text: Inputs from the biosphere may begin with lichen and other microorganisms that secrete oxalic acid. These microorganisms, associated with the lichen community or independently inhabiting rocks, include blue-green algae, green algae, various fungi, and numerous bacteria. Lichen has long been viewed as the pioneers of soil development as the following 1997 Isozaki statement suggests:
  However, lichens are not necessarily the only pioneering organisms nor the earliest form of soil formation as it has been documented that seed-bearing plants may occupy an area and colonize quicker than lichen. Also, eolian sedimentation (wind generated) can produce high rates of sediment accumulation. Nonetheless, lichen can certainly withstand harsher conditions than most vascular plants, and although they have slower colonization rates, they do form the dominant group in alpine regions.
  Organic acids released from plant roots include acetic acid and citric acid. During the decay of organic matter phenolic acids are released from plant matter and humic acid and fulvic acid are released by soil microbes. These organic acids speed up chemical weathering by combining with some of the weathering products in a process known as chelation. In the soil profile, these organic acids are often concentrated at the top of the profile, while carbonic acid plays a larger role towards the bottom of the profile or below in the aquifer.
  As the soil column develops further into thicker accumulations, larger animals come to inhabit the soil and continue to alter the chemical evolution of their respective niche. Earthworms aerate the soil and convert large amounts of organic matter into rich humus, improving soil fertility. Small burrowing mammals store food, grow young and may hibernate in the pedosphere altering the course of soil evolution. Large mammalian herbivores above ground transport nutrients in form of nitrogen-rich waste and phosphorus-rich antlers, while predators leave phosphorus-rich piles of bones on the soil surface, leading to localized enrichment of the soil.