Linear alkylbenzene
Hydrotreated kerosene is a typical feedstock for high purity linear paraffins (n-paraffins), which are subsequently dehydrogenated to linear olefins:
CnH2n+2 → CnH2n + H2
Alternatively, ethylene can be oligomerized (partially polymerized) to produce linear alkenes. The resulting linear mono-olefins react with benzene in the presence of a catalyst to produce the LABs. Hydrogen fluoride (HF) and aluminium chloride (AlCl3) are the two major catalysts for the alkylation of benzene with linear mono-olefins. The HF-based process is commercially dominant; however, the risk of releasing HF (a poisonous substance) into the environment became a concern particularly after the Clean Air Act Amendment. In 1995, a solid catalyst system (the DETAL process) became available. The process eliminates catalyst neutralization and HF disposal. Consequently, most LAB plants built since then have utilized this process. Given the large scale applications of LAB-derived detergents, a variety routes have been developed to produce linear alkylbenzenes: Each process generates LAB products with distinct features. Important product characteristics include the bromine index, sulfonatability, amount of 2-phenyl isomers (2-phenylalkane), the tetralin content, amount of non-alkylbenzene components, and the linearity of the product. The production of n-paraffins often occurs as part of an integrated LAB plant where the producers start from kerosene as raw material. The UOP process for producing normal paraffin includes a kerosene prefractionation unit, a hydrotreating unit and a Molex unit. The ExxonMobil Chemical technology includes a recovery process and can produce LAB grade n-paraffins from most medium to low sulfur kerosene without the use of a hydrotreater stage upstream. A desulfurization process is needed to reduce the sulfur content of some n-paraffins Linear alkylbenzene is sulfonated to produce linear alkylbenzene sulfonate (LAS), a biodegradable surfactant. LAS replaced branched dodecylbenzene sulfonates, which were phased out because they biodegrade more slowly. LAB was identified as a promising liquid scintillator by the SNO+ neutrino detector
due to its good optical transparency (≈20 m), high light yield, low amount of radioactive impurities, and its high flash point (140 °C) which makes safe handling easier. It is also available in large volumes at a relatively low cost at the SNO+ site. It is now used in several other neutrino detectors, such as the RENO and Daya Bay Reactor Neutrino Experiments. The material performs well in deep underwater environments. One study suggested LAB as a suitable material to be employed in a "Secret Neutrino Interactions Finder" (SNIF), a type of antineutrino detector designed to detect the presence of nuclear reactors at distances of between 100 and 500 km. LAB has been subject to concern about its effect on the environment and human health. European Council Regulation (EC) 1488/94 led to it being extensively evaluated. The life-cycle analysis considered the emissions and resulting environmental and human exposures. Following the exposure assessment, the environmental risk characterization for each protection target in the aquatic, terrestrial and soil compartment was determined. For human health the scenarios for occupational exposure, consumer exposure and human exposure indirectly via the environment have been examined and the possible risks identified. The report concludes that there are no concerns for the environment or human health. There is no need for further testing or risk reduction measures beyond those currently practiced. LAB was therefore de-classified and was removed from Annex 1 in the 28th ATP (Directive 2001/59).
Production ; Production details
They are mainly produced as intermediate in the production of surfactants, for use in detergent.