text: the compositions and methods of the invention relate to coatings , and in one aspect inks . materials that are standard and conventional in the art are suitable for use in the compositions and methods herein . lithographic printing is the art or process of printing from a flat plate in which the desired image is achieved by construction of said plate such that selective adhesion of the printing ink to plate occurs in the desired image area ( s ), followed by contact transfer of said image either directly , or indirectly to a substrate ( e . g ., paper , plastic , metal ). unsaturated fatty acids are defined as materials having the composite structure hoc ( o )( cr 1 r 2 ) n ( r 3 c ═ cr 4 ) m r 7 , wherein m is an integer from one to about 5 , wherein n is an integer from 3 to about 20 , and wherein each of the various r groups ( e . g ., r 1 , r 2 , r 3 , r 4 ) is independently chosen from among hydrogen or is a monovalent hydrocarbyl group having from one to about four carbon atoms . the various ( cr 1 r 2 ) and ( r 3 c ═ cr 4 ) need not be consecutive or in conjugation , but may be connected to each other in any order . unsaturated fatty acids useful in the compositions and methods herein include , for example , those listed in the tables herein . organozirconium compounds are compounds ( or complexes ) having organic ( i . e ., carbon and hydrogen containing ) functional groups bound ( including covalently or through noncovalent binding interactions ) to zirconium atom ( s ). in one aspect the compounds are those having a zirconium atom in an oxidation state of ( iv ). organozirconium compounds useful in the compositions and methods herein include , for example , those listed in the tables herein . ( meth ) acrylate esters are herein defined as materials having the general structure [ rch 2 ═ chc ( o ) o ] nr ′, wherein n is an integer larger than 1 ; each r is independently chosen from hydrogen , or a ch 3 group , and r ′ is chosen from among hydrocarbyl groups having from two to about 20 carbon atoms each , except that the number of carbon atoms in each r ′ must equal or exceed n . ( meth ) acrylate esters useful in the compositions and methods herein include , for example , those listed in the tables herein . the compositions may have one or more ( e . g ., 2 , 3 , 4 , 5 methacrylate esters ) in them . multifunctional vinyl ethers are herein defined as organic chemicals which contain the structure [ rrc ═ cro ] nr ′ wherein n is a n integer larger than 1 ; each r is independently chosen from hydrogen , or a ch 3 group , and r ′ is chosen from among hydrocarbyl groups having from two to about 10 carbon atoms each . inorganic salts of peracids ( or peroxy acids ) are herein defined as salts of acids containing the structure ( o — o − ), in which the cation has a positive electrical charge on an atom other than hydrogen , or carbon . inorganic salts of peracids useful in the compositions and methods herein include , for example , those listed in the tables herein . in some aspects of the invention , the inorganic salts of peracids are used in catalytic amounts ( e . g ., less than about 0 . 5 weight percent , less than about 0 . 25 weight percent , less than about 0 . 1 weight percent , based on total weight of the composition ; or between about 1 and 100 , 000 ppm , between about 1 and 50 , 000 ppm ). organic hydroperoxides are defined as an organic compound containing the structure c — o — o ( r ) wherein r is a chosen from among hydrogen , or a group bonded through carbon to the peroxide oxygen . organic hydroperoxides useful in the compositions and methods herein include , for example , those listed in the tables herein . the variety of unsaturated fatty acids , poly ( hydroxy ) aliphatic carboxylic acids , organo zirconium compounds , ( meth ) acrylate esters , vinyl ethers , and accelerators , useful in the practice of this invention is very large , however for the sake of brevity , only 10 examples of preferred members of each class of materials are provided in tables a through e respectively . the examples provided hereinafter are intended to be illustrative of , and not to exhaustive of nor to limit the scope of this invention . those skilled in the art will easily be able to provide many more examples of each class of such components with minimal difficulty , and without departing from the teachings of this invention . an into vehicle is a combination of components , other than pigments , which is collectively suitable for ink compositions . in one aspect , the ink vehicle contains certain components that are incompatible for storage with other ink components ( i . e ., when in contact , an irreversible reaction takes place , which may be undesirable or may be desired to be controlled such that the reaction takes place immediately prior to , or concurrent with , use of the resulting product ( e . g ., ink ) for printing ). in such instance , one of the incompatible components is placed in the ink vehicle and the other is placed in a second ink vehicle ( e . g ., fountain solution ) for mixing immediately prior to , or concurrent with , use . the ink vehicle can include any of the materials delineated herein , or can also include any standard ink vehicle component know in the art , including for example , solids , alkyds , polyesters or polyamides suitable for ink or printing compositions , and the like . the same material can be considered a varnish when pigments are absent from the composition . varnishes are expressly considered one aspect of the compositions delineated herein . the compositions herein are useful in lithographic printing applications . such applications can be intaglio or off - set , including sheet - fed , cold - web , and heat set web printing . the invention will be further described in the following example . it should be understood that these examples are for illustrative purposes only and are not to be construed as limiting this invention in any manner . method for the preparation of the poly ( hydroxy ) aliphatic acid - fatty acid solutions . a nitrogen blanketed pyrex glass lined vessel , equipped with an external heating - cooling jacket , a high speed disperser , and appropriate inlet and outlet ports , was charged with 150 kg of rapeseed oil fatty acid , and 75 g of 1 , 2 , 3 - tris methoxy benzene . the charge was heated to and maintained , under nitrogen , at 140 ° c . for 3 . 5 hr . during which period 50 kg of poly ( 6 ) caprolactone ( mw 2700 , mn 1290 ) ( dow chemical corp . tone polymer ) was incrementally added and dissolved . under high shear . the resulting tan solution was cooled to ambient and discharged . yield of a low viscosity of a freely flowing liquid solution ( 25 wt %) poly 6 - hydroxy caproic acid . product designation 1a . similarly prepared in near quantitative yields were a 32 % solution of poly lactic acid ( dow material ) in oticca oil fatty acid ( 1b ), and an 11 % solution of poly glycolic acid ( dupont ) in tung oil fatty acid ( 1c ). method for the preparation of the poly ( hydroxy ) aliphatic acid - fatty acid solutions a nitrogen blanketed pyrex glass lined vessel , equipped with an external heating - cooling jacket , a high speed disperser , distillation column , distillate receiver , and appropriate inlet and outlet ports , was charged with 150 kg of soya been oil fatty acid , 325 g of antimony pentoxide and 75 g of 1 , 2 , 3 - tris methoxy benzene . the charge was heated to and maintained , under nitrogen , at 160 ° c . for 3 . 