text: Due to the initial lack of a formal definition after the initial conception, the term inherent chirality was utilized to describe a variety of chiral molecules that don't fall into other defined chirality types.  The first fully formulated definition of inherent chirality was published in 2004 by Mandolini and Schiaffino, (and later modified by Szumna):
  Inherent chirality has been known by a variety of names in the literature including bowl chirality (in fullerene fragments), intrinsic chirality, helicity (see section 3a) residual enantiomers (as applied to sterically hindered molecular propellers,) and cyclochirality (though this is often considered to be a more specific example and cannot be applied to all inherently chiral molecules).
  A simple example of inherent chirality is that of corannulene commonly referred to as "bowl chirality" in the literature.  The chirality of an unsubstituted corranulene (containing no classic stereogenic centers) cannot be seen in a 2D representation, but becomes clear when a 3D representation is evoked, as the C symmetry of corranulenes provides the molecules with a source of chirality (figure 2.)  Racemization of these molecules is possible through an inversion of curvature, though some inherently chiral molecules have inversion barriers comparable to a classic chiral center.