text: A knowledge of environmental soil chemistry is paramount to predicting the fate of contaminants, as well as the processes by which they are initially released into the soil. Once a chemical is exposed to the soil environment, myriad chemical reactions can occur that may increase or decrease contaminant toxicity. These reactions include adsorption/desorption, precipitation, polymerization, dissolution, hydrolysis, hydration, complexation and oxidation/reduction. These reactions are often disregarded by scientists and engineers involved with environmental remediation. Understanding these processes enable us to better predict the fate and toxicity of contaminants and provide the knowledge to develop scientifically correct, and cost-effective remediation strategies.