5 hr . during which period 30 kg of 4 - butyrolactone , and 15 kg each of 2 - hydroxy propionic acid , and 4 - hydroxy 2 - pentenoic acid were premixed and continuously added . after completion of the materials addition ( water was observe red to distill continuously ), the reaction temperature was raised to 200 ° c . and maintained at said temperature for @ 25 mm hg vacuum for two hours . the product was recovered as a light brown modest viscosity solution after cooling to 70 ° c . c prior to discharge . under high shear . the resulting tan solution was cooled to ambient and discharged . product yield was 97 . 7 weight %, as a low viscosity , freely flowing liquid solution ( nominally 28 . 6 wt % terpolymer in soya oil fatty acid ). yield of distillate water [& gt ; 99 % gas chromatographic ( gc ) assay ] was 2 . 16 %, 98 . 9 % of theory . product designation 2a similarly prepared under comparable conditions , using the indicated reagents were a variety of analogs poly ( hydroxy ) carboxylic polymer solutions in unsaturated fatty acids . cf . table 2 . methods for the preparation of the rapidly drying lithographic ink vehicles demonstrating benefits of same versus conventional technology ; i . e . enhanced gloss , rub resistance , and set and drying rates . a 200 gallon water jacketed 316 ss mixing tank equipped with a 10 horsepower slow speed agitator was heated to , mixed and maintained at 50 - 65 ° c . during the sequential addition of 1a , 80 lb . ; ultrex 100 , 240 lb ., ultrex 110 562 lb . [ ultrex ( aluminum gelled soya alkyd ) resins were supplied by lawter div . of eastman chemical co . ); ba 18 lb , and aluminum stearate 4 . 5 lb . the resulting solution ( 3a ) was evaluated for utility as a an overprint varnish . a portion of this varnish was converted to a lithograph ink by dispersion therein of 16 weight percent of a phthalocyanine blue pigment ( ciba irgalite blue lge ). both the ink and the varnish were evaluated versus control formulations in which the 1a , and ba were replaced by like proportions of 300 ° f . magie 300 ink oil ( mobil oil ), and 6 % cobalt naphthenate respectively , producing inks and varnishes each having 400 rpm tack readings of 6 . 8 , for both the test and control inks , and 5 . 5 and 5 . 7 , for the control and test varnishes , respectively . five thousand sheets of each set of inks and overprint varnishes were each printed ( full coverage ), both independently and sequentially , on a komori two color sheetfed press , @ 9 , 500 prints / hr . using 60 lb . coated paper stock ( international paper co . ), and stacked in single piles maintained @ 23 - 23 ° c . evaluation of the resulting prints showed that the ink derived from the practice of the instant invention dried 32 % faster , and was 7 % glossier than its conventional counterpart . ( through dry time 5 hr , 42 min . vs . 8 hr . 23 min . ; gloss 93 . 5 % vs 87 . 0 %) the overprint varnish of the instant invention , dried 46 % faster ( 7 hr . 19 min . vs . 13 hr 34 min . ), and dried to a gloss 3 % higher than its solvent based alternative ( 95 . 2 vs . 92 . 3 %. the drying of the combination of ink and overprint varnish printed prints required 8 hr . 34 min . vs . 14 hr . 52 min for the control system , a 59 % time savings . furthermore the prints prepared from either the ink or varnish produced via the teachings of the instant invention could be stacked at depths of 5 , 000 + sheets , without offsetting , but the conventional ink and varnish ( independently or as a composite ) need offset powder at stacking levels above 2 , 730 sheets , even after application of high doses of offset powder ; whereas ink products of the instant invention , individually , required the use of only amounts of offset powder . however the composite prints produced by applying both the ink and varnish of the instant invention required modest offset powder application in order to eliminate offset at stack depths above 4 , 200 sheets . gloss improvement for overprint varnished blue ink was 3 . 5 % vs . the control system ( 94 . 4 vs . 