text: Signatures of mass-anomalous sulfur isotope fractionation preserved in the rock record have been an important piece of evidence for understanding the Great Oxidation Event, the sudden rise of oxygen on the ancient Earth. Nonzero values of ΔS and ΔS are present in the sulfur-bearing minerals of Precambrian rock formed greater than 2.45 billion years ago, but completely absent from rock less than 2.09 billion years old. Multiple mechanisms have been proposed for how oxygen prevents the fingerprints of mass-anomalous fractionation from being created and preserved; nevertheless, all studies of ΔS and ΔS records conclude that oxygen was essentially absent from Earth's atmosphere prior to 2.45 billion years ago.