Thermodynamic versus kinetic reactions 2

I want to ask more following the previous Question. ([Thermodynamic versus kinetic reactions](https://chemistry.stackexchange.com/questions/47857/thermodynamic-versus-kinetic-reactions))


[![enter image description here](https://i.stack.imgur.com/WY7tC.png)](https://i.stack.imgur.com/WY7tC.png)


1. in this reaction below, is the first product 'kinetic product'? and second one is 'thermodynamic product' ?
2. upper pathway is acid/base reaction but doesn't seem reversible, thus looks like far from thermodynamics. but I learned acid/base reaction is about thermodynamics. what did I get wrong?


I'd appreciate any comments^\_^


