Finding the indefinite integral of $\int_0^\pi\sqrt{\sin^3x - \sin^5x}dx$ It's not hard to find that $\int\sqrt{\sin^3x - \sin^5x}dx = \frac{2\sin^{5/2}x}{5} + C$,
But the indefinite integral $\int_0^\pi\sqrt{\sin^3x - \sin^5x}dx = \frac{4}{5}$ does not conform to $\cfrac{2\sin^{5/2} \pi}{5} - \cfrac{2\sin^{5/2} 0}{5} = 0 - 0 = 0$
Why is that we can't simply use Newton-Leibniz axiom here and what is the way to find the value $\frac{4}{5}$ here ?

I'm going to elaborate on Kavi's answer:
The problem here is that the antiderivative $\frac{2}{5}\sin^{\frac{5}{2}}(x)+C$ is only valid when $x\in\left[0,\frac{\pi}{2}\right]$.

Looking at the Desmos plot I provided, it can be seen that the derivative of $\frac{2}{5}\sin^{\frac{5}{2}}(x)$ does not agree with $\sqrt{\sin^3(x)-\sin^5(x)}$ when $x\in\left(\frac{\pi}{2},\pi\right)$. This is because
\begin{align*}
\sqrt{\sin^3(x)-\sin^5(x)} &= \sqrt{\sin^3(x)\left[1-\sin^2(x)\right]}\\
&= \sin^{\frac{3}{2}}(x)\sqrt{\cos^2(x)}\\
&= \sin^{\frac{3}{2}}(x)|\cos(x)|
\end{align*}
and $\cos(x)$ is negative when $x\in\left(\frac{\pi}{2},\pi\right)$.
Don't lose hope, though! We can still find the correct antiderivative and apply $\text{FTC}2$. To begin, note that
$$\sqrt{\sin^3(x)-\sin^5(x)}$$
is continuous over $\left[0,\pi\right]$, so $\text{FTC}1$ asserts that the function
$$f(x)=\int_{0}^{x}\sqrt{\sin^3(t)-\sin^5(t)}\text{ }dt$$
is an antiderivative of $\sqrt{\sin^3(x)-\sin^5(x)}$. We can now boil down the problem of finding an antiderivative to finding a nice expression for this integral.
Using the identity $\sqrt{\sin^3(x)-\sin^5(x)}=\sin^{\frac{3}{2}}(x)|\cos(x)|$, we can write
$$f(x)=\int_{0}^{x}\sin^{\frac{3}{2}}(t)|\cos(t)|\text{ }dt$$
so for $x\in\left[0,\frac{\pi}{2}\right]$,
\begin{align*}
\int_{0}^{x}\sin^{\frac{3}{2}}(t)|\cos(t)|\text{ }dt &= \int_{0}^{x}\sin^{\frac{3}{2}}(t)\cos(t)\text{ }dt\\
&= \int_{0}^{\sin(x)}u^{\frac{3}{2}}\text{ }du\\
&= \frac{2}{5}\sin^{\frac{5}{2}}(x)
\end{align*}
For $x\in\left[\frac{\pi}{2},\pi\right]$,
\begin{align*}
\int_{0}^{x}\sin^{\frac{3}{2}}(t)|\cos(t)|\text{ }dt &= \int_{0}^{\frac{\pi}{2}}\sin^{\frac{3}{2}}(t)|\cos(t)|\text{ }dt+\int_{\frac{\pi}{2}}^{x}\sin^{\frac{3}{2}}(t)|\cos(t)|\text{ }dt\\
&= \frac{2}{5}\sin^{\frac{5}{2}}\left(\frac{\pi}{2}\right)-\int_{\frac{\pi}{2}}^{x}\sin^{\frac{3}{2}}(t)\cos(t)\text{ }dt\\
&= \frac{2}{5}-\int_{1}^{\sin(x)}u^{\frac{3}{2}}\text{ }du\\
&= \frac{2}{5}-\left(\frac{2}{5}\sin^{\frac{5}{2}}(x)-\frac{2}{5}\right)\\
&= \frac{4}{5}-\frac{2}{5}\sin^{\frac{5}{2}}(x)
\end{align*}
Thus,
$$f(x)=\begin{cases}
\frac{2}{5}\sin^{\frac{5}{2}}(x) & \text{if }x\in\left[0,\frac{\pi}{2}\right]\\
\frac{4}{5}-\frac{2}{5}\sin^{\frac{5}{2}}(x) & \text{if }x\in\left[\frac{\pi}{2},\pi\right]
\end{cases}$$
We can now (legally) evaluate the original integral with $\text{FTC}2$.
\begin{align*}
\int_{0}^{\pi}\sqrt{\sin^3(x)-\sin^5(x)}\text{ }dx &= f(\pi)-f(0)\\
&= \frac{4}{5}-\frac{2}{5}\sin^{\frac{5}{2}}(\pi)-\frac{2}{5}\sin^{\frac{5}{2}}(0)\\
&= \frac{4}{5}
\end{align*}
