text: Supramolecular assemblies have no specific applications but are the subject of many intriguing reactions.  A supramolecular assembly of peptide amphiphiles in the form of nanofibers has been shown to promote the growth of neurons. An advantage to this supramolecular approach is that the nanofibers will degrade back into the individual peptide molecules that can be broken down by the body.  By self-assembling of dendritic dipeptides, hollow cylinders can be produced. The cylindrical assemblies possess internal helical order and self-organize into columnar liquid crystalline lattices. When inserted into vesicular membranes, the porous cylindrical assemblies mediate transport of protons across the membrane. Self-assembly of dendrons generates arrays of nanowires. Electron donor-acceptor complexes comprise the core of the cylindrical supramolecular assemblies, which further self-organize into two-dimensional columnar liquid crystalline lattices. Each cylindrical supramolecular assembly functions as an individual wire. High charge carrier mobilities for holes and electrons were obtained.