text: A monosaccharide often switches from the acyclic (open-chain) form to a cyclic form, through a nucleophilic addition reaction between the carbonyl group and one of the hydroxyl groups of the same molecule.  The reaction creates a ring of carbon atoms closed by one bridging oxygen atom.  The resulting molecule has a hemiacetal or hemiketal group, depending on whether the linear form was an aldose or a ketose.  The reaction is easily reversed, yielding the original open-chain form.
  In these cyclic forms, the ring usually has five or six atoms. These forms are called furanoses and pyranoses, respectively—by analogy with furan and pyran, the simplest compounds with the same carbon-oxygen ring (although they lack the double bonds of these two molecules). For example, the aldohexose glucose may form a hemiacetal linkage between the aldehyde group on carbon 1 and the hydroxyl on carbon 4, yielding a molecule with a 5-membered ring, called glucofuranose. The same reaction can take place between carbons 1 and 5 to form a molecule with a  ring, called glucopyranose. Cyclic forms with a seven-atom ring (the same of oxepane), rarely encountered, are called heptoses.
  For many monosaccharides (including glucose), the cyclic forms predominate, in the solid state and in solutions, and therefore the same name commonly is used for the open- and closed-chain isomers.  Thus, for example, the term "glucose" may signify glucofuranose, glucopyranose, the open-chain form, or a mixture of the three.
  Cyclization creates a new stereogenic center at the carbonyl-bearing carbon.  The −OH group that replaces the carbonyls oxygen may end up in two distinct positions relative to the rings midplane.  Thus each open-chain monosaccharide yields two cyclic isomers (anomers), denoted by the prefixes α- and β-.  The molecule can change between these two forms by a process called mutarotation, that consists in a reversal of the ring-forming reaction followed by another ring formation.