.  Since pH is on a log scale dropping by 1 (the difference between normal rain water and acid rain) has a dramatic effect on the strength of the acid.  In the United States, roughly two thirds of all SO and one fourth of all NO come from electric power generation that relies on burning fossil fuels, like coal.
  As it is an important nutrient for plants, sulfur is increasingly used as a component of fertilizers. Recently sulfur deficiency has become widespread in many countries in Europe. Because of actions taken to limit acid rains atmospheric inputs of sulfur continue to decrease, As a result, the deficit in the sulfur input is likely to increase unless sulfur fertilizers are used.