Which expansion of $e$ is more accurate? We have two forms  of $e^x$ 

$$e^x=1+x+\frac{x^2}{2!}+\frac{x^3}{3!}+....$$
  and
  $$e^x=\frac{1}{\displaystyle 1-x+\frac{x^2}{2!}-\frac{x^3}{3!}+....}$$
  The second form comes from $e^x=1/e^{-x}$

Which one is more accurate if I want to find any value of $e^x$ 

The accuracy of any Taylor expansion of a given order is given by the next order of the expansion.   For this very case, the answer is that it depends on how far out you want to take the expansions.  For example,
$$\frac1{1-x} = 1+x+x^2+O(x^3)$$
This has twice the error as the expansion $1+x$, whose next term is $x^2/2!$.  However,
$$\begin{align}\frac1{1-x+x^2/2} &= 1+\left (x-\frac{x^2}{2} \right ) + \left (x-\frac{x^2}{2} \right )^2+ \left (x-\frac{x^2}{2} \right )^3 + \cdots \\&= 1+x+\frac{x^2}{2} + O(x^4)\end{align}$$
Thus, for the second-order expansion, the reciprocal has a smaller error.  However, for the cubic expansion, the expansion is
$$1+x+\frac{x^2}{2}+\frac{x^3}{6}+\frac{x^4}{12} + O(x^5) $$
whereas the fourth order term in the direct, Taylor expansion of the exponential is $x^4/24$.  Thus, the direct Taylor expansion is more accurate out to fourth order.
There is a systematic way to prove that the accuracy alternates with order oddness or evenness by considering the error in the expansion of $e^x \cdot e^{-x}=1$.
ADDENDUM
The proof is actually not all that hard.  Consider the finite approximations to the equation $e^x \cdot e^{-x}=1$:
$$\left (\sum_{k=0}^m \frac{x^k}{k!} \right ) \left (\sum_{k=0}^m (-1)^k \frac{x^k}{k!} \right ) $$
It may be easily shown that the coefficients of $x$, $x^2$, ..., $x^m$ are zero.  We now consider the first error term, i.e., the coefficient of $x^{m+1}$:
$$\frac{x^1}{1!} \frac{(-1)^m x^m}{m!} + \frac{x^2}{2!} \frac{(-1)^{m-1} x^{m-1}}{(m-1)!} +\cdots + \frac{x^m}{m!} \frac{(-1)^1 x^1}{1!} = \sum_{k=1}^m \frac{(-1)^{m-k+1}}{k! (m-k+1)!} x^{m+1}$$
Rewrite this sum, sans the $x^{m+1}$ term, as
$$\sum_{k=0}^{m-1} \frac{(-1)^{m-k}}{(k+1)! (m-k)!} = (-1)^m \sum_{k=0}^{m-1} \frac{(-1)^k}{k! (m-k)!} \frac1{k+1}$$
We can evaluate this sum by realizing that
$$(1-x)^m = \sum_{k=0}^m (-1)^k \binom{m}{k} x^k $$
so that
$$\sum_{k=0}^m (-1)^k \binom{m}{k} \frac1{k+1} = \int_0^1 dx \, (1-x)^m = \frac1{m+1}$$
Therefore, by subtracting off the last term in the sum, we find that
$$(-1)^m \sum_{k=0}^{m-1} \frac{(-1)^k}{k! (m-k)!} \frac1{k+1}  = - \frac{1-(-1)^m}{(m+1)!}$$
Therefore, we now may say that

$$\frac1{\displaystyle \sum_{k=0}^m (-1)^k \frac{x^k}{k!} } =
 \sum_{k=0}^m \frac{x^k}{k!} + \frac{1-(-1)^m}{(m+1)!} x^{m+1} +
 O(x^{m+2})$$

For even values of $m$, the next term error is zero, which is smaller than that for the direct Taylor series, which has error $x^{m+1}/(m+1)!$.  On the other hand, for odd values, the error is double that of the direct Taylor series.  This agrees with the above examples.
ADDENUDUM II
You may use the above analysis to determine whether you can get better accuracy using 
$$e^x = \frac{e^{x/2}}{e^{-x/2}} $$
(Generally speaking, rational approximations to functions that agree with Taylor series in certain limits are called Pade approximates, and may be very useful in some situations.)
