text: As in metal–carbonyls, electrons are partially transferred from a d-orbital of the metal to antibonding molecular orbitals of the alkenes and alkynes.  This electron transfer strengthens the metal–ligand bond and weakens the C–C bonds within the ligand. In the case of metal-alkenes and alkynes, the strengthening of the M–CR and M–CR bond is reflected in bending of the C–C–R angles which assume greater sp and sp character, respectively.  Thus strong π backbonding causes a metal-alkene complex to assume the character of a metallacyclopropane. Alkenes and alkynes with electronegative substituents exhibit greater π backbonding. Some strong π backbonding ligands are tetrafluoroethylene, tetracyanoethylene, and hexafluoro-2-butyne.