text: The isomeric shift on atomic spectral lines is the energy or frequency shift in atomic spectra, which occurs when one replaces one nuclear isomer by another. The effect was predicted by Richard M. Weiner in 1956, whose calculations showed that it should be measurable by atomic (optical) spectroscopy (see also). It was observed experimentally for the first time in 1958. The theory of the atomic isomeric shift is also used in the interpretation of the Mössbauer isomeric shift.