text: The two terminal N–O bonds are nearly equivalent and relatively short, at 1.20 and 1.21 Å. This can be explained by theories of resonance; the two major canonical forms show some double bond character in these two bonds, causing them to be shorter than N–O single bonds. The third N–O bond is elongated because its O atom is bonded to H atom, with a bond length of 1.41 Å in the gas phase. The molecule is slightly aplanar (the nitro group| and NOH planes are tilted away from each other by 2°) and there is restricted rotation about the N–OH single bond.