## Acknowledgements 

Work supported by UChicago Argonne, LLC, Operator of Argonne National Laboratory (Argonne). Work at Argonne and use the Advanced Photon Source at Argonne was supported by the U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. We acknowledge use of the oxide-MBE at the Center for Nanoscale Materials. We acknowledge support from NDSEG (JMR) the NSF under grant no. DMR 0940420 (NAS) and discussions with the Army Research Office MURI program (award no. W911-NF-09-1-0398). Portions of this work made use of the SGI Altix cobalt system at the National Center for Supercomputing Applications under grant no. TG-DMR-050002S, and the CNSI Computer Facilities at UC Santa Barbara under NSF award no. CHE-0321368. Correspondence regarding the diffraction measurements should be made to P.R. (pryan@aps.anl.gov). Correspondence regarding the DFT calculations should be made to J.M.R. (rondo@mrl.ucsb.edu). 

∗ Electronic address: smay@drexel.edu 

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