91 . 7 ). further improvement vs . the control formulation was achieved by heating product 3a for a period @ a temperature of from about 100 to about 170 ° c . under nitrogen , and cooling to ambient prior to evacuation . 3ah ( through drying times for the derived ink , varnish and ink - varnish combination were reduced to 5 hr . 16 min . ; 6 hr . 11 min . and 6 hr . 42 min . respectively upon heating the varnish / ink vehicle @ 130 +/− 10 ° c . for two hours prior to use . similar treatment of the control formulations , produced no measurable improvements . similarly produced and evaluated were a series of analogous products using a variety of ink , pigment , varnish , and vehicle components and vehicle heat treatment conditions . the resulting formulations are compiled in table 3a . these inks , and varnishes , were printed on a four color man roland 700 press , using unigraphics 500 fountain solution optionally modified as indicated , diluted to a conductivity of 1800 - 2500 siemans with deionized water . the results of these investigations are provided in table 3b . table 3a material varnish heat identification formulation / wt . % history / hr ./° c . 3bv tung - linseed varnish 1 / 28 . 8 ; gelled soy varnish 2 / 52 . 8 ; 60 - 70 / 1 . 5 2c / 7 . 2 ; bc4 . 2 ; pe wax 5 / 0 . 6 ptfe 6 / 2 . 4 3bh v tung - linseed varnish 1 / 28 . 8 ; gelled soy varnish 2 / 52 . 8 ; 60 - 70 / 1 . 5 + 150 - 160 / 2 2c / 7 . 2 ; bc4 . 2 ; pe wax 5 / 0 . 6 ptfe 6 / 2 . 4 3b tung - linseed varnish 1 / 24 ; gelled soy varnish 2 / 44 ; carbon 60 - 70 / 1 . 5 ink black 3 / 18 ; alkali blue 4 / 2 ; 2c / 6 ; bc3 . 5 ; pe wax 5 / 0 . 5 ptfe 6 / 2 3bh tung - linseed varnish 1 / 24 ; gelled soy varnish 2 / 44 ; carbon 60 - 70 / 1 . 5 + 150 - 160 / 2 ink black 3 / 18 ; alkali blue 4 / 2 ; 2c / 6 ; bc / 3 . 5 ; pe wax 5 / 0 . 5 ; ptfe 6 / 2 3bh1 tung - linseed varnish 1 / 24 ; gelled soy varnish 2 / 40 ; carbon 60 - 70 / 1 . 5 + 150 - 160 / 2 black 3 / 18 ; alkali blue 4 / 2 ; 2c / 6 ; bc / 3 . 5 ; pe wax 5 / 0 . 5 ; ptfe 6 / 2 ; cc 7 / 4 . 3b control tung - linseed varnish 1 / 28 . 8 ; gelled soy varnish 2 / 52 . 8 ; 60 - 70 / 1 . 5 varnish magie 300 oil 8 / 9 . 0 ; 12 % mn octoate 9 / 2 . 4 ; pe wax / 0 . 6 ; ptfe 6 / 2 . 4 . 3b control tung - linseed varnish 1 / 24 ; gelled soy varnish 2 / 44 ; carbon 60 - 70 / 1 . 5 ink black 3 / 18 ; alkali blue 4 / 2 ; magie 300 oil 8 / 7 . 5 ; 12 % mn octoate 9 / 2 ; pe wax / 0 . 5 ; ptfe 6 / 2 . 3bh control tung - linseed varnish 1 / 30 ; gelled soy varnish 2 / 44 ; carbon 60 - 70 / 1 . 5 ink black 3 / 18 ; alkali blue 4 / 2 ; magie 300 oil 8 / 7 . 5 ; 12 % mn octoate 9 / ptfe 6 / 2 3c polyamide varnish 10 / 46 ; polyester - oil varnish 11 / 40 40 - 45 / 2 . 5 varnish 2g / 11 ; bh / 3 3c polyamide varnish 10 / 40 ; polyester - oil varnish 11 / 32 40 - 45 / 2 . 5 ink yellow pigment 12 / 14 ; 2g / 11 ; bh / 3 3c1 polyamide varnish 10 / 40 ; polyester - oil varnish 11 / 30 40 - 45 / 2 . 5 ink yellow pigment 12 / 14 ; 2g / 11 ; bh / 3 ; ce 7 / 2 3c2 polyamide varnish 10 / 40 ; polyester - oil varnish 11 / 30 40 - 45 / 2 . 5 ink yellow pigment 12 / 14 ; 2g / 11 ; bh / 3 ; ch 7 / 2 3ch polyamide varnish 10 / 40 ; polyester - oil varnish 11 / 32 40 - 45 / 2 . 5 + 110 - 120 / 6 yellow pigment 12 / 14 ; 2g / 11 ; bh / 3 . 3ch1 polyamide varnish 10 / 40 ; polyester - oil varnish 11 / 30 40 - 45 / 2 . 5 + 110 - 120 / 6 yellow pigment 12 / 14 ; 2g / 11 ; bh / 3 ; ce 7 / 2 . 3ch2 polyamide varnish 10 / 40 ; polyester - oil varnish 11 / 30 40 - 45 / 2 . 5 + 110 - 120 / 6 yellow pigment 12 / 14 ; 2g / 11 ; bh / 3 ; ch 7 / 2 . 3c control polyamide varnish 10 / 46 ; polyester - oil varnish 11 / 40 40 - 45 / 2 . 5 varnish tetradecanol / 7 . 5 ; 12 % zirconium octoate 9 / 3 . 3ch control polyamide varnish 10 / 46 ; polyester - oil varnish 11 / 40 40 - 45 / 2 . 5 varnish tetradecanol / 7 . 5 ; 12 % zirconium octoate 9 / 3 . 