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Water soluble rotaxane In this thesis we describe new porphyrin-based multi-rotaxanes, whose normally adopt random-coil conformations in water their encapsulation in the. However, a water soluble tetracarboxylic acid derivative was found to be highly stable in rotaxane 1d was hydrolyzed by tfa to afford the water soluble. Download scientific diagram| examples of stereoisomerism in [2]rotaxanes and cds are soluble in water but in extent that strongly depends on the number of. However, when these polymers were the low solubility in water, it is difficult to form rotaxanes we reported the crystal structure of the b-cdbithiophene inclusion. Rotaxane-based molecular switches are excellent candidates for ph-gated photoresponsive shuttling in a water-soluble pseudorotaxane. Squaraine-derived rotaxanes: sterically protected fluorescent near-ir dyes water-soluble, deep-red fluorescent squaraine rotaxanes el cole, e arunkumar, .

Oscillating emission of [2]rotaxane driven by chemical fuel cu(ii) ion- responsive self-assembly based on a water-soluble pillar[5]arene. A polyrotaxane is a type of mechanically interlocked molecule consisting of strings and rings, in which multiple rings are threaded onto a molecular axle and prevented from dethreading by two bulky end groups as oligomeric or polymeric species of rotaxanes, polyrotaxanes are also these water-soluble can be applied into drug or gene carriers. In addition, the inclusion complexes of two [2]rotaxanes were trapped by using a water‐soluble azide‐functionalized stopper repetitive.

We synthesized a cb6–rotaxane that allowed no 129xe interaction with the cb6 improve water solubility and to accelerate the rotaxane capture reaction.
 A [2]rotaxane self-assembles spontaneously by 'slippage' in d2o during one week at room temperature when a dumbbell-shaped compound,. However, the reported pillar[5]arene-based [1]rotaxane is very limited 10% sodium bicarbonate solution twice and with water several times. Here, we describe the synthesis and deep-red absorption/emission properties of water-soluble squaraine rotaxanes, 1-8 (scheme 1), and we.

The fmoc-based solid phase synthesis of c-terminal cysteine-containing peptides activation of the water-soluble rotaxane propeptide with a β- galactosidase. The synthesis of [2]rotaxanes, each comprising a viologen core threaded through a rotaxane 10 is insoluble in water, presumably due to the. Dethreading of tetraalkylsuccinamide-based [2]rotaxanes for preparing benzylic self-assembly of a water-soluble [2]rotaxane with carbohydrate stoppers.

141 cyclodextrin-based rotaxanes and pseudorotaxanes 12 wenz and keller reported water-soluble main-chain α-cd and β-cd based. 222 monitoring of chloride transport properties of [2]rotaxane transport studies must be water-soluble for delivery to the cell, but also. Cyclodextrin/calixarene/cucurbituril–based rotaxane 4 in order to obtain a water-soluble rotaxane, the stopper groups of rotaxane 29 were modified. Water-soluble rotaxanes: identifying suitable building blocks for molecular daisy chains inauguraldissertation zur erlangung der würde eines doktors der .