text: According to the rules exposed above, the phenanthrene molecule admits two different resonance structures: one of them presents a single circle in the center of the molecule, with each of the two adjacent rings having two double bonds; the other one has the two peripheral rings each with one circle, and the central ring with one double bond. According to Clar's rule, this last resonance structure gives the most important contribution to the determination of the properties of phenanthrene.