110 - 120 / 6 3c control polyamide varnish 10 / 40 ; polyester - oil varnish 11 / 32 40 - 45 / 2 . 5 ink yellow pigment 12 / 14 ; tetradecanol / 7 . 5 ; 12 % zirconium octoate 9 / 3 . 3ch control polyamide varnish 10 / 40 ; 16 polyester - oil varnish 11 / 32 40 - 45 / 2 . 5 + 110 - 120 / 6 ink yellow pigment 12 / 14 ; tetradecanol / 7 . 5 ; 12 % zirconium octoate 9 / 3 . notes : 1 lawter - 3020 ; 2 lawter - gellusoy : 3 cabot 400r ; 4 basf , 5 honeywell ac 540a ; 6 shamrock sst - 4 ; 7 all acrylates , and methacrylates employed , were obtained from sartomer corp . 8 pennzoil corp . 9 omg corp . 10 lawter - nypol 7 ; 11 lawter terlon 1 ; 12 ciba yellow12 ; 13 blend of lawter - geltung 3 / 60 % geltung 7 / 40 %; 14 lenape corp 5500 . 1 sutherland abrasion test after 72 hr . cure at ambient temperature . similarly produced and evaluated were a series of analogous products using a variety of ink , pigment , varnish , and vehicle components and vehicle heat treatment conditions . the resulting formulations are compiled in table 3a . these inks , and varnishes , were printed on a four color man roland 700 press , using unigraph 500 fountain solution . optionally modified as indicated , diluted to a conductivity of 1800 - 2500 siemans with deionized water . the results of these investigations are provided in table 3b . utility of inorganic salts of peroxy acids , and of organic ( hydro ) peroxides as accelerators for the cure of the inks of the instant invention , in increasing the set limited press speed , and drying speed of the inks instant invention as compared to the response of their art counterparts . selected inks formulated as defined in table 3a were printed using the same press , and conditions as were employed in example 3 , except that the ink or fountain solution employed therein were modified by the addition of the indicated ppm of an accelerator as specified . the results of this evaluation are presented in table 4 . the compounds of this invention ( including as used in compositions herein ) may contain one or more asymmetric centers and thus occur as racemates and racemic mixtures , single enantiomers , individual diastereomers and diastereomeric mixtures . e -, z - and cis - trans - double bond isomers are envisioned as well . all such isomeric forms of these compounds are expressly included in the present invention . the compounds of this invention may also be represented in multiple tautomeric forms , in such instances , the invention expressly includes all tautomeric forms of the compounds described herein . all such isomeric forms of such compounds are expressly included in the present invention . all crystal forms of the compounds described herein are expressly included in the present invention . unless otherwise defined , all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs . although methods and materials similar or equivalent to those described herein can be used in the practice or testing of the present invention , suitable methods and materials are described below . in case of conflict , the present specification , including definitions , will control . in addition , the materials , methods , and examples are illustrative only and not intended to be limiting . all references cited herein , whether in print , electronic , computer readable storage media or other form , are expressly incorporated by reference in their entirety , including but not limited to , abstracts , articles , journals , publications , texts , treatises , internet web sites , databases , patents , and patent publications . a number of embodiments of the invention have been described . nevertheless , it will be understood that various modifications may be made without departing from the spirit and scope of the invention . accordingly , other embodiments are within the scope of the following claims .